Chemical Additives Migration in Rubber

Mechanical properties of the cuticle of Manduca sexta larvae treated with cyromazine

Degradation in mechanical and physical properties of carbon fiber/bismaleimide composite subjected to proton irradiation in a space environment

Aging, from 40 to +80 years old, causes geometrical and mechanical properties changes in the proximal femur. The subperiosteal width expands faster in men compared to women during aging, while the cortical thickness varies unequally in each sector and differently between men and women. Another change which occurs during aging is bone mechanical properties such as stiffness and ultimate strains. Numerical analysis allows us to study the potential effects of each of the age-dependent changes on the fracture forces separately and combined. We investigated the effects of the geometrical and bone mechanical properties changes due to aging on the femoral strength during a common falling scenario using a transverse isotropic continuum damage model. First, the femur model was adapted from a previously developed human body model named THUMS v4.02. Then, three sets of models were developed to address each of the changes separately and combined for both sexes. We found that the fracture forces in women are on average 1500 N less than in men of the same age. The age-dependent geometrical changes increased the fracture forces in men (25 N/decade), whereas it reduced the fracture forces by 116 N/decade in women. The mechanical properties changes reduced the fracture forces in men more than in women (354.5 N/ decade vs. 225.4 N/decade). When accounting for both geometrical and mechanical properties changes due to aging, the fracture forces decreased by 10.7% of the baseline in women per decade compared to 7.2% per decade in men.

Examining the feasibility of applying principal component analysis to detecting localized changes in mechanical properties

Investigations on Lanthanide polymers for radiation shielding purpose

There have been many studies (see for instance Reference 1) directed at quantifying the effects of ionizing radiation on polymers. Mainly these studies have focused on assessing the degradation of mechanical properties. In addition to changes in mechanical properties, a mixture of gases results from the irradiation of polymeric compounds. The amount of gas produced is related to the total absorbed dose while the type of gas is independent of dose and is related only to polymer structure. For many polymers, hydrogen is the major component in the gaseous mixture but polyesters and anhydride-cured epoxide resins are a notable exception.Some problems associated with radiation damage may be further complicated when the irradiation temperature is in the cryogenic range. When materials are irradiated at low temperatures (<150 K), the release of volatile degradation products is delayed and occurs—possibly very rapidly and exceeding normal diffusion rates—only when the polymer is warmed. The rapid release of gaseous degradation products could occur as a result of warming a superconducting magnet that has been resin bonded and irradiated at low temperatures during operation. Radiation damage-related problems may be summarized as follows: (1) changes in short-term mechanical properties, (2) production of gases and low-molecular-weight species, and (3) longer term and geometrical effects (unknown) of trapped gases on electrical and mechanical properties.This article considers mechanisms of radiation-induced damage and relates the chemical structure of the polymer to the rate of damage accumulation. Changes in electrical properties measured on irradiated polymers are generally small, and mechanical damage is generally more significant than changes in electrical characteristics. However all such reports are a result of electrical measurements on thin films and do not consider the effects of trapped gases on long-term electrical properties in bulk specimens.

Electric and mechanical detection of changes in heated apple flesh

Polymeric composite insulators consisting of core fiber reinforced polymer insulators covered with polydimethylsiloxane (PDMS) housing are now replacing conventional ceramic insulators especially for high-outdoor power transmission lines due to some specific advantages. Unlike ceramics, polymers have relatively shorter life. Outdoor insulators experience different electrical, mechanical, chemical, and thermal stresses during service. The long-term service performance of these insulators and their service life estimation is an important issue, but it is complicated and time-consuming. The objective of the present investigation is to check the rate of property deterioration during service and to find the approximate lifetime. Working insulators with different ages were collected from service, and the changes in mechanical and electrical properties and hydrophobicity of the PDMS cover against aging time were measured. The service life estimated from the change in mechanical properties and surface hydrophobicity (using MATLAB software) was compared with the service life of a new compound subjected to accelerated aging tests. Prediction of service life is helpful for replacement of aged insulators from service to avoid interruption in power transmission.

Matrix stiffening has been recognized as one of the key drivers of the progression of liver fibrosis. It has profound effects on various aspects of cell behavior such as cell function, differentiation, and motility. However, as these processes are not homogeneous throughout the whole organ, it has become increasingly important to understand changes in the mechanical properties of tissues on the cellular level. To be able to monitor the stiffening of collagen-rich areas within the liver lobes, this paper presents a protocol for measuring liver tissue elastic moduli with high spatial precision by atomic force microscopy (AFM). AFM is a sensitive method with the potential to characterize local mechanical properties, calculated as Young's (also referred to as elastic) modulus. AFM coupled with polarization microscopy can be used to specifically locate the areas of fibrosis development based on the birefringence of collagen fibers in tissues. Using the presented protocol, we characterized the stiffness of collagen-rich areas from fibrotic mouse livers and corresponding areas in the livers of control mice. A prominent increase in the stiffness of collagen-positive areas was observed with fibrosis development. The presented protocol allows for a highly reproducible method of AFM measurement, due to the use of mildly fixed liver tissue, that can be used to further the understanding of disease-initiated changes in local tissue mechanical properties and their effect on the fate of neighboring cells.

Perception of action capabilities can be altered by changes in sensorimotor processes, as showed in previous works in populations dealing with regular and pathological sensorimotor deficits. Misestimating changes in performance ability could lead to risky behavior, injury, and/or reduced performance. However, the relationship between sensorimotor processes, the action-perception coupling, and the related anatomical structures is still a matter of debate. We investigated whether changes in the muscle-tendon system's mechanical properties experimentally induced by eccentric contractions could alter the action-perception coupling (APC) in a reaching-to-grasp task, in which the participants estimated the maximal distance they predicted that they would able to reach a glass. Based on their repartition, volunteers performed a conditioning session the first day: a series of isokinetic elbow extension in passive condition (control group, n = 11) or when performing elbow flexors eccentric contractions (eccentric group, n = 11). Performance estimates and actual performances in a reaching-to-grasp task were completed before, and immediately, 24 hours and 48 hours after the conditioning session. Alterations of musculo-articular mechanical properties were assessed through global joint stiffness (joint passive torque through load/unload cycles) and local stiffness (muscle elastography). The results showed that the APC related to reaching-to-grasp performance was not impacted by post-exercise changes in mechanical properties of the musculo-articular system. These findings emphasize the central dimension of sensorimotor processing instead of peripheral structures to investigate the APC for an altered sensorimotor environment.

Osteocytes can remove and remodel small amounts of their surrounding bone matrix through osteocytic osteolysis, which results in increased volume occupied by lacunar and canalicular space (LCS). It is well established that cortical bone stiffness and strength are strongly and inversely correlated with vascular porosity, but whether changes in LCS volume caused by osteocytic osteolysis are large enough to affect bone mechanical properties is not known. In the current studies we tested the hypotheses that (1) lactation and postlactation recovery in mice alter the elastic modulus of bone tissue, and (2) such local changes in mechanical properties are related predominantly to alterations in lacunar and canalicular volume rather than bone matrix composition. Mechanical testing was performed using microindentation to measure modulus in regions containing solely osteocytes and no vascular porosity. Lactation caused a significant (∼13%) reduction in bone tissue-level elastic modulus (p < 0.001). After 1 week postweaning (recovery), bone modulus levels returned to control levels and did not change further after 4 weeks of recovery. LCS porosity tracked inversely with changes in cortical bone modulus. Lacunar and canalicular void space increased 7% and 15% with lactation, respectively (p < 0.05), then returned to control levels at 1 week after weaning. Neither bone mineralization (assessed by high-resolution backscattered scanning electron microscopy) nor mineral/matrix ratio or crystallinity (assessed by Raman microspectroscopy) changed with lactation. Thus, changes in bone mechanical properties induced by lactation and recovery appear to depend predominantly on changes in osteocyte LCS dimensions. Moreover, this study demonstrates that tissue-level cortical bone mechanical properties are rapidly and reversibly modulated by osteocytes in response to physiological challenge. These data point to a hitherto unappreciated role for osteocytes in modulating and maintaining local bone mechanical properties. © 2016 American Society for Bone and Mineral Research.

Changes in the mechanical properties and chemical structure of polystyrene by γ-irradiation

This study examines the changes in specimen color, surface morphology, chemical bonds, and mechanical properties of high-density polyethylene (HDPE) under the influence of aging factors such as ultraviolet light, ozone, temperature, and salt spray. The changes in mechanical properties over aging time is explained based on extensive experimental data and the findings are validated by constructing a finite element method (FEM) model. The fluctuations in mechanical properties are strongly dependent on the competition among scission, crosslinking, and rearrangement of molecular chains due to the breaking and forming of chemical bonds. The aging process is confined to the specimen surface, resulting in an aged layer hundreds of micrometers thick and slight changes in the overall mechanical properties of the specimen, as indicated by tensile test results and FEM simulations. This study will significantly contribute to understanding the aging mechanisms of HDPE and improving the durability analysis of its products.

Rubber is the indispensable raw material for the manufacture of tires; it is obtained from plants, trees and currently can be produced synthetically. The tire rubber is mixed with compounds such as carbon black, sulfur, cement, paints, antioxidants, oils and fats, steel wire, almost etc., making impossible to recycle the tires itself. In this work, we investigate, the effects of the incorporation of ground rubber in concrete, mixture designed to establish the possibility of being used in the construction industry. The samples of concrete were addition with, 5 vol. %., 15 vol. % and 25 vol. % of rubber. Samples with different rubber addition were irradiated by a cobalt 60 gamma source to study the effect on their mechanical compression properties and microwave absorption capacity. Likewise, the microwave absorption capacity was studied for both irradiated and the non-irradiated. It was found that between 5 vol. % and 15 vol. % of rubber addition change the mechanical properties approximately 25 %, higher rubber additions result in a decrease in a 75 % of its mechanical properties. The fracture behavior is not the expected one due to as the curves of stress vs. strain show a double slope, which is associated with the concrete porosity and rubber content. The aging with the gamma rays generates loss of mechanical properties, especially at lower rubber addition, since at content greater than 15 Vol % the radiation effect is less. These rubber additions allow moderate deformations in compression, thus contributing to the care and preservation of the environment.

Data relating to the degradative conversion of 14C present in low density polyethylene (LDPE) film to respiratory 14CO2 during a 10‐year aerated cultivation with soil are presented. The degradation was performed with two sets of LDPE samples, one without additive (PE) and the other containing UV sensitizer (NDPE). Samples were exposed to UV irradiation for 0, 7, 26, and 42 days. The degradation is characterized by three stages: (I) a constant degradation rate, (II) a parabolic decline in the rate of degradation, and (III) a subsequent final increase in the rate of degradation. The first step (I) is probably dependent on the environment. The material changes rapidly until some kind of equilibrium with the environment has been achieved. CO2 is evolved, oxygen uptake is rapid, and a rapid change in mechanical properties is also observed. The second step (II) is characterized by low oxygen uptake, a low evolution of CO2 and slow changes in the mechanical properties, crystallinity, and molecular weight. The changes in mechanical properties are not necessarily synchronous with the decrease in molecular weight. Step III, finally, is a rapid deterioration of the structure. The degradation rate increases again, and all the mechanical properties are more or less lost due to the final collapse of the structure. For an inert material such as PE, 10 years is a short time, so that only small indications of step III and a coming mineralization point can be observed. The changes are more evident for NDPE. The use of degradable materials, for example polypropiolactone, however, means that it is possible during a 2‐year period to study all three stages. An understanding of the mechanisms in each step will give a better base for lifetime predictions.