- Conference Article
- 10.1117/12.3069798
Development of ammonia gas visualization technique using the resonance Raman effect
- Oct 28, 2025
- Takehiro Kawasaki + 7 more +7
In this study, we conducted a basic study on the visualization of ammonia gas using a flash lidar, which uses the resonance Raman effect, for the purpose of visualizing gas leak locations and analyzing gas flow. We have previously developed a remote ammonia leak detection technology (resonance Raman LIDAR) using the resonance Raman effect. In general, the Raman effect has significant advantages such as the ability to identify various substances that cannot be detected by other optical methods and to perform spectroscopic measurements of multiple substances. On the other hand, the Raman effect is extremely weak compared to other light-matter interactions, so the resonance Raman effect, which can significantly enhance the weak Raman effect, is effective for remote detection of trace components. The resonance Raman effect is a phenomenon in which Raman scattered light corresponding to a conjugate vibration mode is greatly enhanced when the target substance is excited by light with a wavelength corresponding to the electronic absorption band of the target substance. In actual measurements, the pattern of the ultraviolet-visible absorption spectrum indicating the electronic transition energy of the target substance serves as an indicator of the applicability of the resonance Raman effect, and the fifth harmonic of the Nd:YAG laser (wavelength 213nm) matches the electronic absorption band of ammonia. Resonance Raman LIDAR can measure gas concentrations and their distance remotely, but to obtain two- or three-dimensional images of the gas concentration distribution, it is necessary to scan the optical axis of the laser and observation optical system. If flash lidar, a technology that expands a laser beam and emits it into the observation space like a camera flash and uses a camera as a detector to instantly visualize the gas concentration distribution as a two-dimensional image, could be applied to ammonia gas leak detection, its usefulness as a safety technology would be enhanced. In this study, a pulsed laser with a wavelength of 213nm was used as the excitation light source and successfully visualized ammonia gas by observing the 4318cm<sup>-1</sup> spectra among the multiple resonance Raman spectra of ammonia.
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