Chapter 16 - Oxyhalides-based photocatalysts: the case of bismuth oxyhalides

Recent advances in enhanced photocatalytic activity of bismuth oxyhalides for efficient photocatalysis of organic pollutants in water: A review

Bismuth oxyhalides: Recent progress and its applications in photocatalysis, hydrogen production, antibacterial studies, and sensors

Photocatalysis has been considered as an environmental-friendly strategy for degradation of organic pollutants to the nontoxic products of H2O and CO2. Compared to metal oxide semiconductors, BiOX (X = Cl, Br and I) photocatalysts exhibit some advantages, such as, unique layered structure, good chemical stability and superior photocatalytic activity. This review provides an overview on the controllable synthesis of BiOX-based photocatalysts and their application in photodegradation of organic pollutants. Firstly, the controllable synthesis of BiOX is introduced, including hydrothermal, solvothermal, hydrolysis, precipitation, two-phase methods, ultrasonic/microwave-assisted methods, and physical methods. Then, the doping and surface modification of BiOX are summarized, including non-metal doping, metal doping, dual doping, and the modification by introducing surface terminations or carriers. In addition, the heterojunctions of BiOX/BiOY and BiOX/BimOnXz are introduced. At last, the promising research trends of BiOX-based photocatalysts are put forward. The main purpose is providing practical guidelines for developing high-performance BiOX photocatalysts.

Opening a tunable and sizable band gap in single-layer graphene (SLG) without degrading its structural integrity and carrier mobility is a significant challenge. Using density functional theory calculations, we show that the band gap of SLG can be opened to 0.16 eV (without an electric field) and 0.34 eV (with a strong electric field) when properly sandwiched between two hexagonal boron nitride single layers. The zero-field band gaps are increased by more than 50% when the many-body effects are included. The ab initio quantum transport simulation of a dual-gated field effect transistor (FET) made of such a sandwich structure reveals an electric-field-enhanced transport gap, and the on/off current ratio is increased by a factor of 8.0 compared with that of a pure SLG FET. The tunable and sizeable band gap and structural integrity render this sandwich structure a promising candidate for high-performance SLG FETs. Jing Lu and co-workers have revealed how to open up a tunable band gap in single-layer graphene, the one-atom-thick honeycomb carbon layer that has sparked much interest both in fundamental physics and in practical applications. Although graphene's excellent mechanical, thermal and electrical properties are very attractive, one major drawback is its lack of ‘band gap’ — the energy gap in the electronic structure of a material that enables to switch its conductivity on and off. Previous attempts to create such a gap in single-layer graphene have typically damaged its structure or conductivity. Through extensive calculations, the researchers have now examined the properties of single-layer graphene when sandwiched between two honeycomb boron nitride (BN) layers. They revealed that for a specific positioning of the layers, a sizable band gap can be opened and further tuned by applying an electric field without causing damage, making the sandwich structure a promising component for field-effect transistors. An electric field-enhanced transport gap is well established in a dual-gated field effect transistor (FET) based on the h-BN/single-layer graphene/h-BN sandwich structure, and the on/off current ratio is increased by a factor of 8.0 compared with pure single-layer graphene FET. The tunable and sizeable band gap and structural integrity render this sandwich structure a promising candidate for high-performance single-layer graphene FETs.

Recent advances in basic fabrication techniques of TiO2-based nanomaterials such as nanoparticles, nanowires, nanoplatelets, and both physical- and solution-based techniques have been adopted by various research groups around the world. Our research focus has been mainly on various deposition parameters used for fabricating nanostructured materials, including TiO2-organic/inorganic nanocomposite materials. Technically, TiO2 shows relatively high reactivity under ultraviolet light, the energy of which exceeds the band gap of TiO2. The development of photocatalysts exhibiting high reactivity under visible light allows the main part of the solar spectrum to be used. Visible light-activated TiO2 could be prepared by doping or sensitizing. As far as doping of TiO2 is concerned, in obtaining tailored material with improved properties, metal and nonmetal doping has been performed in the context of improved photoactivity. Nonmetal doping seems to be more promising than metal doping. TiO2 represents an effective photocatalyst for water and air purification and for self-cleaning surfaces. Additionally, it can be used as an antibacterial agent because of its strong oxidation activity and superhydrophilicity. Therefore, applications of TiO2 in terms of photocatalytic activities are discussed here. The basic mechanisms of the photoactivities of TiO2 and nanostructures are considered alongside band structure engineering and surface modification in nanostructured TiO2 in the context of doping. The article reviews the basic structural, optical, and electrical properties of TiO2, followed by detailed fabrication techniques of 0-, 1-, and quasi-2-dimensional TiO2 nanomaterials. Applications and future directions of nanostructured TiO2 are considered in the context of various photoinduced phenomena such as hydrogen production, electricity generation via dye-sensitized solar cells, photokilling and self-cleaning effect, photo-oxidation of organic pollutant, wastewater management, and organic synthesis.

A critical review on bismuth oxyhalide based photocatalysis for pharmaceutical active compounds degradation: Modifications, reactive sites, and challenges

Photocatalysis, a promising approach for addressing environmental and energy challenges, involves the acceleration of chemical reactions by light in the presence of a catalyst. Metal oxide-based nanomaterials, such as TiO2, ZnO, SnO2, and CuO, are among the most studied photocatalysts due to their unique electronic, optical, and chemical properties. This review presents a comprehensive exploration of metal oxide nanomaterials in photocatalytic applications, including their synthesis, characterization, and photocatalytic mechanisms. We discuss various synthesis methods—such as sol-gel, hydrothermal, chemical vapor deposition, and green synthesis—along with their advantages and limitations. The characterization techniques used to evaluate structural, optical, properties, and electrochemical including X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy (PL), and BET analysis, are also reviewed. The fundamental photocatalytic mechanisms, including charge generation, electron-hole pair separation, and surface reactions, are discussed in detail. Applications of metal oxide photocatalysts in environmental remediation (e.g., degradation of organic pollutants and wastewater treatment), energy production (e.g., water splitting for hydrogen generation), and CO2 reduction are highlighted, along with advancements in material modification such as doping, heterojunction formation, and composite materials. Despite the potential of metal oxide-based photocatalysts, challenges such as photo-corrosion, limited light absorption, and scalability remain significant. This review concludes by identifying future research directions to overcome these challenges and enhance the commercial applicability of metal oxide nanomaterials in sustainable energy and environmental solutions.

The synergistic effect of non-metal doping or defect engineering and interface coupling on the photocatalytic property of g-C3N4: First-principle investigations

Fluorine-doped TiO 2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde

Polycrystalline lead selenide prepared by an oxygen ion beam induction

Solar-light-driven ternary MgO/TiO2/g-C3N4 heterojunction photocatalyst with surface defects for dinitrobenzene pollutant reduction

Flexible photodetectors (PDs) have garnered increasing attention for their potential applications in diverse fields, including weather monitoring, smart robotics, smart textiles, electronic eyes, wearable biomedical monitoring devices, and so on. Notably, perovskite nanostructures have emerged as a promising material for flexible PDs due to their distinctive features, such as a large optical absorption coefficient, tunable band gap, extended photoluminescence decay time, high carrier mobility, low defect density, long exciton diffusion lengths, strong self-trapped effect, good mechanical flexibility, and facile synthesis methods. In this review, we first introduce various synthesis methods for perovskite nanostructures and elucidate their corresponding optical and electrical properties, encompassing quantum dots, nanocrystals, nanowires, nanobelts, nanosheets, single-crystal thin films, polycrystalline thin films, and nanostructured arrays. Furthermore, the working mechanism and key performance parameters of optoelectronic devices are summarized. The review also systematically compiles recent advancements in flexible PDs based on various nanostructured perovskites. Finally, we present the current challenges and prospects for the development of perovskite nanostructures-based flexible PDs.

Zinc oxide (ZnO) nanostructured materials have received significant attention because of their unique physicochemical and electronic properties. In particular, the functional properties of ZnO are strongly dependent on its morphology and defect structure, particularly for a semiconductor ZnO-based photocatalyst. Here, we demonstrate a simple strategy for simultaneous morphology control, defect engineering and photoactivity tuning of semiconductor ZnO by utilizing the unique surfactant properties of graphene oxide (GO) in a liquid phase. By varying the amount of GO added during the synthesis process, the morphology of ZnO gradually evolves from a one dimensional prismatic rod to a hexagonal tube-like architecture while GO is converted into reduced GO (RGO). In addition, the introduction of GO can create oxygen vacancies in the lattice of ZnO crystals. As a result, the absorption edge of the wide band gap semiconductor ZnO is effectively extended to the visible light region, which thus endows the RGO-ZnO nanocomposites with visible light photoactivity; in contrast, the bare ZnO nanorod is only UV light photoactive. The synergistic integration of the unique morphology and the presence of oxygen vacancies imparts the RGO-ZnO nanocomposite with remarkably enhanced visible light photoactivity as compared to bare ZnO and its counterpart featuring different structural morphologies and the absence of oxygen vacancies. Our promising results highlight the versatility of the 2D GO as a solution-processable macromolecular surfactant to fabricate RGO-semiconductor nanocomposites with tunable morphology, defect structure and photocatalytic performance in a system-materials-engineering way.

Enhanced electrochemical CO2 reduction to ethylene over CuO by synergistically tuning oxygen vacancies and metal doping

Influence of intrinsic defects on the electrical and optical properties of TiO2:Nb films sputtered at room temperature