- Research Article
- 10.1007/s11236-005-0058-8
Effect of the initial temperature of a reactive medium on the critical conditions for thermal explosion
- Mar 01, 2005
- Theoretical Foundations of Chemical Engineering
- I A Zaev + 3 more +3
A nonstationary formulation of critical conditions for thermal explosion in the Thomas problem (asymmetric self-ignition) and the classical Frank-Kamenetskii problem (symmetric self-ignition) are numerically studied. By the example of the Thomas problem, it is shown that the thermal explosion limit depends on the form of the initial spatial temperature distribution of the medium. For the Frank-Kamenetskii problem, the effect of the initial spatial temperature distribution and the initial overheating of the reactant on the critical value of the Frank-Kamenetskii number is studied. The particular initial spatial temperature distribution is determined; the investigation of its evolution allows one to make a conservative estimate of the thermal explosion limit. The limitation of the classical criterion for thermal explosion is shown, and the limits of applicability of the stationary theory are numerically determined from the initial overheating. For engineering calculations, an analytical formula for conservatively estimating the critical conditions for thermal explosion as a function of the initial reactant overheating is obtained.
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