- Research Article
- 10.1021/acsomega.5c08239
HydrothermallySynthesized Mn2V2O7 Nanopebble-DecoratedZIF-67: A Promising Cathode Materialfor Energy Storage Applications
- Mar 16, 2026
- ACS Omega
- Senthilselvan Sanjana + 7 more +7
Metal–organic framework (MOF) based electrodestypicallyare very good at holding energy and have low electrical conductivitylimitations. Studies on redox additive electrolytes (RAEs) have beenexplored to further enhance the electrochemical characteristics andscale up. Additionally, additives make a Faradaic charge storage mechanismpossible, increasing energy density and capacitance while also enhancingstability and rate capability. In the present study, a novel Mn2V2O7@ZIF-67 nanocomposite has been synthesized,and its electrochemical properties were studied in KOH and RAE. Thesynthesized Mn2V2O7@ZIF-67 compositematerial shows a polyhedral morphology. In the three-electrode system,the specific capacitances are determined to be 687.4 and 265.2 F/gfor RAE and KOH electrolytes, respectively, and a capacitance retentionwas 90.21% after 10,000 GCD cycles in RAE. The fabricated Mn2V2O7@ZIF-67//AC demonstrates 92.56% capacityretention after 10,000 GCD cycles with a specific capacitance of 62.65F/g. The Rs values of the fabricated deviceare 1.88 Ω before and 1.97 Ω after GCD cycles.
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