Frontier Advanced Technology (China)

Electron transfer reactions driven by two-photon ionization in the higher excited state were investigated via transient absorption spectroscopy, with the aim to develop a method for creating the charge-separated (CS) state with a large formation rate, high energy level, and long lifetime. In the proof-in-principle experiments using pyrene and biphenyl as a model system, femtosecond transient absorption spectroscopy revealed that intense irradiation of an ultraviolet laser pulse at 355 nm efficiently pumps up pyrene into a higher excited state via a stepwise two-photon absorption, and then an ionization process takes place. An electron ejected from pyrene is directly captured by biphenyl with a time constant of 200 fs without the diffusion process of the electron in solution. The energy level of the CS state (Py+-Bp-) thus formed was estimated to be higher than that of the S1 state of pyrene by 0.53 eV. In addition, the subsequent ionic dissociation without a remarkable geminate recombination in the sub-nanosecond to nanosecond time region effectively avoids the quantity loss of the CS state. By applying the two-photon excitation method, we experimentally achieved ultrafast formation of the long-lived CS state at a high energy beyond the traditional framework of electron transfer reactions.

Spring Festival is the most important event in China, when families reunite in the town where the children grew up. At the film's core is the tradition of hanging a `Fú' (meaning `blessing') banner upside down, symbolizing "good luck comes", tying in to the overall campaign idea of turning traditional concepts on their head; in this case, 'home' coming to you rather than the other way around.

We demonstrated one-colour control of activation, excitation and deactivation of a fluorescent diarylethene derivative by using a 532 nm CW laser at a weak output power. This one-colour control method was applied to single-molecule tracking in polymer films over a total duration of a few hours at room temperature and PALM for the nanostructures of polymer systems.