An Experimental Approach to Determining the Average Diffusion Coefficient of Volatile Components in Polymer Waste Materials

Bamboo shows great potential as reinforcement material in polymer matrix. However, as a plant based fiber, its thermal stability should be carefully assessed for further application. It is expected that understanding the thermal stability of the composites will provide sufficient information in analyzing the feasibility for application under high temperature. This study aims to analyze the thermal behavior a bamboo-based composite using the Thermogravimetric Analysis (TGA) method with ASTM E-1131 standard. The composites were prepared by compression moulding using virgin and recycled high density polyethylene (HDPE) as the polymer matrix. For comparison purpose, the bamboo strips from inner and outer layer were investigated. Those strips were processed into particles with a size of 20 mesh and then treated with 5% of NaOH for 2 h priors to composite fabrication. The prepared composite consists of 10% bamboo loading and 90% of HDPE matrix. TGA analysis was performed using sample weight of 15–30 mg, a heating speed of 10 ℃/min and a heating temperature of 30–600 ℃. The results of this research show that the virgin HDPE composites had better thermal stability than r-HDPE composites. The highest thermal stability is on pure HDPE matrix composites with bamboo fiber from outer layer with a weight reduction of 5% at a temperature of 301.01 ℃ and a weight reduction of 10% at a temperature of 336.79 ℃.

High density polyethylene (HDPE) is a thermoplastic polymer which is classified as one of the highly consumed types of plastics. One major advantage of thermoplastic materials is their ability of recycling and reprocessing which will bring considerable economic and environmental benefits. The present paper, therefore, endeavors to explore the practical possibility of using recycled HDPE hollow section as a replacement of virgin HDPE made by the extrusion process. The main focus of the study was to evaluate the mechanical performance of the recycled HDPE and compare the results with virgin or non-recycled HDPE. The modulus of elasticity, tensile yield and ultimate strength, compressive yield and ultimate strength, flexural yield and ultimate strength and the coefficient of thermal expansion were the main parameters to be checked against the respective mechanical properties. Thus, pursuant to the results, it was found out that the modulus of elasticity and the tensile yield strength are lower in recycled HDPE compared to the non-recycled HDPE. However, there is no significant difference between the recycled and non-recycled HDPE for the tensile ultimate strength, compressive yield strength and compressive ultimate strength. The flexural yield strength and flexural ultimate strength properties of the recycled HDPE proved to be superior to those of the non-recycled HDPE. The coefficient of linear thermal expansion of the recycled HDPE sample was 130 μm/(m.°C) and that for the non-recycled HDPE was 142 μm/(m.°C).

Six hundred conventional recycled HDPE flake samples, which were recollected and sorted in the UK, were screened for post-consumer contamination levels. Each analysed sample consisted of 40-50 individual flakes so that the amount of analysed individual containers was in the range 24 000-30 000 post-consumer milk bottles. Predominant contaminants in hot-washed flake samples were unsaturated oligomers, which can be also be found in virgin high-density polyethylene (HDPE) pellet samples used for milk bottle production. In addition, the flavour compound limonene, the degradation product of antioxidant additives di-tert-butylphenol and low amounts of saturated oligomers were found in higher concentrations in the post-consumer samples in comparison with virgin HDPE. However, the overall concentrations in post-consumer recycled samples were similar to or lower than concentration ranges in comparison with virgin HDPE. Contamination with other HDPE untypical compounds was rare and was in most cases related to non-milk bottles, which are <2.1% of the input material of the recycling process. The maximum concentration found in one sample of 1 g was estimated as 130 mg kg-1, which corresponds to a contamination of 5200-6500 mg kg-1 in the individual bottle. The recycling process investigated was based on an efficient sorting process, a hot-washing of the ground bottles, and a further deep-cleaning of the flakes with high temperatures and vacuum. Based on the fact that the contamination levels of post-consumer flake samples are similar to virgin HDPE and on the high cleaning efficiency of the super-clean recycling process especially for highly volatile compounds, the recycling process investigated is suitable for recycled post-consumer HDPE bottles for direct food-contact applications. However, handpicking after automatically sorting is recommended to decrease the amount of non-milk bottles. The conclusions for suitability are valid, provided that the migration testing of recyclate contains milk bottles up to 100% and that both shelf-life testing and sensorial testing of the products are successful, which are topics of further investigations.

High Density Polyethylene (HDPE) is a commodity thermoplastic used to produce a major percentage of plastic containers on the market today. The need for recycling of plastic waste is a result of the high price of material and environmental pollution. Blends of virgin/postconsumer HDPE from water bottles at different ratios ranging from virgin to 100 % post-consumer HDPE were reprocessed for 10 passes using twin screw extruder. The effects of reprocessing and varying the amount of post-consumer HDPE on processability, thermal and mechanical properties were investigated. It was found that virgin HDPE and blends of virgin/post-consumer HDPE can be reprocessed at 235 ℃ for 10 passes with better processability, decrease in viscosity and percentage of crystallinity, and small changes in mechanical properties. A decrease in MFI was hypothesized to be due to crosslinking or chain branching rather than to chain scission.

Research on graphene-related two-dimensional (2D) materials (GR2Ms) in recent years is strongly moving from academia to industrial sectors with many new developed products and devices on the market. Characterization and quality control of the GR2Ms and their properties are critical for growing industrial translation, which requires the development of appropriate and reliable analytical methods. These challenges are recognized by International Organization for Standardization (ISO 229) and International Electrotechnical Commission (IEC 113) committees to facilitate the development of these methods and standards which are currently in progress. Toward these efforts, the aim of this study was to perform an international interlaboratory comparison (ILC), conducted under Versailles Project on Advanced Materials and Standards (VAMAS) Technical Working Area (TWA) 41 "Graphene and Related 2D Materials" to evaluate the performance (reproducibility and confidence) of the thermogravimetric analysis (TGA) method as a potential new method for chemical characterization of GR2Ms. Three different types of representative and industrially manufactured GR2Ms samples, namely, pristine few-layer graphene (FLG), graphene oxide (GO), and reduced graphene oxide (rGO), were used and supplied to ILC participants to complete the study. The TGA method performance was evaluated by a series of measurements of selected parameters of the chemical and physical properties of these GR2Ms including the number of mass loss steps, thermal stability, temperature of maximum mass change rate (Tp) for each decomposition step, and the mass contents (%) of moisture, oxygen groups, carbon, and impurities (organic and non-combustible residue). TGA measurements determining these parameters were performed using the provided optimized TGA protocol on the same GR2Ms by 12 participants across academia, industry stakeholders, and national metrology institutes. This paper presents these results with corresponding statistical analysis showing low standard deviation and statistical conformity across all participants that confirm that the TGA method can be satisfactorily used for characterization of these parameters and the chemical characterization and quality control of GR2Ms. The common measurement uncertainty for each parameter, key contribution factors were identified with explanations and recommendations for their elimination and improvements toward their implementation for the development of the ISO/IEC standard for chemical characterization of GR2Ms.

This article presents the potential use of tree waste materials such as the leaves (L), branches (B) and trunks (T) of Azadirachta excelsa (Sentang) tree in the production of wood polymer composite (WPC). The WPC was fabricated from high-density polyethylene (HDPE) as bonding matrix, maleic anhydride (MA) as coupling agent, and Sentang tree waste particles (L, B and T) as filler, prepared using twin-screw extruder followed by injection moulding machine. The effects of incorporating these types of Sentang tree waste particle (at 35% and 45% particles loading by weight) on the thermal stability of WPC were reported. The chemical compositions of L, B and T were also determined and their influences on the thermal stability of WPC were discussed. The thermal behaviour was determined by using thermogravimetric analysis (TGA), whereas the chemical analysis using Technical Association of the Pulp and Paper Industry (TAPPI) methods. The addition of these tree waste particles as filler has increased the thermal stability of WPC compared to virgin HDPE (without any particle incorporation). The highest mass loss was experienced by virgin HDPE. It was also observed that chemical compositions of the particles played vital role in influencing the thermal stability of WPC.

Diffusion and solubility coefficients determined by permeation and immersion experiments for organic solvents in HDPE geomembrane

Obituary: David Slater

Ignition temperatures of various bio-oil based fuel blends and slurry fuels

With the rise of additive manufacturing, the demand for 3D printing feedstock has increased exponentially and its sustainability is critical in the future. Many scholars are now concerned about how 3D printing filaments should be reproduced from recycled plastic. This study aimed to develop a filament extruder machine and investigate the potential of using recycled high-density polyethylene (HDPE), one of the most commonly used and recyclable thermoplastic, for 3D printing filament material. Desktop sized filament extruder machine was built, and a smooth and round-shaped 1.75±0.01mm diameter recycled HDPE filament was produced. Its mechanical, thermal, chemical, and physical properties were characterized by conducting various tests and validation test was conducted by comparing its properties with its virgin counterpart. The ultimate tensile strength of the recycled HDPE filament was obtained 19.02±0.35MPa, which is comparable to the ultimate tensile strength of virgin HDPE, making it a viable 3D printing feedstock for rapid prototyping. According to Thermogravimetric analysis (TGA), the recycled HDPE filament offers significant thermal stability with an onset degradation temperature of 430℃ and a full degradation temperature of 520℃. Its Fourier Transform Infrared (FTIR) spectrum shows the same functional groups as virgin HDPE polymer. The recycled HDPE filament has also excellent water-rejecting capability. In general, the study revealed a promising result for the use of recycled HDPE plastic as a more sustainable and environmentally friendly source material for 3D printing filament. To increase the potential and market competitiveness of recycled filaments, further investigation is required to optimize the filament extrusion and 3D printing process parameters, improve the mechanical properties, and overall development methods for both the recycled HDPE filament and 3D printed products.

Quantitative assessment of plastic waste in rubber plantations through modelling approach

The simultaneous sorption behaviors of four analytes from the UV filters group, benzophenone (BPh), 4-methylbenzylidene camphor (4MBC), benzophenone 3 (BPh3), and benzophenone 2 (BPh2) on virgin and aged high-density polyethylene (HDPE) with a particle size of 125 μm in milliQ and river water were examined in this study. The aging processes of HDPE particles were carried out with the use of simulated sunlight. Conducted research revealed that the sorption of UV filters on HDPE particles follows pseudo-second-order kinetics. A Temkin isothermal model best described the adsorption process for 4BMC, BPh, BPh3, BPh2 on aged HDPE in river water, and 4MBC, BPh, BPh3 on virgin HDPE in milliQ water. The adsorption of BPh2 onto virgin MPs in milliQ water was consistent with the Langmuir isothermal model. Environmental conditions and physicochemical properties of analytes influenced the sorption mechanism between UV filters and MPs particles. It was observed that the main mechanisms responsible for the sorption of BPh, 4MBC, BPh3, and BPh2 on the surface of HDPE are hydrophobic interactions, that may change through the involvement of electrostatic interactions.

Thermal behavior of liquefied wood polymer composites (LWPC)

This study aims to quantify the overall environmental performances of mechanical recycling of the postconsumer high‐density polyethylene (HDPE) and polyethylene terephthalate (PET) in Jordan. The life‐cycle assessment (LCA) methodology is used to assess the potential environmental impacts of recycling postconsumer PET and HDPE. It quantifies the total energy requirements, energy sources, atmospheric pollutants, waterborne pollutants, and solid waste resulting from the production of recycled PET and HDPE resin from the postconsumer plastic. System expansion and cut‐off recycling allocation methods are applied. The analysis has been carried out according to the LCA standard, series UNI EN ISO 14040‐14044:2006. A standard unit of output (functional unit) is defined as “one ton of PET flake” and “one ton of HDPE pellet.” The results of the production of virgin resin are compared with the “cut‐off” and “system expansion” recycling results. Depending on the allocation methods applied, a nonrenewable energy saving of 40–85% and greenhouse gas emission saving of 25–75% can be achieved. Based on two allocation methods, PET and HDPE recycling offers important environmental benefits over single‐use virgin PET and HDPE. LCA offers a powerful tool for assisting companies and policy‐makers in the waste plastic industry. Furthermore, the “system expansion” recycling method is not easy to apply because it requires detailed data outside of the life cycle of the investigated product.

Thermal decomposition of allyl-imidazolium-based ionic liquid studied by TGA–MS analysis and DFT calculations