- Research Article
- 10.1149/1945-7111/ae6894
Efficient Reformulation of Linear and Nonlinear Solid-Phase Diffusion in Lithium-Ion Battery Models Using Symmetric Polynomials: Part II. Dimensional Form for Spherical, Cylindrical, and Rectangular Coordinates
- May 05, 2026
- Journal of The Electrochemical Society
- Puneet Jindal + 7 more +7
Solving the solid-state diffusion equation in a typical pseudo-two-dimensional (P2D) battery model using conventional finite difference methods (FDM) substantially increases the model complexity (in terms of number of equations) as well as the computational time. In our previous work, we approximated the solid-state diffusion in spherical particles using Galerkin weak form method based on symmetric polynomials, which significantly improved the robustness of modeling, achieving a tenfold reduction in computational time, even for non-linear diffusion problems. However, we found that the equations represented in non-dimensional form for mathematical compactness are relatively difficult to interpret and apply in P2D and other battery models. Therefore, as a follow-up to previous work, we present the weak form formulations of solid-state diffusion in dimensional form to provide better physical interpretation and easier adaptability to battery modelling and other applications. Further, considering diverse particle morphologies in modern battery materials, we extend these formulations for cylindrical and rectangular coordinates, in addition to the spherical coordinate. We further present simulations using various experimentally reported concentration-dependent diffusivities and find that the solution convergence is strongly influenced by the degree of non-linearity in diffusion. The study enables the proposed formulation to be widely applicable facilitating accurate and fast simulations.
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