Toyon (United States)

Sudden onset of solubilization is observed widely around or below the critical micelle concentration (CMC) of surfactants. It has also been reported that micellization is induced by the solutes even below CMC and the solubilized solute increases the aggregation number of the surfactant. These observations suggest enhanced cooperativity in micellization upon solubilization. Recently, we have developed a rigorous statistical thermodynamic theory of cooperative solubilization. Its application to hydrotropy revealed the mechanism of cooperative hydrotropy: hydrotrope self-association enhanced by solutes. Here we generalize our previous cooperative solubilization theory to surfactants. We have shown that the well-known experimental observations, such as the reduction of CMC in the presence of the solutes and the increase of aggregation number, are the manifestations of cooperative solubilization. Thus, the surfactant self-association enhanced by a solute is the driving force of cooperativity and a part of a universal cooperative solubilization mechanism common to hydrotropes and surfactants at low concentrations.

Reactions of CuX with the bis(triazolyl) ligand Hbtm [bis(1-benzyl-1H-1,2,3-triazol-4-yl)phenylmethanol] in CH2Cl2 afforded trinuclear copper(ii) complexes with a core structure (μ-X)Cu3(μ-κ3-N,O,N-btm)3(L)2+ [X = Cl, L = CH3OH (1); X = Br, L = H2O (2)], while a similar reaction of [Cu(CH3CN)4](PF6) with the mono(triazolyl) ligand HPhtm [(1-benzyl-1H-1,2,3-triazol-4-yl)diphenylmethanol] resulted in the mononuclear complex [Cu(κ2-N,O-Phtm)(κ2-N,O-HPhtm)(κ1-N-HPhtm)][PF6] (3). The structural characterization of these complexes was made by single-crystal X-ray crystallography in combination with elemental and ESI mass analyses. Catalytic studies toward aerobic oxidation of benzyl alcohol to benzaldehyde revealed that the trinuclear 1 and 2 exhibited higher activities than the mononuclear 3 in both CH3CN and EtOH/H2O solvent systems.

We prepared enzyme-immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme-immobilized hydrogels increased as the cross-linking density in the hydrogels increased. In addition, we controlled the oxidation rate using hydrogels exhibiting an appropriate interaction with a decoy molecule in the hydrogel.

Metal halide perovskites are semiconductors with many fascinating characteristics and their widespread use in optoelectronic devices has been expected. High-quality thin films and single crystals can be fabricated by simple chemical solution processes and their fundamental electrical, optical, and thermal properties can be changed significantly by compositional substitution, in particular halogen ions. In this perspective, we provide an overview of phonon and thermal properties of metal halide perovskites, which play a decisive role in determining device performance. After a brief introduction to fundamental material properties, longitudinal-optical phonons and unusual thermal properties of metal halide perovskites are discussed. Remarkably, they possess very low thermal conductivities and very large thermal expansion coefficients despite their crystalline nature. In line with these discussions, we present optical properties governed by the strong electron-phonon interactions and the unusual thermal properties. By showing their unique thermo-optic responses and novel application examples, we highlight some aspects of the unusual thermal properties.

Crystals of (HDABCO+)9(DABCO)[Ni(dmit)2]9·6CH3CN were shown to have a space group of R3[combining macron], a hexapetal flower-like channel of [Ni(dmit)2] anions, and a one-dimensional hydrogen bonding chain composed of protonated DABCO and CH3CN molecules. The crystals display antiferromagnetic and ferromagnetic interactions within and between hexamers, respectively, whereas the flexible DABCO-CH3CN array shows dielectric relaxation.

This study reports pollutant remediation by a catalyst-loaded, β-cyclodextrin cross-linked polymer monolith. The monolith enabled removal of the pollutant to a residual concentration with no environmental effect and conversion of the adsorbed pollutant into useful compounds with enriched concentration, allowing for the adsorption capacity regeneration.

Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a RhIII4ZnII4 polycarboxylate is reported.

The tetraarylporphyrin/POM complexes with CT character show negative differential resistance because of the memristor-like behavior.

Passive sensor target tracking has the challenge to 3-D tracking applications in that the raw angle-only measurements cannot be converted into Cartesian measurements. Multi-sensor methods can be used to convert the raw measurements into Cartesian measurements by finding the intersection of the two lines of sight. Examples include triangulation, law of sines, and maximum likelihood estimation. However, many of these methods can have an inherent bias present in the conversion as a result of its nonlinearity. In long range applications this can cause significant error. This paper investigates the conversion of passive sensor angle-only measurements into Cartesian coordinates and evaluates the conversion bias present in triangulation.