Polysolar (United Kingdom)

Bismuth-based coordination complexes are advantageous over other metal complexes, as bismuth is the heaviest nontoxic element with high spin-orbit coupling and potential optoelectronics applications. Herein, four bismuth halide-based coordination complexes [Bi2Cl6(phen-thio)2] (1), [Bi2Br6(phen-thio)2] (2), [Bi2I6(phen-thio)2] (3), and [Bi2I6(phen-Me)2] (4) were synthesized, characterized, and subjected to detailed photophysical studies. The complexes were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and NMR studies. Spectroscopic analyses of 1-4 in solutions of different polarities were performed to understand the role of the organic and inorganic components in determining the ground- and excited-state properties of the complexes. The photophysical properties of the complexes were characterized by ground-state absorption, steady-state photoluminescence, microsecond time-resolved photoluminescence, and absorption spectroscopy. Periodic density functional theory (DFT) calculations were performed on the solid-state structures to understand the role of the organic and inorganic parts of the complexes. The studies showed that changing the ancillary ligand from chlorine (Cl) and bromine (Br) to iodine (I) bathochromically shifts the absorption band along with enhancing the absorption coefficient. Also, changing the halides (Cl, Br to I) affects the photoluminescent quantum yields of the ligand-centered (LC) emissive state without markedly affecting the lifetimes. The combined results confirmed that ground-state properties are strongly influenced by the inorganic part, and the lower-energy excited state is LC. This study paves the way to design novel bismuth coordination complexes for optoelectronic applications by rigorously choosing the ligands and bismuth salt.

Repeatable and accurate tests are important when designing hardware and algorithms for solar-powered wireless sensor networks (WSNs). Since no two days are exactly alike with regard to energy harvesting, tests must be carried out indoors. Solar simulators are traditionally used in replicating the effects of sunlight indoors; however, solar simulators are expensive, have lighting elements that have short lifetimes, and are usually not designed to carry out the types of tests that hardware and algorithm designers require. As a result, hardware and algorithm designers use tests that are inaccurate and not repeatable (both for others and also for the designers themselves). In this article, we propose an indoor test methodology that does not rely on solar simulators. The test methodology has its basis in astronomy and photovoltaic cell design. We present a generic design for a test apparatus that can be used in carrying out the test methodology. We also present a specific design that we use in implementing an actual test apparatus. We test the efficacy of our test apparatus and, to demonstrate the usefulness of the test methodology, perform experiments akin to those required in projects involving solar-powered WSNs. Results of the said tests and experiments demonstrate that the test methodology is an invaluable tool for hardware and algorithm designers working with solar-powered WSNs.