Certifying steady-state properties of open quantum systems

While the scaling of entanglement in a quantum system can be used to distinguish many-body quantum phases, it is usually hard to quantify the amount of entanglement in mixed states of open quantum systems, while measuring entanglement experimentally, even for the closed systems, requires in general quantum state tomography. In this work we show how to remedy this situation in system with a fixed or conserved charge, e.g., density or magnetization, due to an emerging relation between quantum correlations and coherence. First, we show how, in these cases, the presence of multipartite entanglement or quantumness can be faithfully witnessed simply by detecting coherence in the quantum system, while bipartite entanglement or bipartite quantum discord are implied by asymmetry (block coherence) in the system. Second, we prove that the relation between quantum correlations and coherence is also quantitative. Namely, we establish upper and lower bounds on the amount of multipartite and bipartite entanglement in a many-body system with a fixed local charge, in terms of the amount of coherence and asymmetry present in the system. Importantly, both for pure and mixed quantum states, these bounds are expressed as closed formulas, and furthermore, for bipartite entanglement, are experimentally accessible by means of the multiple quantum coherence spectra. In particular, in one-dimensional systems, our bounds may detect breaking of the area law of entanglement entropy. We illustrate our results on the example of a many-body localized system, also in the presence of dephasing.

Information scrambling refers to the phenomenon in which local quantum information in a many-body system becomes dispersed throughout the entire system under unitary evolution. It has been extensively studied in closed quantum systems, where it is quantified by operator size growth, revealing deep connections between condensed matter physics, high-energy physics, and quantum information. However, when extending the study of operator size dynamics to open quantum systems, two different definitions of operator size distributions emerge. These definitions are based on different treatments of the bath. In this work, we aim to establish a unified picture for operator size dynamics in open quantum systems, using the solvable Brownian SYK models at generic system size. In particular, we provide the conditions under which the signature of scrambling transition — discovered using one particular definition — appears in operator size dynamics under the other definition. Additionally, we extend previous studies by exploring finite-size effects that are not captured by the scramblon theory. Our results provide a refined understanding of operator size dynamics in open quantum systems.

Adiabatic elimination methods allow the reduction of the space dimension needed to describe systems whose dynamics exhibit separation of timescale. For open quantum systems, it consists in eliminating the fast part assuming it has almost instantaneously reached its steady state and obtaining an approximation of the evolution of the slow part. These methods can be applied to eliminate a linear subspace within the system Hilbert space or, alternatively, to eliminate a fast subsystem in a bipartite quantum system. In this work, we extend an adiabatic elimination method used for removing fast degrees of freedom within a system [Phys. Rev. A 101, 042102 (2020)] to eliminate a subsystem from an open bipartite quantum system. As an illustration, we apply our technique to a dispersively coupled two-qubit system and in the case of the open Rabi model.

Using Liouville space and superoperator formalism we consider pure stationary states of open and dissipative quantum systems. We discuss stationary states of open quantum systems, which coincide with stationary states of closed quantum systems. Open quantum systems with pure stationary states of linear oscillator are suggested. We consider stationary states for the Lindblad equation. We discuss bifurcations of pure stationary states for open quantum systems which are quantum analogs of classical dynamical bifurcations.

Symmetries in an open quantum system lead to degenerated Liouvillians that physically imply the existence of multiple steady states. In such cases, obtaining the initial condition independent steady states is highly nontrivial since any linear combination of the true asymptotic states, which may not necessarily be a density matrix, is also a valid asymptote for the Liouvillian. Thus, in this work, we consider different approaches to obtain the true steady states of a degenerated Liouvillian. In the ideal scenario, when the open system symmetry operators are known, we show how these can be used to obtain the invariant subspaces of the Liouvillian and hence the steady states. We then discuss two other approaches that do not require any knowledge of the symmetry operators. These could be powerful numerical tools to deal with quantum many-body complex open systems. The first approach that is based on Gram–Schmidt orthonormalization of density matrices allows us to obtain all the steady states, whereas the second one based on large deviations allows us to obtain the non-degenerated maximum and minimum current carrying states. We discuss the symmetry-decomposition and the orthonormalization methods with the help of an open para-benzene ring and examine interesting scenarios such as the dynamical restoration of Hamiltonian symmetries in the long-time limit and apply the method to study the eigenspacing statistics of the nonequilibrium steady state.

Continuing our work on the nature and existence of fluctuation-dissipation relations (FDR) in linear and nonlinear open quantum systems [J.-T. Hsiang, B. L. Hu, and S.-Y. Lin, Phys. Rev. D 100, 025019 (2019); J.-T. Hsiang, B. L. Hu, S.-Y. Lin, and K. Yamamoto, Phys. Lett. B 795, 694 (2019); J.-T. Hsiang and B. L. Hu, Physics (Utrecht) 1, 430 (2019); J.-T. Hsiang and B. L. Hu, Phys. Rev. D 101, 125003 (2020)], here we consider such relations when a linear system is in a nonequilibrium steady state (NESS). With the model of two-oscillators (considered as a short harmonic chain with the two ends) each connected to a thermal bath of different temperatures we find that when the chain is fully relaxed due to interaction with the baths, the relation that connects the noise kernel and the imaginary part of the dissipation kernel of the chain in one bath does not assume the conventional form for the FDR in equilibrium cases. There exists an additional term we call the ``bias current'' that depends on the difference of the bath's initial temperatures and the interoscillator coupling strength. We further show that this term is related to the steady heat flow between the two baths when the system is in an NESS. The ability to know the real-time development of the interheat exchange (between the baths and the end-oscillators) and the intraheat transfer (within the chain) and their dependence on the parameters in the system offers possibilities for quantifiable control, and in the design of quantum heat engines, or thermal devices.

Adiabatic theorem and non-adiabatic corrections have been widely applied in modern quantum technology. Recently, non-adiabatic linear response theory has been developed to probe the many-body correlations in closed systems. In this work, we generalize the non-adiabatic linear response theory to open quantum many-body systems. We show that, similar to the closed case, the first-order deviation from the instantaneous steady state is memoryless—it depends only on the final parameters and not on the initial state or ramping path. When ramping the Hamiltonian, the linear response of observables is governed by the derivative of the retarded Green’s function, as in closed systems. In contrast, ramping the dissipation gives rise to a different response, characterized by a high-order correlation function defined in the steady state. Our results offer a compact and physically transparent formulation of non-adiabatic response in open systems, and demonstrate that ramping dynamics can serve as a versatile tool for probing many-body correlations beyond equilibrium.

Photovoltaic devices, electrochemical cells, catalysis processes, light emitting diodes, scanning tunneling microscopes, molecular electronics, and related devices have one thing in common: open quantum systems where energy and matter are not conserved. Traditionally quantum chemistry is confined to isolated and closed systems, while quantum dissipation theory studies open quantum systems. The key quantity in quantum dissipation theory is the reduced system density matrix. As the reduced system density matrix is an O(M! × M!) matrix, where M is the number of the particles of the system of interest, quantum dissipation theory can only be employed to simulate systems of a few particles or degrees of freedom. It is thus important to combine quantum chemistry and quantum dissipation theory so that realistic open quantum systems can be simulated from first-principles. We have developed a first-principles method to simulate the dynamics of open electronic systems, the time-dependent density functional theory for open systems (TDDFT-OS). Instead of the reduced system density matrix, the key quantity is the reduced single-electron density matrix, which is an N × N matrix where N is the number of the atomic bases of the system of interest. As the dimension of the key quantity is drastically reduced, the TDDFT-OS can thus be used to simulate the dynamics of realistic open electronic systems and efficient numerical algorithms have been developed. As an application, we apply the method to study how quantum interference develops in a molecular transistor in time domain. We include electron-phonon interaction in our simulation and show that quantum interference in the given system is robust against nuclear vibration not only in the steady state but also in the transient dynamics. As another application, by combining TDDFT-OS with Ehrenfest dynamics, we study current-induced dissociation of water molecules under scanning tunneling microscopy and follow its time dependent dynamics. Given the rapid development in ultrafast experiments with atomic resolution in recent years, time dependent simulation of open electronic systems will be useful to gain insight and understanding of such experiments. This Account will mainly focus on the practical aspects of the TDDFT-OS method, describing the numerical implementation and demonstrating the method with applications.

Estimation of physical parameters is essential in almost any part of science and technology. The enhancement of performance in this task (e.g. beating the standard classical shot-noise limit) using available physical resources is a major goal in metrology. Quantum metrology in closed systems has indicated that entanglement in such systems may be a useful resource. However, whether in open quantum systems such enhancements may still show up is not yet fully understood. Here, we consider a dissipative (open) quantum system of identical particles in which a parameter of the open dynamics itself is to be estimated. We employ a recently developed dissipative quantum metrology framework, and investigate whether the entanglement produced in the course of the dissipative dynamics may help the estimation task. Specifically, we show that, even in a Markovian dynamics in which states become less distinguishable in time, at small enough times the entanglement generated by the dynamics may offer some advantage over the classical shot-noise limit.

We analyze the dynamics of entanglement entropy in a generic quantum many-body open system from the perspective of quantum information and error corrections. We introduce a random unitary circuit model with intermittent projective measurements, in which the degree of information scrambling by the unitary and the rate of projective measurements are independently controlled. This model displays two stable phases, characterized by the volume-law and area-law scaling entanglement entropy in steady states. The transition between the two phases is understood from the point of view of quantum error correction: the chaotic unitary evolution protects quantum information from projective measurements that act as errors. A phase transition occurs when the rate of errors exceeds a threshold that depends on the degree of information scrambling. We confirm these results using numerical simulations and obtain the phase diagram of our model. Our work shows that information scrambling plays a crucial role in understanding the dynamics of entanglement in an open quantum system and relates the entanglement phase transition to changes in quantum channel capacity.

A longstanding tool to characterize the evolution of open Markovian quantum systems is the GKSL (Gorini-Kossakowski-Sudarshan-Lindblad) master equation. However, in some cases, open quantum systems can be effectively described with non-Hermitian Hamiltonians, which have attracted great interest in the last twenty years due to a number of unconventional properties, such as the appearance of exceptional points. Here, we present a short review of these two different approaches aiming in particular to highlight their relation and illustrate different ways of connecting non-Hermitian Hamiltonian to a GKSL master equation for the full density matrix.

Coherence and quantum correlations have been identified as fundamental resources for quantum information tasks. As recently shown, these resources can be interconverted. In multipartite systems, entanglement represents a prominent case among quantum correlations, one which can be activated from coherence. All this makes coherence a key resource for securing the operational advantage of quantum technologies. When dealing with open systems, decoherence hinders full exploitation of quantum resources. Here, we present a protocol that allows reaching the maximal achievable amount of coherence in an open quantum system. By implementing our protocol, or suitable variants of it, coherence losses might be fully compensated, thereby leading to coherence revivals. We provide an experimental proof of principle of our protocol through its implementation with an all-optical setup.

The idea of the out-of-time-order correlator (OTOC) has recently emerged in the study of both condensed matter systems and gravitational systems. It not only plays a key role in investigating the holographic duality between a strongly interacting quantum system and a gravitational system, it also diagnoses the chaotic behavior of many-body quantum systems and characterizes information scrambling. Based on OTOCs, three different concepts-quantum chaos, holographic duality, and information scrambling-are found to be intimately related to each other. Despite its theoretical importance, the experimental measurement of the OTOC is quite challenging, and thus far there is no experimental measurement of the OTOC for local operators. Here, we report the measurement of OTOCs of local operators for an Ising spin chain on a nuclear magnetic resonance quantum simulator. We observe that the OTOC behaves differently in the integrable and nonintegrable cases. Based on the recent discovered relationship between OTOCs and the growth of entanglement entropy in the many-body system, we extract the entanglement entropy from the measured OTOCs, which clearly shows that the information entropy oscillates in time for integrable models and scrambles for nonintgrable models. With the measured OTOCs, we also obtain the experimental result of the butterfly velocity, which measures the speed of correlation propagation. Our experiment paves a way for experimentally studying quantum chaos, holographic duality, and information scrambling in many-body quantum systems with quantum simulators.

The dynamical behavior of open quantum systems plays a key role in many applications of quantum mechanics, examples ranging from fundamental problems, such as the environment-induced decay of quantum coherence and relaxation in many-body systems, to applications in condensed matter theory, quantum transport, quantum chemistry and quantum information. In close analogy to a classical Markov process, the interaction of an open quantum system with a noisy environment is often modelled by a dynamical semigroup with a generator in Lindblad form, which describes a memoryless dynamics leading to an irreversible loss of characteristic quantum features. However, in many applications open systems exhibit pronounced memory effects and a revival of genuine quantum properties such as quantum coherence and correlations. Here, recent results on the rich non-Markovian quantum dynamics of open systems are discussed, paying particular attention to the rigorous mathematical definition, to the physical interpretation and classification, as well as to the quantification of memory effects. The general theory is illustrated by a series of examples. The analysis reveals that memory effects of the open system dynamics reflect characteristic features of the environment which opens a new perspective for applications, namely to exploit a small open system as a quantum probe signifying nontrivial features of the environment it is interacting with. This article further explores the various physical sources of non-Markovian quantum dynamics, such as structured spectral densities, nonlocal correlations between environmental degrees of freedom and correlations in the initial system-environment state, in addition to developing schemes for their local detection. Recent experiments on the detection, quantification and control of non-Markovian quantum dynamics are also discussed.

Quantum science and technology is a rapidly growing field that harnesses the unique properties of quantum mechanics. The manipulation of quantum systems has led to unprecedented development in secure quantum communication, simulation, computing, sensing and metrology. Despite the significance of these technologies, the existing literature lacks a comprehensive understanding of how they can address various challenges faced by Africa. We address this gap by using systematic literature review methods and draw insights from diverse perspectives to present an overview of the current state of quantum science and technology in Africa. Furthermore, we explore how the full adoption and implementation of quantum technologies can contribute to achieving the United Nations Sustainable Development Goals 1-4, 10, 13, and 17. We analyze the data from literature review and insights from African quantum experts, which we synthesize into a cohesive summary. This review underscores that, with appropriate efforts, quantum technologies can significantly promote social, economic, and environmental sustainability in Africa. This review goes beyond the present literature to offer a conceptual framework, theoretical insights and practical recommendations. This study is particularly timely, coinciding with the 2025 International Year of Quantum Science and Technology, which recognizes 100 years since the initial development of quantum mechanics.