Hewlett-Packard (Austria)

Despite its connecting character to the Sutjeska National Park in the North-East, the course of the upper Neretva (Ulog and Borač valley) in Bosnia and Herzegovina (BiH), has to date not been an area of focus for carnivore research. With the aim of contributing to an improved understanding of the present distribution of large and endangered carnivores in this area, a field survey was conducted during the Neretva Science Week 2022. Opportunistic data collection was carried out along a predefined road transect (20 km) and six line transects (13 km) tracked by foot. Additionally, reports of mammal signs for six corresponding research sites along the Neretva were registered. Altogether, at least 15 mammal species could be distinguished. From the identified carnivores, four are listed in Annex II of the Habitats Directive. Furthermore, the signs of lynx presence, in addition to brown bear and grey wolf, highlight the connectivity value of the upper Neretva in its current state. Based on information from local practitioners, the main threats to large carnivores are hunting pressure and a negative perception as competitors. A likely decline in habitat quality and fragmentation, due to the planned hydropower plants expansion and logging activities, exacerbate these threats. Consequently, further systematic monitoring is recommended to assess the possible impact of human driven environmental changes.

Decision logic extraction from natural language texts can be a tedious, labor-intensive task. This is especially true for legislative texts, since they do not always follow usual speech and writing patterns. This paper explores the possibility of using machine learning and natural language processing approaches to identify decision rules within legislative documents, and ultimately provides the possibility of building an extraction algorithm on top of the solution to extract and visualize decision logic automatically. Such a novel method for decision rules identification bears the potential to reduce human labor, minimize mistakes, and lessen context dependency. To accomplish this, we use pre-trained word vectorization in conjunction with a complex multi-layer convolutional neural network (CNN). The relevant data used in this project was generated from the Austrian income tax code and labeled by hand. A quantitative evaluation shows that our approach can be trained on as little as a single code of law and still obtain significant accuracy.

The Belousov–Zhabotinsky (BZ) oscillating chemical reaction involves the oxidation of an organic compound by the bromate ion in the presence of a metal ion catalyst such as cerium(iv), manganese(ii), or ferroin. Simple periodic oscillations are generally obtained for the BZ reaction in a batch (closed) system. However, complex oscillations have been observed for the BZ reaction in batch with malonic acid and either cerium or ferroin ions as the catalyst. We report here that fascinating complex oscillations in the potential of a Pt electrode have been found in the batch BZ reaction with methylmalonic acid (MeMA) and manganese(ii). Relatively high initial concentrations of NaBrO3 and MeMA are required, and the [NaBrO3]0/[MeMA]0 ratio is the main factor determining the type of oscillations obtained. Other relevant factors are [NaBr]0, [MnSO4]0, [H2SO4]0 or [NaOH]0, temperature, and stirring rate. Complex phenomena observed include mixed mode oscillations, birhythmicity, quasiperiodicity, bursting, and possible chaos. A mechanism is proposed involving the reversible formation of a manganese(iii) complex with bromomethylmalonic acid followed by two-electron oxidation to methyltartronic acid and Mn2+.

Der im vorliegenden Beitrag präsentierte Briefwechsel zwischen Camila Lucerna und Franz Schütz setzt sich aus insgesamt 258 Schriftstücken in deutscher Sprache zusammen, beherbergt in zwei Bibliotheken in Graz: der Universitätsbibliothek und der Steiermärkischen Landesbibliothek. Den Briefen ist eine enge freundschaftliche Beziehung der Autoren zu entnehmen. Sie dienten nicht der bloßen Mitteilung der Nachrichten an abwesende Person, sondern transportieren die Meinung der Autoren zu Kunstrichtungen, philosophischen Ideen, gesellschaftsspezifischen oder staatspolitischen Fragen ihrer Zeit. Der Briefwechsel ist Ausdruck eines vielfältigen kulturellen Dialogs in historisch denkwürdigen Zeiten.

We measure the diamagnetic deflection of anthracene and adamantane in a long-baseline matter-wave interferometer. From the nanometer-level deflection we extract the magnetic susceptibilities of the molecules which we compare with calculations and previous results. Adamantane yields an isotropic average mass susceptibility of -8.0 ± 1.1 m3 kg-1, consistent with expectations, while anthracene yields a higher-than-anticipated value of -13.6 ± 1.3 m3 kg-1. We attribute the high anthracene value to the planar aromatic molecule's magnetic anisotropy and partial alignment in the molecular beam, and estimate the magnitude of the effect on the observed deflection.

In the past decade, ion mobility spectrometry (IMS) in combination with mass spectrometry (IM-MS) became a widely employed technique for the separation and structural characterization of ionic species in the gas phase. Similarly to chromatography, where studies on the mechanism of band broadening and adequate plate-height equations have been aiding method development and promoting advancements in column technology, a suitable resolving power theory of drift tube ion mobility-mass spectrometry (DTIM-MS) is essential to stimulate further progress in this emerging field of separation science. In the present study, therefore, we explore dispersion processes in detail and present a plate-height model of ion mobility-mass spectrometry. We quantify the effects of five major dispersion processes that contribute to zone broadening and determine the resolving power in DTIM-MS: diffusion, Coulomb repulsion, electric field inhomogeneities, the finite initial spread of the ion cloud and dispersion outside the mobility cell. A solution is provided to account for the nonuniform separation field in IM-MS in the presence of multiple compartments. The equations - derived from first principles - serve as the basis for formulating an expression that is similar in nature to van Deemter's plate-height equation for chromatography. A comprehensive set of experiments was performed on a custom-built DTIM-MS instrument to evaluate the accuracy of the plate-height model, resulting in satisfactory agreement between experiment and theory. Building on these findings, the plate-height equation was employed to explore the influence of drift gas pressure, injection pulse-width and the mobility of ions on resolving power from a theoretical point of view. Our findings may aid instrument design and development in the future, as well as the optimization of measurement conditions to improve ion mobility separations. By employing the plate-height concept and the general formalism of differential migration processes to describe zone spreading in IM-MS, we aim to find a common ground between this emerging method and such well-established techniques as HPLC or CZE. We also hope that the work presented here will facilitate a broader acceptance of IMS as a separation method of great potential by the communities of chromatography and electrophoresis, as well as that of mass spectrometry.