- Research Article
51
- 10.1080/01932691.2015.1022654
Soft-Glassy Rheology of Asphaltenes at Liquid Interfaces
- Apr 02, 2015
- Journal of Dispersion Science and Technology
- Joseph R Samaniuk + 4 more +4
The presence of asphaltenes in oil and water emulsions promotes emulsion stability, a major concern in the recovery of oil reserves. A number of mechanisms for this stabilizing effect have been proposed recently, including those that implicate the interfacial rheology of asphaltenes as a primary factor. We present interfacial shear rheological data for asphaltenes at liquid–liquid interfaces and show conclusively that asphaltenes at an oil–water interface exhibit a soft-glassy rheological behavior in agreement with the soft-glassy rheology (SGR) model. This characteristic allows the stabilization of emulsions via mechanical resistance to coalescence.
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