- Research Article
- 10.1149/ma2025-01381829mtgabs
Advances of AWE and their Indications for AEMWE
- Jul 11, 2025
- Electrochemical Society Meeting Abstracts
- Hui Xu + 4 more +4
Alkaline water electrolysis (AWE) is one major water electrolysis technology. AWE has been successfully commercialized for decades; however, its drawbacks include low operating current density, high shunt current, difficult in integration with renewable energy. However, AWE technologies have been recently revitalized due to high demand of low cost green H2. Among recent advances of AWE are thinner diaphragm, zero-gap configuration, advanced catalyst coating. Therefore, the performance of AWE has been tremendously improved, which exceeds 1A/cm2 at a voltage of 1.9 V. The development of AWE technologies may provide some insightful insights for the AEMWE. The current AEMWE faces some challenges including poor membrane durability and resulting short lifetime. Most AEMWEs only show extended lifetime (> 5, 000 hours) at a low current density (< 1 A/cm2) and the performance rapidly decays at elevated current density (> 2 A/cm2). The fast decay could be due to the chemical and electrochemical degradation of AEMs, and deteriorating interface between electrode and membrane. However, if the AEMWE cannot boost its durability at elevated current density, its competitiveness against AWE could become less meaningful. The improvements of AEMWEs need deep understanding of some key factors like membrane degradation, membrane/electrode interface, and component corrosion. Some effective probes and analytical approaches need to be developed to fully elucidate these important degradation mechanisms before one can transform the performance and lifetime of AEMWE.
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