Constant Torque Mechanisms: A Survey

The origami mechanisms possess numerous unique advantages, including folding, reconfigurability, and multi-stability. The presence of multi-stability introduces a novel concept for the design of constant force mechanisms (CFM). In this study, we present a CFM with multi-segment constant-force regions by leveraging the multi-stable characteristics of the origami mechanism. The design principle behind this CFM involves combining an accordion origami structure with positive stiffness and a Kresling origami structure with multi-segment negative stiffness regions. To achieve zero stiffness, the Kresling origami structure is aligned parallel to the accordion origami. To effectively utilize both the Kresling and accordion origamis, we have established a mechanical model that describes their respective stiffness characteristics to establish design rules for the constant-force mechanism. By carefully designing the parameters of these two origami structures, we evaluate how variations in the structural parameters of Kresling influence the constant force properties of our proposed multi-segment CFM. To illustrate its inherent property of providing constant force across multiple segments, we employ finite element analysis and experiments to obtain force-displacement curves for our mechanism. The results demonstrate the feasibility of our presented design method which paves the way for constructing a simple CFM.

Design and modeling of constant-force mechanisms: A survey

Design and experimental verification of an adjustable constant-force mechanism

Constant force mechanisms maintain a near constant reactionary force over a sizable displacement range. Compliant constant force mechanisms gain some or all of their motion from flexing members as opposed to traditional rigid links with revolute (pin) joints. In this paper we focus on the development of constant force mechanisms for small scale electrical connectors. We address the problem of these mechanisms being sensitive to manufacturing uncertainties. This is an extension of work previously done to design a robust constant force electrical contact. In our previous work the computational intensity of the analysis limited the thoroughness of the robust optimization search. We now present a surrogate modeling approach that will allow us to more thoroughly explore the tolerance window of our design to ensure robustness. Our approach in this paper allows us to identify a design that is 93.61% constant with a standard deviation of 0.77%.

Design of an adjustable cam based constant force mechanism

Lithium-ion batteries (LIBs) are the major power sources for electronic and transportation applications due to their high specific energy, good cyclability and environmental friendliness. Intercalation compounds were commercially employed as the positive (cathode) electrode material. However, they have a limited capacity, which are not likely to meet the growing demand on specific energy and energy/power density. Transition-metal oxides, fluorides and oxyfluorides have attracted a lot of interest due to their ability to deliver high electrochemical specific energy arising from 2-3 electrons transferred. FeOF was proposed as a promising candidate1 because it has a high theoretical specific capacity, 885 mAh/g (3-electron process) and 590 mAh/g (2-electron process), leading to an exceptionally high specific energy of 1328 Wh/kg. However, the electrochemical performance of FeOF is drastically different in practice due to its low electronic conductivity and poor structure stability during charge/discharge cycling process. To overcome these obstacles, conducting carbon matrices have been introduced to absorb the volume changes and to improve the structural stability of the electrodes. Graphene, a single−layer of sp2 carbon lattices, has been considered as one of the most attractive carbon materials for its excellent charge carrier mobility, mechanical robustness and thermal and chemical stability2. Our approach is to prepare a mixture of precursor of FeOF and graphene oxide in solution and to ensure a better bonding between FeOF and GO through a hydrothermal procedure. The resulted hybrid material showed much improved initial columbic efficiency and cyclability compared with the blank FeOF material. The initial specific capacity reached 621 mAh/g (Fig. 1) and the capacity retention was 78.9% (specific capacity 493 mAh/g) after 100 cycles at 0.1 C rate. It has been demonstrated that the performance improvement could be attributed to introduction of graphene which improved the electric conductivity and provide a substrate to stablize the FeOF particles by morphology observation and structure characterization. SEM (Fig. 2) and TEM were employed to observe the morphology change after introducing graphene. The structure evolution during charge/discharge process were also characterized by in situ XAS and high resolution XRD. The results showed that the graphene nano-sheets serve as substrates to stabilize the structure of FeOF and form a framework to stabilize the Fe clusters through bonding them to their original sites without migration. Thus, the FeOF/Graphene composite can keep the (de)lithiation reaction reversible during discharge and charge process. Figure 1

This paper presents the design, simulation, and testing of a compliant gripper that can provide a constant gripping force to handle objects of various sizes. Maintaining a proper gripping force is challenging when manipulating delicate objects with uncertain sizes and stiffnesses. To avoid damage and provide a stable grip of an object, force feedback is often required so that the gripping force can be directly or indirectly regulated. Without using additional sensors and control, the proposed gripper passively maintains a constant prespecified contact force between fingertip and object. The gripper is designed to have a constant input force generated by a constant-force mechanism (CFM). Transmitted through a statically balanced (SB) mechanism, a constant gripping force is obtained at the fingertip. After a formulation to find the optimal gripper configuration, the design is verified through comparison with simulation results. Finally, a prototype of the constant-force gripper is demonstrated. The novel gripper is expected to serve as a reliable alternative for object manipulation.

Electrical vehicles (EVs) have enjoyed extensive focus this decade as next-generation vehicles. However, high specific energy, high power density and low-cost batteries are essential for EVs to replace vehicles with internal combustion engines. Here, we propose a novel high specific energy and power density rechargeable aqueous lithium battery with an aqueous SnCl2 cathode and a lithium metal anode, where the lithium anode and the aqueous cathode are separated by a water-stable high lithium-ion conductivity solid electrolyte of Li1.4Al0.4Ge0.2Ti1.4(PO4)3. The theoretical specific energy density of this battery was 681 Wh kg−1, which is around 1.8 times higher than that of conventional lithium-ion batteries. The cell was successfully cycled at 1.5 mA cm−2 and 25°C for a specific areal capacity of 15 mAh cm−2.

The World's energy consumption has increased drastically over the past several decades, particularly driven by increasing population and economic activities as well as rising living standards with technological advancements. Since the industrial revolution, fossil fuels have been the major source of energy productions, which is today shown as the primary cause of the ongoing climate change and associated environmental challenges in threatening the existence of many living species and human life and comfort. According to the statistics provided by International Energy Agency (IEA),1 the global energy supply was 14 282 Mtoe in 2018 that is 115% higher than that of the value for 1973. Fossil fuels, such as natural gas, coal and oil are still playing a critical role and covering more than 80% of global energy demands. The concerns associated with global warming and depletion of energy sources have been directing the attention to renewable and environmentally-benign energy solutions. However, efficient, affordable, and nature-friendly energy storage systems are the key to using renewable energy sources effectively. In this study, a comprehensive literature search is conducted to study and bibliografically evalute Canada's energy storage research and development activities over the last five decades. The present study intends to present the cumulative picture on energy storage reseach and development efforts and assess how universities, research institutes and funding agencies have contributed to this particular field. The literature search compiles a total of fifty-year data on energy storage-related research and development activities conducted in Canada. The number of conducted studies associated with energy storage regarding research articles, books, research projects, dissertations, and patents is presented in the period from 1971 to 2021. Furthermore, the Canadian institutes are ranked based on their scholarly ouputs and publications to indicate the most productive ones in the field of energy storage based on the data presented in the literature sources. Energy storage is described as the capture of harvested energy for later use to maintain the balance fluctuations between energy demand and supply. As the world moves towards a low-carbon economy, energy storage systems are exepcted to even play a more critical role in extracting more energy from renewable resources.10 The intermittent characteristic of renewable resources, specifically solar and wind, is one of the major challenges ahead of a reliable and steady renewable energy supply. This can be avoided by storing excess energy to re-use when the renewable resources are not sufficient or unavailable. Energy storage systems can be categorized in different ways in regards to the form of converted and stored energy. Figure 1 presents an overview of energy storage system categories which are considered in this study. It is important to note that chemical energy storage allows to storage and transportation of large amounts of energy for long distances with minimal self-discharge rates, which is crucial for the distribution and effective use of renewable energy resources. Figure 2 presents the energy density of various chemical fuels and batteries. Despite possessing high energy density, environmental concerns associated with the production and consumption of fossil-based chemical fuels, e.g. diesel, gasoline or natural gas, should be adrressed. In regards to nature-friendly chemical energy storage, particularly power-to-gas chemical storage, hydrogen is attracting favorable attention nowadays. In this regard, hydrogen appears to be the lightest and most abundant chemical element in the universe, but is not available freely (by itself). However, it occurs naturally within a compound such as water (H2O); therefore, it is an intermediate energy form. Excess electricity from renewables can be utilized in hydrogen production processes, i.e. electrolysis of water, to store energy in chemical form. Power-to-hydrogen chemical energy storage is a unique and clean method, and it can be compatible with electrochemical storage since hydrogen possesses much greater energy content. One of the major challenges with hydrogen is the low calorific value per unit of volume (MJ/m3) due to its low density. This can be avoided by deploying alternative hydrogen carriers, such as ammonia. Liquefaction at atmospheric conditions, high hydrogen atom content and high energy density characteristics make ammonia a favorable medium for storage and transportation of energy. It is further to note that batteries and capacitors are devices allowing electrochemical storage of electricity. The potential energy is stored in chemical form in batteries, while capacitors are expected to store their potential energy in the form of an electric field.14 Batteries are thus most commonly used and matured options that propose high energy densities and voltages. Lithium-ion (Li-ion), sodium-sulphur (NaS), nickel-cadmium (NiCd), lead acid (Pb-acid), lead-carbon batteries, zebra batteries (Na-NiCl2) and flow batteries are the existing battery types used in various applications. Due to their high specific energy (per unit weight) and high specific energy (per unit volume), lithium batteries attract considerable attention in electrical energy storage. Capacitors can be classified as electrostatic capacitors, electrolytic capacitors, and electrochemical capacitors, among which electrochemical, so-called supercapacitors, promote the highest capacitance per unit of volume owing to a porous structure 15. As a mechanical energy storage method, pumped hydro accounts for more than 95% of the global installed energy storage capacity.15 The main advantage of mechanical energy storage is to readily deliver energy. The method is easy to adapt for conversion and storage of energy from various sourcessuch as water current, wave, or tidal. Pumped hydro, compressed air, and flywheel are the commonly practiced mechanical energy storage methods. Pumped hydro and compressed air are bound to specific geographical characteristics, which is the main restriction for the implementation of these energy storage methods. A flywheel stores the energy obtained from a rotor mass spinning at very high speeds as kinetic energy. The stored kinetic energy can be later used to produce electricity by altering the angular velocity of the flywheel through a decelerating torque and using an electric motor in reverse 16. Despite of being non-suitable for long-term energy storage, flywheels offer favorable advantages, that is, long-life spin, high energy densities and low maintenance costs, and fast charging.17 Thermal energy storage (TES) systems are effective systems to store heat in a reservoir for a period of time (defined or undefined) for later use, that is, space heating and cooling, electricity production, hot water. If the reservoir temperature is kept under the atmospheric temperature, the storage process is called cold thermal energy storage.18 Operating temperature range, capacity requirements, charging and discharging requirements are some of important parameters when choosing an appropriate TES system for a desired application. Since the major proportion of produced and consumed energy is heat around the world, TES systems carries a significant weight regarding the development of effective energy systems . Furthermore, energy losses from the systems commonly occur in the form of heat. Decreasing losses via further utilizing from waste energy is one of many way to mitigate environmental impacts, which can be accomplished by implementing TES systems in a cost effective manner. In the current study, an overview of Canada's energy storage related studies from 1971 to 2021 is presented. The scope of this study is to present the contributions of Canadian universities, research institutes and funders to energy storage research and development efforts over the last five decades. The keywords and methodology that are used for the literature search are depicted in Figure 3. The collected and compiled data for the corresponding fields are presented in figures, and results are discussed in the following sections. In this study, an online literature search is conducted on Canada's energy storage related studies over the last five decades. The current section presents collected and compiled data in charts. The findings of the conducted study are discussed in detail. The most productive institutes of Canada regarding conducting or sponsoring energy storage-related studies are presented. The documents associated with energy storage in all subject areas are presented in Figure 4. In this regard, the highest number of energy storage-related studies were conducted in the subject area of engineering in Canada from 1971 to 2021. The fields of energy and chemistry appear as the other two major subject areas in which high number of energy storage research was conducted. While compiling data, attention has been paid to any potential field conflicts concerning the multi attribution of interdisciplinary publications. Therefore, it should be noticed that chemistry may have an impact on the subject areas of biochemistry, genetics, and molecular biology. The same impact of engineering could be seen on the subject area of energy. The data collected and analysed for comparative evaluation reveals that the Canadian institutes have produced 37 386 energy storage-related academic research publications over the last 50-year period. In this regard, Figure 5A presents the breakdown of energy storage-related publications affiliated to Canada in the corresponding material types in accordance with the publication years. Figure 5A shows that studies in this field consistently increases every year. Consequently, the year 2020 appears as the most productive one in this regard as of April 2021. In the light of this trendline, predicting that the year 2021 will be more productive than 2020 would not be wrong. Figure 5B has been prepared as a heat map to show Canada's provinces where energy storage-related studies were conducted over the last 50 years. In this regard, Ontario appears as the most productive province of Canada in terms of scholarly publications. However, one has to keep in mind that Ontario has the highest number of contributing institutes/universities compared to the rest of the provinces in Canada. Figure 6 presents the breakdown of the number of energy storage-related books, book chapters, and editorials in accordance with publication years in Canada. The year 2018 was the most productive year of Canada by producing 200 documents in the corresponding classification. The other important point that should be pinned in the figure is the year 2005. Compared to the previous year, almost five times more energy storage-related books were published in 2005. Compared to 2019, the number of published books decreased almost by half in 2020. The impact of COVID-19 is recognized as one of numerous reasons behind this result. The number of energy storage-related dissertations completed in Canada over the last five decades is primarily searched through and collected from Library and Archives Canada. The search results are, in this regard, presented in Figure 7. It can be noted that the data presented in Figure 7 is based on the number of energy storage-related theses available in the library; and thus, the results are subject to change in accordance with instantaneous new data entry to the library. As of April 2021, there are 626 energy storage-related MSc and PhD theses/dissertations entered in the online system of Library and Archives Canada. The highest number of theses/dissertations was recorded in the year of 2013 with a value of 62. Based on data collected from the website of Canadian Intellectual Property Office, the number of energy storage-related patents of Canada is 11 719 for the last 50 years. The corresponding results are presented Figure 8. According to this, the year of 2018 appeared to be the Canada's most productive year in terms of patents registered under the title of energy storage. Canada is blessed with institutions that have been supporting energy storage-related research and developments by providing funds. Over the evaluated period of 50 years, the Natural Sciences and Engineering Research Council of Canada (NSERC) appears as the major funding agency for Canada's energy storage related research, development, partnership, strategic innovation and commercialization efforts and has supported more than 8500 projects in the field of energy storage. A total number of projects that have been funded by Canadian institutes have become 18021 from 1971 to 2021. It is most likely to observe a major increase in the number of projects by the impact of the recent hydrogen strategic plan of Canada. Being an excellent energy storage medium is one of many advantages of hydrogen. Therefore, there is a significant correlation in between hydrogen and energy storage research efforts. The subject matter report is already named as call-to-action for green hydrogen transition for the energy sector. In the report, the importance of dedicating more domestic resources to green hydrogen efforts to achieve the targets by 2050 is emphasized clearly (Figure 9). The development and implementation efforts of effective, affordable, and nature-friendly energy storage systems are recognized as a key requirement in achieving a green energy transition. In this regard, Canada intends to be the country leading and inspiring many others. Figure 10 shows the a number of Canadian institutes/universities that have produced more than 100 scholarly publications on energy storage under the subject area of energy. According to this, the total number of such scholarly publications has been 9125 over the past five decades. The results clearly show that there are two universities, such as University of Waterloo with 809 publications and Ontario Tech. University (formerly University of Ontario Institute of Technology) with 697 publications, leading in this particular area. University of Waterloo appears as the most productive Canadian university with a total number of 809 publications while Ontario Tech. University, which is one of the Canada's youngest universities, follows with a total number of 697 publications. The specific affiliations in the publications show that the researchers working in the productive environment of Clean Energy Research Laboratory (CERL) at Ontario Tech. have played a major role in this achievement. The data that support the findings of this study are available in Scopus, Library and Archives Canada and Canadian Intellectual Property Office with the reference number of [17], [18], and [19], respectively. These data were derived from the following resources available in the public domain: https://www.scopus.com/search/form.uri?display=basic&zone=header&origin, https://www.bac-lac.gc.ca/eng/services/theses/Pages/search.aspx, https://www.ic.gc.ca/opic-cipo/cpd/eng/search/basic.html?wt_src=cipo-patent-main.

Lithium-ion (Li-ion) batteries are still the best technology to power the Electric Vehicle (EV), due to their high power and energy density. However, the use of these batteries can be limited in cars with a high demand for peak power and very high energy density. One way to improve the performance of the Li-ion battery and reduce its weight is to associate this battery with another technology of higher specific energy as a second energy source, e.g. Lithium-sulfur (Li-S). The development of Hybrid Energy Storage Systems (HESSs) is a promising solution optimizing the energy management of EVs. In this paper, we present experimental results obtained with a high specific energy and power capability HESS prototype, composed of i) a Lithium-Titanate-Oxide battery to ensure high power capabilities, ii) a Li-S battery to improve specific energy, and iii) a power converter based on Gallium Nitride (GaN) devices to link both battery modules, minimizing at the same time system weight, volume and power losses. The developed GaN-based power converter achieves high efficiency (96.5%) operating at 300 kHz with a reduced size (0.4 L). Besides, the behavior of the developed HESS prototype is experimentally evaluated under standard automotive profiles, for different driving scenarios. The HESS prototype achieves an increase of energy density and specific energy of +5.56% and +28.21%, respectively, compared to a battery system composed only of Li-ion cells. The limitation of the developed system for automotive application are highlighted, and the critical research needs are clearly identified to accelerate the implementation of such systems on commercial EV solutions.

Boosting the electrochemical performance and reliability of conducting polymer microelectrode via intermediate graphene for on-chip asymmetric micro-supercapacitor

Titanium alloys were synthesized and coated with oxide dielectric films using anodizing in electrolytic baths. They possess high specific energies based on high charge-densities and high breakdown-electric-fields. These were made into alloy ribbons by rapid solidification by vacuum-spin casting, then anodized to form homogeneous dielectric films that serve as the medium in which electric charges are stored with high specific energy density in electrolytic capacitors. The new energy-dense dielectrics were formed by anodizing homogeneous Ti-Zr-X anode alloys, where X is a combination of Hf, Nb, Mo, Be, and/or Si. Thus homogeneous, dense and essentially-defect-free oxide-glass films were formed, e.g., (Ti-Zr-Hf-Be)O2 films with high specific energy with stability over a wide voltage range, up to over 300 Volt, at temperatures from cryogenic to over 100 degrees C. When packaged with oxidizing electrolyte the dielectric is self-repairing in the event that accidental defects spring up. This provides reliable high-energy and high power performance with little de-rating, i.e., high reliability and lifetime in pulsed or high-frequency operating conditions.

For widespread adoption of electric vehicles, lithium-ion batteries need to achieve energy densities of around 350 Wh/kg, cost less than $100/Wh, and be able to charge quickly within 15 minutes. The production of most inactive materials within modern Li-ion cells (e.g. separator, current collector, packaging) have already undergone tremendous optimization but many opportunities remain for improving the performance of the electrodes and reducing the cost and time of wetting, formation and aging processes. By increasing the thickness of electrodes clear opportunities exist for enhancing the energy densities of conventional cell materials and reducing cost. For example, doubling the thickness of electrodes in full cells from 50 μm to 100 μm can increase the energy density of the cell by about 16% and reduce the cost of the cell by 50% (from $249/kWh to $172/kWh)1. These benefits arise from increasing the ratio of electrode active material to inactive material within cells; however, increased thickness is often accompanied by reduced rate performance and increasingly difficult electrolyte wetting and formation processes due to the challenge of infiltrating the electrode pore structure with electrolyte and displacing gases during formation2. One emerging electrode processing technology involves the laser-ablation of small micro pores or channels into Li-ion battery electrodes to enhance their electrolyte wetting and rate performance. Pulsed lasers are increasingly being used in advanced manufacturing processes due to their ability to weld, sinter, or remove materials quickly and with very high precision. When applied to high energy density thick electrodes, micro-structuring by laser patterning has been shown to improve the rate capabilities of cells while maintaining high capacity retention3. These laser ablated pores or channels provide low tortuosity paths for lithium ions to reach deeper regions in the thick electrodes more quickly than before, limiting concentration gradients and thus reducing unwanted lithium plating at elevated rates. Despite these benefits, the utilization of ultrafast lasing ablation systems as an in-line technique to selectively remove patterned regions of active material from lithium-ion battery electrodes during production has not yet been widely adopted by the industry. In this work, we identify and manufacture laser-ablated 3D electrode architectures for enhanced Li+ transport and electrochemical performance with the hope of inspiring confidence in the benefits, practicality and cost effectiveness of the laser patterning technique. Preliminary modelling work at NREL has explored the limitations of planar electrodes for fast charge performance and the importance of microscale features for improving ion-transport4-8. With the correct pore/channel geometry, the energy density of ablated electrodes can be significantly improved compared to traditional architectures. We have combined simulation models and experimental data to optimize the 3-D laser patterning of our electrodes. Modelling elucidated the electrodes baseline transport limitations and quickly identified the most promising electrode architectures for favorable cost, energy- and power-density. Next, we used our benchtop ultrafast femtosecond laser ablation system to pattern our thick (ca. 100 µm) electrodes. After processing, the electrodes were inspected using cross-section scanning electron microscopy (SEM) so that ablation parameters such as laser wavelength, power and repetition rate could be optimized and distributions of feature sizes could be identified giving insight into the limitations of the laser system. We observed that the anode and cathode materials responded significantly different to the laser ablation process and that this must be considered during electrode preparation. Next, scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and x-ray diffraction (XRD) were used to probe for local chemical or structural changes in the electrodes’ with patterning to determine if the remaining active materials experienced permanent laser-induced damages. Once successful achievement of the target electrode architecture was confirmed, the benefits of the achieved 3-D patterning were investigated by cycling the electrodes in full cell coin cells and comparing their performance against standard cells with unmodified electrodes (benchmark). Cycling data clearly shows improved rate performance and capacity retention derived from the patterning of the thick graphite and NMC electrodes. Direct structuring of the electrodes has improved their ion transport and reduced lithium concentration gradients (cell polarization) resulting in high specific energy- and high power-density. While clear evidence of rapid lithium plating was observed in the standard benchmark cells at rates exceeding 1C, this has been largely mitigated in the laser ablated electrodes. Lastly, we probed the wetting of these electrodes with electrochemical impedance spectroscopy to map in real time the improved rate and extent of wetting achieved through the adoption of our 3-D laser patterns. Achieving shorter wetting times will correspond to reductions in cell manufacturing costs and is expected to present a significant market advantage. Figure 1

Impacts of lean electrolyte on cycle life for rechargeable Li metal batteries

We have been successfully using Li-ion batteries in several NASA missions since 2000, including the Mars Exploration Rovers (Spirit and Opportunity), Mars Science Laboratory (MSL), Phoenix Lander, JUNO, Aquarius, Keppler Rovers and SMAP. Being compact, lightweight and durable, these batteries have contributed to a significant enhancement or even enablement of these missions. However, NASA’s future missions, e.g., Astronaut’s Portable Life Support System (PLSS) for Extra-Vehicular Activities (EVA), small planetary rovers, planetary probes, CubeSats etc., require more advanced battery technologies with higher energy densities. The lithium-sulfur system emerges as the most promising technology, because of its high theoretical specific energy (3-4x) compared to Li-ion cells. However, despite many significant developmental efforts over the last few years, Li-S technology hasn’t matured yet, mainly due to the challenges from the soluble polysulfides forming a redox shuttle and also poisoning the lithium anode. Several attempts are being reported in the literature to develop novel cathode designs, e.g., hierarchical porous carbon structures to sequester sulfur and its reduction products, and also electrolyte solutions to minimize their solubility. 1-5 Good cycle life was reported in some of these cases with nanostructured sulfur cathodes in both organic electrolytes containing suitable additives (LiNO3) and in ionic liquids, but the sulfur loadings are much lower (below 4 mg/cm2), while high loadings of >12 mg/cm2 are essential for high specific energy Li-S cells. In this context, we have developed new sulfur composite cathodes blended with transition metal sulfides (e.g., titanium and molybdenum disulfide), which not only provided adequate electronic and ionic conductivity, but also facile electrochemical activity at sulfur reduction potentials to function as redox mediators.6 With such blended cathodes, we have been able to realize high specific capacities of ≥800 mAh/g at C/3 rates with high material loadings. In this paper, we will describe the performance of these composite sulfur cathodes in different electrolytes, and also in conjunction with a polymer-protected Li anode. Y. Yin, S. Xin, Y. Guo and L. Wan, Angew. Chem. Int. Ed. 2013, 52, 13186 (2013).S. Evers, L. F. Nazar, Acc. Chem. Res., 46, 1135 (2013);X. Ji, K. T. Lee, L. F. Nazar, Nat. Mater. 8, 500 (2009).A. Manthiram, S.-H. Chung, C. Zu, Adv. Mater. 27, 1980 (2015).S. S. Zhang, Front. Energy Res. 1, 1 (2013).Ratnakumar Bugga, Simon Jones, Jasmina Pasalic, Dan Addison and Ramanathan Thillaiyan, 228th ECS Meeting, Phoenix, AZ, Oct. 11 (2015)