Further Developments on a Characteristic Time Model for NOx Emissions from Diesel Engines

<div class="section abstract"><div class="htmlview paragraph">Increasing concerns due to global warming have led to stringent regulation of greenhouse gas (GHG) emissions from diesel engines. Specifically, for GHG phase-2 regulation (2027), more than 4% improvement is needed when compared to phase-1 regulation (2017) in the light heavy-duty (LHD) diesel engine category. At the same time, California Air Resources Board (CARB) and Environmental Protection Agency (EPA) have proposed the new Low NOx standards that require up to 90% reduction in tailpipe (TP) NOx emissions in comparison to the current TP NOx standards that were implemented in 2010. In addition, CARB and EPA have proposed new certification requirements – Low Load Cycle (LLC) and revised heavy-duty in-use testing (HDIUT) based on the moving average window (MAW) method that would require rigorous thermal management. Hence, strategies for simultaneous reduction in GHG and TP NOx emissions are required to meet future regulations.</div><div class="htmlview paragraph">This paper presents potential pathways to achieve the GHG phase-2 and the ultra-low NOx (ULN) regulations with minimum changes in engine design, while meeting the constraints that need to be considered for engine performance stability, component durability, and vehicle drivability. Experimental evaluations were performed focusing on transient cycles such as heavy-duty Federal Test Procedure (hereafter referred as FTP), LLC, and custom transient cycles for HDIUT assessment. We used a model-year (MY) 2021 production Isuzu diesel engine and an advanced dual-dosing aftertreatment system comprising of a close-coupled SCR (ccSCR), diesel oxidation catalyst (DOC), diesel particulate filter (DPF), selective catalytic reduction (SCR), and Ammonia Slip Catalyst (ASC). Conventional thermal management techniques such as multi-injection, intake, and exhaust throttling were implemented to achieve the emissions targets. In addition to the proposed system design, this paper presents following test results from a full-scale system evaluation: <ol class="list nostyle"><li class="list-item"><span class="li-label">1</span><div class="htmlview paragraph">Achieve rapid and sustained turbine-out exhaust temperatures (>200°C) while meeting the engine-out emissions constraints for soot and total hydrocarbon (THC) emissions.</div></li><li class="list-item"><span class="li-label">2</span><div class="htmlview paragraph">A summary of TP NOx, TP N2O and GHG emissions over a composite FTP and LLC.</div></li><li class="list-item"><span class="li-label">3</span><div class="htmlview paragraph">HDIUT assessment results and observations for LLC and custom transient cycles.</div></li><li class="list-item"><span class="li-label">4</span><div class="htmlview paragraph">Robustness evaluation of TP NOx emissions for composite HDT, LLC and custom transient cycles by imposing component variations.</div></li></ol></div></div>

<div class="htmlview paragraph">A chemical and physical characterization of particulate emitted in undiluted exhaust of single cylinder direct injection (D.I.) diesel engine was made by an optical technique.</div> <div class="htmlview paragraph">On-line scattering and extinction measurements in the spectral range from 200 to 500nm were carried out in the exhaust ofthe engine operating under steady-state conditions. These measurements provided a useful tool for the comprehension of chemical and physical structure of the particulate. They allowed the evaluation in real time of the size, the concentration and also the optical properties. Preliminary results of size and mass concentration of particulate are presented.</div> <div class="htmlview paragraph">A good agreement was observed comparing the results with those obtained by gravimetric measurements, TEM and X-ray diffraction.</div> <div class="htmlview paragraph"><b>HIGH EFFICENCY OF DIESEL ENGINES</b> and their ability to burn heavy fuels make them ofgreat interest in the transportation field. On the other hand, present exhaust emission levels produced by this type ofengine will not satisfy stringent international regulations on environ- menta protection.</div> <div class="htmlview paragraph">The studies of the chemical and physical structure of diesel particulate in the exhaust of the engine help manufacturers both to optimize the efficiency of the combustion process and give useful information to designers of after-treatment devices.</div> <div class="htmlview paragraph">Historically, most studies on the particulate in the engine exhaust were carried out by electron microscopy and chemical analysis [<span class="xref">1</span>,<span class="xref">2</span>]<span class="xref">*</span>. These conventional techniques are time consuming, not real time, and not useful in transient operating conditions. Because the composition of the particulate materia depends on the collection system the data can be influenced by sampling procedures.</div> <div class="htmlview paragraph">Size distribution measurementtechniques of particulate based on electrical mobility, diffusion and inertial separation were proposed by Dolanetal.[<span class="xref">3</span>]. These techniques are real time but intrusive and can change the size distribution through collisions between particles.</div> <div class="htmlview paragraph">The recent advances in non-intrusive optical diagnostic techniques have made it possible to study on-line the evolution of particulate emitted in the exhaust with good temporal and spatial resolution.</div> <div class="htmlview paragraph">In the last decade, the optical measurements carried out in the exhaust, were made by nephetometry, transmissiometryor opacimetry, generally at a single wavelength in the visible range or in the infrared by photoacoustic and absorption measurements, These measurements are used to determine both the mass of particulate and the amount of dry soot and SOF [<span class="xref">4</span>,<span class="xref">5</span>,<span class="xref">6</span>,<span class="xref">7</span>.]</div> <div class="htmlview paragraph">In particular, simultaneous light scattering and extinction measurements at a single wavelength in the visible have provided a fast method to determine the dimension and concentration of soot particles i n flame [<span class="xref">8</span>].</div> <div class="htmlview paragraph">The purpose of the present study is to demonstrate the feasibility and flexibility of a new optical technique applied in the undiluted exhaustof a D.I. diesel engine. The technique consists of the use of simultaneous spectral measurements of scattering and extinction coefficients from the near ultraviolet to visible. These measurements allow the on-line simultaneous evaluation of the size, concentration and particulate mass as well as estimating the optical properties of the particulate. In particular, optical measurements in the near ultraviolet region are particularly promising because both graphite and large aro- maticmolecules exhibit absorption bands between 200 and 350nm [<span class="xref">9</span>,<span class="xref">10</span>].</div>

<div class="section abstract"><div class="htmlview paragraph">Diesel aftertreatment (AT) systems are critical for controlling emissions of CO, HC, NO<sub>X</sub>, and PM in the on-road transportation sector. Ensuring compliance with regulatory standards throughout the AT system's lifespan requires precise prediction of various degradation mechanisms under real-world operating conditions and mitigating their impact through proper catalyst sizing and advanced controls. In the SwRI A2CAT-II consortium, a medium-duty diesel engine production aftertreatment system was subjected to full useful life aging, involving chemical poisoning with phosphorus (P) and sulfur (S) species, along with hydrothermal aging following the DAAAC protocol. This study was aimed to model and predict the aging trajectory of this production AT system thereby capturing changes in system dynamics under both steady-state and transient conditions. The system, designed to meet the 0.2 g/bhp-hr standard, comprised a Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and Ammonia Slip Catalyst (ASC). It was aged to 3600 hours equivalent to the DAAAC protocol and tested across a series of steady-state and regulatory cycles (HFTP, RMC, and LLC) at degreened, 33%, 66%, and 100% aging points. A linear decrease in system NOx conversion was observed between 0% to 66% aging, followed by a nonlinear drop from 66% to 100%. The cumulative decline in NOx conversion was 0.8%, which could significantly impact systems designed to meet a 0.05 g/bhp-hr target.</div><div class="htmlview paragraph">IntroductionAftertreatment durability demonstration is a mandatory validation exercise for on-road medium and heavy-duty diesel engine certification. This requirement ensures that the emission compliance can be achieved for the intended full useful life (FUL) of the engine system or multiple vehicle families. Conventional Deterioration Factor (DF) approach considers linear effect of sulfur and phosphorous poisoning on the catalysts over the entire useful life based on performance from 33% of aging the catalysts and extrapolating them to FUL. However, based on various studies, the impact of fuel derived Sulfur on diesel aftertreatment components was found to be exponentially significant particularly on the SCR due to the sulfur poisoning effect which require an active means to liberate sulfur to maintain appropriate SCR NOx conversion performance. Phosphorous from lubricating oil is known to adversely affect the activity of the oxidation catalyst in a catalyzed DPF thereby reducing the passive regenerative performance of DPF. For these reasons, an extensive understanding of chemical poisoning (particularly Sulfur and Phosphoros) and hydrothermal aging are warranted to design, validate and demonstrate the durability of aftertreatment components that are subjected to the prolonged chemical exposure.</div><div class="htmlview paragraph">To address the extensive challenges in durability demonstration, the Diesel Aftertreatment Accelerated Aging Protocol, or DAAAC, was developed by Southwest Research Institute as a part of consortium effort that includes input from diesel engine manufacturers [<span class="xref">1</span>, <span class="xref">2</span>, <span class="xref">3</span>]. DAAAC is an accelerated aging cycle developed for each application based on the available field data. It includes the exposure from hydrothermal aging, sulfur and lubricant derived poison at accelerated rates. The protocol also requires the entire aftertreatment system to be aged as a complete system, since the upstream components, such as DOC, can impact the chemical makeup of sulfur derived constituents.</div><div class="htmlview paragraph">The protocol does not introduce chemical constituents not normally observed in the field. The accelerated chemical exposure rate is limited only to a degree that has previously demonstrated successful correlation to normal, unaccelerated aging. The Protocol also requires that chemical aging mechanisms are to be introduced and / or consumed in a manner representative of the engine’s defined consumption pathways. Examples include sulfur exposure via high sulfur fuel or gaseous SO<sub>2</sub> and oil consumption via pre-combustion / post-combustion pathways. The Protocol also does not introduce chemical components that are not normally present in oil or fuel (other than doping the fuel with higher concentrations of sulfur, but this amount is relatively small). A comprehensive step by step breakdown of DAAAC protocol is presented elsewhere [<span class="xref">2</span>].</div><div class="htmlview paragraph">The primary objective of this paper is to disseminate the observation of long-term impacts of chemical poisoning and hydrothermal aging on a production aftertreatment catalyst subjected to FUL DAAAC protocol. The results of this experimental campaign were used to develop and validate a model capable of predicting hydrothermal and chemical aging mechanisms of conventional diesel aftertreatment to optimize long term emissions reduction performance. The paper is divided into following sections: <ol class="list nostyle"><li class="list-item"><span class="li-label">1</span><div class="htmlview paragraph">Introduction: An overview of the system</div></li><li class="list-item"><span class="li-label">2</span><div class="htmlview paragraph">Background: A review of literature in the field of diesel AT aging</div></li><li class="list-item"><span class="li-label">3</span><div class="htmlview paragraph">Test Campaign: Description of experimental setup used for collection of both steady state and transient data.</div></li><li class="list-item"><span class="li-label">4</span><div class="htmlview paragraph">Experimental setup: Description of burner stand used for data collection.</div></li><li class="list-item"><span class="li-label">5</span><div class="htmlview paragraph">Results and Discussion: Description of experimental results followed by discussion about underlying degradation mechanism identified through simulation work.</div></li><li class="list-item"><span class="li-label">6</span><div class="htmlview paragraph">Summary and conclusion</div></li></ol></div></div>

<div class="htmlview paragraph">A modified version of KIVA II code was used to perform three-dimensional calculations of combustion in a DI diesel engine. Both an ignition delay submodel and a different formulation of the fuel reaction rate were implemented and tested.</div> <div class="htmlview paragraph">The experiments were carried out on a single cylinder D.I. diesel of 0.75 I displacement equipped with sensors to detect injection characteristics and indicated pressure. A fast acting sampling valve was also installed in the combustion chamber to allow the measurement of main pollutants during the combustion cycle, by an ensemble average technique. Computational and experimental results are compared and the discrepancies are discussed.</div> <div class="htmlview paragraph">Today the demand for light duty engines that produce less emission and consume less fuel is increasing. Thus, if limits on CO<sub>2</sub> emissions are established, the direct injection diesel engine for light duty applications will become an attractive option. Also, manufacturers of heavy duty diesel engines are facing increasingly stringent emission standards. New research efforts aim at improving DI diesels emission behaviour.</div> <div class="htmlview paragraph">Given the complexity of the interaction between the different processes in diesel combustion, comprehensive models of in-cylinder phenomena prove to be useful in providing guidelines for prototype development. Multidimensional analytical models of in cylinder phenomena have been greatly improved over the last decade, given the progress of the efficiency of computer hardware and diagnostic techniques. In particular many authors [<span class="xref">1</span>, <span class="xref">2</span>, <span class="xref">3</span>, <span class="xref">4</span>, <span class="xref">5</span>, <span class="xref">6</span> and <span class="xref">7</span>] have numerically simulated the interaction between the airflow field and the spray and have compared it with experimental data. However, both three dimensional calculations of combustion in the presence of fuel sprays and the corresponding comparisons with experimental data are hardly found in literature. In most cases the comparison between numerical and experimental results is limited to the pressure history and to the fitting of some pollutant emissions late in the expansion stroke.</div> <div class="htmlview paragraph">In particular, limiting the review to diesel combustion, Zellat and others [<span class="xref">8</span>] present calculations of a swirl chamber engine at different loads, injection timings, and speeds, obtained with a modified version of KIVA code. In their results, the computed in-cylinder pressure agrees well with the experimental one. Takeneka and others [<span class="xref">9</span>] used KIVA code to perform calculations of DI Diesel combustion for both swirl chamber and quiescent chamber systems. No details about the modifications introduced in the original code are provided.</div> <div class="htmlview paragraph">Computational comparisons with in cylinder measurements, performed in a quiescent chamber system by Kamimoto [<span class="xref">10</span>], show discrepancies between computations and measurements. Gonzales and others [<span class="xref">11</span>] also used the KIVA II code with the Reitz atomization model and a single step Arrhenius mechanism to describe combustion of tetradecane in a D.I. quiescent chamber engine. The paper focuses on the spray submodel effect on the accuracy of pressure history prediction. It was demonstrated that, if adequate grid resolution is used, prediction of combustion is sensitive to the details of combustion and fuel injection models.</div> <div class="htmlview paragraph">In the present paper a detailed comparison between experiments with a fast acting sampling valve and 3D calculations is presented for a medium duty swirl supported DI engine. Calculations are performed by KI-VA II code with the adoption of the TAB jet break up sub-model and wall impingement modelling. In addition, a different formulation of combustion model is discussed. The current status of the “numerical engine program” in progress at Istituto Motori of CNR, is thus defined.</div>

<div class="htmlview paragraph">Regulated and non-regulated emissions from five current European diesel passenger cars and one light-duty diesel truck were measured to assess the environmental impact of diesel vehicles and to help determine the emission characteristics of the two types of combustion systems: indirect injection (IDI) and high speed direct injection (HSDI). The vehicle emissions were measured using the European Motor Vehicle Emissions Group (MVEG) cycle and the U.S. Federal (FTP 75) test procedures. Measured emissions included HC, CO, NO<sub>x</sub> and particulate mass (PM), C<sub>1</sub> to C<sub>12</sub> hydrocarbon species (here called light hydrocarbon or LHC), aldehydes, particulate composition and particle size distribution. The particulate composition measurements included soluble organic fraction (SOF), its oil and fuel sub-fractions, and the sulfate fraction. All passenger cars and the light-duty commercial vehicle tested complied with the current European Emissions Directive 91/441/EEC. Two passenger cars achieved the EEC Stage 2 levels, and one nearly met the 1994 Tier I U.S. Federal standards. The LHC accounted for between 35 to 78% of the total HC measured by the heated FID analyzer. Fuel and oil comprised between 12 and 30% of the PM emissions. The non-methane organic gases (NMOG) emissions and the LHC ozone reactivity from diesel cars were both about 50% less than those from gasoline cars. Of the non-regulated emissions, formaldehyde was generally below 0.009 g/km, and benzene emissions were below 0.0035 mg/km. The results were compared with European gasoline vehicles and the Current Gasoline Vehicle fleet of the U.S. Air Quality Improvement Program (AQIRP), and an assessment was made of the relative environmental impacts of gasoline and diesel vehicles.</div> <div class="htmlview paragraph">Over the last 20 years, there has been a substantial effort to lower the exhaust emissions from both diesel and gasoline passenger vehicles. Over the same period, the percentage of diesel passenger vehicles purchased in Europe has been increasing steadily(<span class="xref">1</span>)<span class="xref">*</span>. Lower operating(<span class="xref">2</span>) and maintenance costs, and better durability with equivalent drive performance appear mainly responsible for the increased diesel sales. However, even though both diesel and gasoline vehicles meet the current emission standards, questions have arisen about their relative impact on the environment(<span class="xref">3</span>). In addition, with future requirements for lower emissions, these questions will undoubtedly continue.</div> <div class="htmlview paragraph">The relative environmental impact of diesel and gasoline vehicles is still uncertain because there are relatively few published data on the emissions of current diesel vehicles and because the environmental impacts of the expected emissions are not clearly understood. Data on the regulated emissions for diesel passenger vehicles sold in Europe are available from the German Government:(<span class="xref">4</span>) starting in 1991. There are also published reports on regulated emissions from late 1980 and early 1990 diesel cars in the literature(<span class="xref">5</span>,<span class="xref">6</span>,<span class="xref">7</span>). Still there are few reports on the non-regulated emissions from current diesel vehicles(<span class="xref">8</span>,<span class="xref">9</span>,<span class="xref">10</span>).</div> <div class="htmlview paragraph">On the other hand, there are substantial published data on the regulated emissions of current gasoline vehicles(<span class="xref">11</span>). In addition, there are substantial data on the non-regulated emissions of gasoline cars, especially from the U.S. Air Quality Improvement Research Program (AQIRP)(<span class="xref">12</span>). The AQIRP emissions data included measurements of over 150 individual hydrocarbon and aldehydic compounds which allow estimates of the amount of urban ozone formed from the exhaust and of the atmospheric toxic compound levels. Diesel vehicles were not included in AQIRP.</div> <div class="htmlview paragraph">This paper reports on detail regulated and non-regulated emissions measurements for six 1992/93 model year diesel vehicles, including two Ford and four competitor vehicles. The emissions were measured on both the 1993 European MVEG cycle and the U. S. Federal test procedure. The U. S. AQIRP analytical methods were used for hydrocarbon and aldehydic speciation. The report discusses the regulated emissions from the six diesel vehicles compared to emissions standards, their contribution to urban ozone formation, toxic levels and global warming. It also compares the exhaust emissions of current diesel and gasoline vehicles to help clarify their relative environmental impact.</div>

<div class="htmlview paragraph">Several years ago some of the most prominent leaders in automotive industries cooperated to form a purely engineering group that had as its primary purpose developing a type of rigid-airship construction in which the public would have confidence. It was conceived that such an airship should be</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"> <span class="li-label">(1)</span> <div class="htmlview paragraph">Fireproof</div> </li> <li class="list-item"> <span class="li-label">(2)</span> <div class="htmlview paragraph">Weatherproof</div> </li> <li class="list-item"> <span class="li-label">(3)</span> <div class="htmlview paragraph">Durable and permanent in structure</div> </li> <li class="list-item"> <span class="li-label">(4)</span> <div class="htmlview paragraph">Navigable in practically all kinds of weather</div> </li> <li class="list-item"> <span class="li-label">(5)</span> <div class="htmlview paragraph">Economical in the use of buoyant gas and ballast</div> </li> </ol> </div> <div class="htmlview paragraph">To meet all of these requirements it was decided, after mature consideration, that a substantially all-metal construction was imperative. Development of the Metalclad airship has now reached a point where the general soundness of the design seems fully assured as</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"> <span class="li-label">(1)</span> <div class="htmlview paragraph">The structural and aerodynamic efficiencies have been established by both analytical and experimental methods</div> </li> <li class="list-item"> <span class="li-label">(2)</span> <div class="htmlview paragraph">The technical problems involved in the construction have been mastered to a certainty hitherto unapproached in any new design</div> </li> <li class="list-item"> <span class="li-label">(3)</span> <div class="htmlview paragraph">The general design of an airship of demonstration size, 200,000 cu. ft. or one-tenth the size of the Shenandoah, has been completed</div> </li> <li class="list-item"> <span class="li-label">(4)</span> <div class="htmlview paragraph">Full-sized structural members of every part of the framework have been built and tested to destruction revealing that the minimum safety factor is double that of the Shenandoah. The longitudinal strength of the metal hull will be more than four times as great as that of the Shenandoah</div> </li> <li class="list-item"> <span class="li-label">(5)</span> <div class="htmlview paragraph">The problem of riveting the metal hull-plating has been solved through the perfection of an automatic riveting-machine</div> </li> <li class="list-item"> <span class="li-label">(6)</span> <div class="htmlview paragraph">The problem of making the metal hull gas-tight has been solved with surprising efficiency indicating an osmosis of about one-tenth that through gold-beaters skin and only one-hundredth that through rubberized fabric</div> </li> <li class="list-item"> <span class="li-label">(7)</span> <div class="htmlview paragraph">A suitable coating to prevent corrosion has been satisfactorily tested</div> </li> <li class="list-item"> <span class="li-label">(8)</span> <div class="htmlview paragraph">A source of supply of aluminum alloys of dependable quality is assured</div> </li> <li class="list-item"> <span class="li-label">(9)</span> <div class="htmlview paragraph">Shop facilities for fabrication are available in Detroit</div> </li> <li class="list-item"> <span class="li-label">(10)</span> <div class="htmlview paragraph">Skilled metal-workers familiar with aluminum and its alloys are at hand</div> </li> </ol> </div> <div class="htmlview paragraph">These results depend upon certain fundamental principles that are described in the paper. In effect, the design is an entirely new one, but adheres to the fundamental unalterable principles underlying all sound engineering-work.</div> <div class="htmlview paragraph">The paper states that the Metalclad airship is the last step in the development of rigid airships and most certainly must be adopted if such a means of transportation is to be made available both for the arms of National Defense and for commercial purposes.</div> <div class="htmlview paragraph">Appendices that include extracts from studies and texts arranged to illustrate the subject matter in the main paper and furnish food for discussion supplement the paper. This material is partially elementary in form as limitations of space preclude any attempt at completeness.</div>

<div class="section abstract"><div class="htmlview paragraph">All internal combustion piston engines emit solid nanoparticles. Some are soot particles resulting from incomplete combustion of fuels, or lube oil. Some particles are metal compounds, most probably metal oxides. A major source of metal compound particles is engine abrasion. The lube oil transports these abraded particles into the combustion zone. There they are partially vaporized and ultrafine oxide particles formed through nucleation [<span class="xref">1</span>]. Other sources are the metallic additives to the lube oil, metallic additives in the fuel, and debris from the catalytic coatings in the exhaust-gas emission control devices. The formation process results in extremely fine particles, typically smaller than 50 nm. Thus they intrude through the alveolar membranes directly into the human organism. The consequent health risk necessitates a careful investigation of these emissions and effective curtailment.</div><div class="htmlview paragraph">Substantial information is available on diesel engine particulate emissions [<span class="xref">2</span>, <span class="xref">3</span>, <span class="xref">4</span>] but less for SI engines. Beside an example of metal oxide particles from a diesel engine, the present paper shows preliminary results of nanoparticles emissions of SI engines.</div><div class="htmlview paragraph">Four SI engines were investigated: two older and two newer engines, comprising two car engines and two motorbikes. The tests were done on standard transient driving cycles, and steady-state at constant 50 km/h and idling. Prior investigations observed, especially during idling, high concentrations of metal oxide particles [<span class="xref">2</span>]. All tests were done with particle samples collected from the CVS tunnel, during a long operating period, to have sufficient material for analyzing the composition. At the steady-state points, the particle size spectra were measured.</div><div class="htmlview paragraph">The results show that the older SI engines emit high concentrations of soot particles and metal oxide (= ash) particles. The size distribution is decisively bimodal for both soot and ash particles.</div><div class="htmlview paragraph">The newer engines' emission results are less uniform and the concentrations lower, as expected. Altogether, the concentrations of these metal oxide particles are so high, that more detailed investigations are recommended.</div></div>

<div class="htmlview paragraph">Controlled Auto-Ignition (CAI) combustion, also known as HCCI or PCCI, has recently emerged as a viable alternative combustion process to the conventional spark ignition (SI) or compression ignition (CI) process for internal combustion (IC) engines, owing to its potential for high efficiency and extremely low emissions. One of the most effective and practical means of achieving CAI combustion in an engine is to retain or recycle the burnt gases. In order to understand better the effects of recycled burnt gases on CAI combustion, detailed analytical and experimental studies have been carried out. The analytical studies were performed using an engine simulation model with detailed chemical kinetics.</div> <div class="htmlview paragraph">The five effects of the recycled burned gases studied include:</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"><span class="li-label">(1.)</span><div class="htmlview paragraph">Charge heating effect: higher intake charge temperature due to hot burned gases;</div></li> <li class="list-item"><span class="li-label">(2.)</span><div class="htmlview paragraph">Dilution effect: the reduction of oxygen due to the presence of the burned gases;</div></li> <li class="list-item"><span class="li-label">(3.)</span><div class="htmlview paragraph">Heat capacity effect: due to higher specific heat capacity of burned gases;</div></li> <li class="list-item"><span class="li-label">(4.)</span><div class="htmlview paragraph">Chemical effect: chemical reactions involving CO<sub>2</sub> and H<sub>2</sub>O in the burned gases</div></li> <li class="list-item"><span class="li-label">(5.)</span><div class="htmlview paragraph">Stratification effect: recycled burned gases are stratified from the fuel/air mixture.</div></li> </ol> </div> <div class="htmlview paragraph">And the main conclusions are:</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"><span class="li-label">(1.)</span><div class="htmlview paragraph">The charge heating effect is mainly responsible for the advanced AI timing due to hot burned gases. It increases the heat release rate and shortens the combustion duration.</div></li> <li class="list-item"><span class="li-label">(2.)</span><div class="htmlview paragraph">The dilution effect does not affect AI timing, but it extends combustion duration. Its slows down the heat release rate only when large amount of burned gases is present.</div></li> <li class="list-item"><span class="li-label">(3.)</span><div class="htmlview paragraph">The heat capacity effect is mainly responsible for the reduction in the heat release rate, and it has a similar effect to extend the combustion duration as the dilution effect.</div></li> <li class="list-item"><span class="li-label">(4.)</span><div class="htmlview paragraph">The chemical effect does not affect AI timing and heat release rate. It reduces the combustion duration slightly at high concentrations of burned gases.</div></li> <li class="list-item"><span class="li-label">(5.)</span><div class="htmlview paragraph">The stratified burned gases facilitate the CAI combustion due to the presence of higher temperature region at the boundary between of the hot burned gases and combustible charge.</div></li> </ol> </div>

<div class="htmlview paragraph">To help account for fuel distribution during combustion in diesel engines, a fuel film model has been developed and implemented into the KIVA-II code [<span class="xref">1</span>]. Spray-wall interaction and spray-film interaction are also incorporated into the model. Modified wall functions for evaporating, wavy films are developed and tested.</div> <div class="htmlview paragraph">The model simulates thin fuel film flow on solid surfaces of arbitrary configuration. This is achieved by solving the continuity, momentum and energy equations for the two dimensional film that flows over a three dimensional surface. The major physical effects considered in the model include mass and momentum contributions to the film due to spray drop impingement, splashing effects, various shear forces, piston acceleration, dynamic pressure effects, and convective heat and mass transfer. In order to adequately represent the drop interaction process, impingement regimes and post-impingement behavior have been modeled using experimental data and mass, momentum and energy conservation constraints. The regimes modeled for spray-film interaction are stick, rebound, spread, and splash. Further details of the model are found in [<span class="xref">2</span>, <span class="xref">3</span>].</div> <div class="htmlview paragraph">The spray-wall interaction and fuel film models are used to simulate evaporating sprays impinging on a flat surface. The vapor and liquid phase distributions are compared to exciplex fluorescence data. Additionally, the models are used to investigate the performance of a two-stroke, direct injection diesel engine with loop-scavenging. Numerical simulations compared well with experimental data for fuel film thickness, percentage of fuel that adheres to the wall and the spreading area of the film, as well as global engine parameters such as cylinder pressure. The film model provides a predictive tool for examination of wall wetting and secondary atomization characteristics at varying engine loads.</div>

<div class="htmlview paragraph">A major challenge for researchers and engineers in the field of diesel engine development is the simultaneous reduction of both NOx and soot emissions from diesel engines to comply with strict future emission legislation. One of the promising internal measures that focus on the reduction of soot emissions is post fuel injection which does not have a serious effect on NOx emissions. The main parameters involved when using this technique are post fuel quantity and dwell angle between the main and the post fuel injection events. In the present work a detailed computational investigation has been conducted to determine the effect of post fuel injection on engine performance and pollutant emissions (NOx and soot). To this scope, a phenomenological multi-zone combustion model has been used, properly modified to take into account the interaction of post and main injected fuel amounts. Using the proposed model a parametric study has been conducted varying both post fuel injection quantity and dwell angle and maintaining model's constants the same when switching from normal to post injection. From this analysis it is revealed that post fuel injection enhances soot oxidation due to the increase of in-cylinder temperature at the late phase of combustion cycle, and mainly due to the improved air-fuel mixing as a result of the post injection mechanism. To validate the model various performance parameters and exhaust tailpipe values are compared with experimental data obtained from measurements performed on a heavy duty turbocharged DI Diesel engine, equipped with a common rail fuel injection system with and without post injection. As observed the model manages in general to capture the effect of both post injection parameters examined on engine performance and emissions despite differences observed in absolute values for some cases. Furthermore, information is provided for soot formation and oxidation rates and the actual effect of post injection upon them.</div>

<div class="htmlview paragraph">The production unit number of small diesel engine cars tends to decline except recreational vehicles in Japanese market in recent years, while the production unit number in Europe market keeps on increasing owing to the merits of the durability and the fuel consumption. The small diesel engines will have to be improved in the near future by solving major problems such as noise and vibration pollution, environmental pollution, improvement in performance of diesel engines, in order to expand the production of the engines.</div> <div class="htmlview paragraph">This paper refers to a basic study on the experimental and analytical methods for the reduction of resonant vibration in each vibration mode on some cylinder blocks of small high-speed diesel engines in rated engine speed range. Hammering test method, which is easy and useful for measuring frequency response functions, is carried out in the experiments. In this test, the cylinder blocks are directly excited with the impulse hammer, and more the main journals are excited via the newly-made force transmission parts in the next experiment. Two kinds of the engines which have been recently recognized as low noise and vibration engines are chosen in this study. The cylinder blocks of the engines are called of long skirt type and ladder frame type, respectively. The vibration characteristics of these cylinder blocks are obtained in the frequency range from 500 <i>Hz</i> to 2 <i>kHz</i> using the experimental modal analysis. This frequency range is chosen in consideration of the reliability of the vibration experiments. And the force transmission routes from the piston heads to the crank journals of each cylinder block are considered as mentioned in the latter experimental method. The experimental results are used to calculate the natural frequencies by the modal analysis and the calculated results are compared with the ones obtained from FEM analysis. Furthermore, the cylinder blocks are remodeled in order to reduce the vibrations of all modes using FEM analysis.</div> <div class="htmlview paragraph">Consequently, it has been shown that the vibration stress of the cylinder block can be reduced by higher rigidities and more lightening weights of the crankcase and the crank journals in the measured frequency range.</div> <div class="htmlview paragraph">The conclusions are described as follows;</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"> <span class="li-label">1</span> <div class="htmlview paragraph">The hammering test method using the force transmission parts is useful to measure the natural frequencies of a cylinder block. This method can be easy to get the equal results with the measured ones on running conditions without engine operation.</div> </li> <li class="list-item"> <span class="li-label">2</span> <div class="htmlview paragraph">The hammering test method using the force transmission parts can easily analyze the natural frequencies at all the vibration modes on equal conditions with running ones. Then the method is a useful tool for improving the vibration characteristics.</div> </li> <li class="list-item"> <span class="li-label">3</span> <div class="htmlview paragraph">It has been proved from the analytical viewpoints that the cylinder block of the ladder frame type can be adopted as low-noise, small diesel engines with little increase of the engine weight while maintaining higher rigidity.</div> </li> </ol> </div>

<div class="htmlview paragraph">An engine cycle simulation program has been developed to predict both engine performance and NO<sub>x</sub> emission with reasonable accuracy. The program is a product that combines two programs, VIPRE™ and ALAMO_ENGINE, both developed at Southwest Research Institute (SwRI). VIPRE™ is a comprehensive tool for engine systems with intake and exhaust dynamics, emphasizing engine performance <sup>[<span class="xref">1</span>]</sup>, while ALAMO_ENGINE is a program focusing on NO<sub>x</sub> prediction <sup>[<span class="xref">2</span>]</sup>.</div> <div class="htmlview paragraph">Demonstrations in this paper were based on a six-cylinder, turbocharged diesel engine with a high-pressure exhaust gas recirculation (EGR) loop. The EGR system is connected upstream of the intake manifold from the exhaust manifold located in the turbine entrance. A two-way butterfly valve is used to control the EGR rate. The major challenge in this modeling work is the prediction of engine performance and NO<sub>x</sub> emission in an acceptable and systematical fashion. There are many programs used for either engine performance or NO<sub>x</sub> prediction in literature. <sup>[<span class="xref">3</span>, <span class="xref">4</span> and <span class="xref">5</span>]</sup> However, very few programs are capable of predicting both engine performance and NO<sub>x</sub> emission over wide operating conditions with acceptable accuracy. This paper will demonstrate that the program developed by SwRI is one of only a few programs that can carry out this task.</div> <div class="htmlview paragraph">Comparisons of engine performance and NO<sub>x</sub> emission between simulations and measurements were carried out over a wide range of operating conditions. It was shown that the integrated program could predict both engine performance and relative NO<sub>x</sub> with reasonable accuracy.</div>

<div class="htmlview paragraph">To overcome the trade-off between NOx and particulate emissions for future diesel vehicles and engines it is necessary to seek methods to lower pollutant emissions. The desired simultaneous improvement in fuel efficiency for future DI (Direct Injection) diesels is also a difficult challenge due to the combustion modifications that will be required to meet the exhaust emission mandates.</div> <div class="htmlview paragraph">This study demonstrates the emission reduction capability of split injections, EGR (Exhaust Gas Recirculation), and other parameters on a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system using an RSM (Response Surface Method) optimization method. The optimizations were conducted at 1757 rev/min, 45% load. Six factors were considered for the optimization, namely the EGR rate, SOI (Start of Injection), intake boost pressure, and injection pressure, the percentage of fuel in the first injection, and the dwell between injections. In addition, the effects of swirl were investigated.</div> <div class="htmlview paragraph">The benefit of the combined effects of EGR with supercharging was well realized by the RSM optimization, which resulted in simultaneous reductions in both NOx and PM emissions, while even improving BSFC (Brake Specific Fuel Consumption). Through the present optimization process, it was shown that RSM optimization is an effective and powerful tool for realizing the full advantages of the combined effects of combustion control techniques. In addition, observation of the optimization process provides a more thorough understanding of HSDI diesel combustion since the observed trends can be explained by monitoring the effects of the operating parameters.</div>

<div class="htmlview paragraph">The new concept catalyst for diesel engine has been developed. When the exhaust temperature is low, SOF and HC are temporarily adsorbed by the adsorbent within the catalyst and are oxidized as the temperature rise. This is a different that the low-temperature oxidation activity is appeared by the noble metal loading of the catalyst. The process of this development have manifested as follows.</div> <div class="htmlview paragraph"> <ol class="list nostyle"> <li class="list-item"> <span class="li-label">1.</span> <div class="htmlview paragraph">The coating material is important factor to govern the oxidation activity.</div> </li> <li class="list-item"> <span class="li-label">2.</span> <div class="htmlview paragraph">SOF is reduced by the coating material in low temperature less than 200</div> </li> <li class="list-item"> <span class="li-label">3.</span> <div class="htmlview paragraph">The coating material, which has low SO2 adsorbing rate suppress the sulfate formation at high temperature.</div> </li> <li class="list-item"> <span class="li-label">4.</span> <div class="htmlview paragraph">To reduce NOx in the diesel engine exhaust gas is possibility by utilizing adsorptive characteristics of the catalyst.</div> </li> </ol> </div>

<div class="htmlview paragraph">Currently, throughout the world combustion engine development is influenced by two primary concerns. First is the increasing concern for global warming, and second is the concern over particulate and oxides of nitrogen emissions, each of which affect the environment and human health because of the particles' toxicity and ground level ozone production, respectively.</div> <div class="htmlview paragraph">To address the global warming issue, in late 1997, various nations approved the <i>Kyoto Protocol</i> to reduce CO<sub>2</sub> emissions because of its identified contribution to the greenhouse effect. The Diesel engine is the most efficient power plant for mobile and stationary purposes and, thus, Diesel engines are considered to be one alternative to gasoline engines to reduce fuel consumption and, thus, CO<sub>2</sub> emissions.</div> <div class="htmlview paragraph">To address the emission concerns, the European Community and the U.S. Environmental Protection Agency (EPA) proposed emissions standards prescribing substantial reductions of NO<sub>X</sub> and PM emissions [<span class="xref">1</span>,<span class="xref">2</span>]<span class="xref"><sup>1</sup></span>. As a result of these proposed standards, reductions in particulate and NO<sub>X</sub> emissions have become major challenges in Diesel engine development. Unfortunately, in the paradigm of Diesel engine development, ultra low emissions and very low fuel consumption are two opposing objectives. Moreover, NO<sub>X</sub> reduction from lean exhaust is fundamentally difficult because of the excess oxygen present. Particulate mass emissions from modern Diesel engines are already on very low levels; however, recently particulate numbers rather than particulate mass have attracted much attention and, thus, further reductions are necessary.</div> <div class="htmlview paragraph">This paper describes new approaches to ultra low emission Diesel vehicles that comply with the proposed emission standards. Advanced exhaust gas aftertreatment technology, including Diesel particulate filters and NO<sub>X</sub> catalysts, have previously been subjected to detailed research. In this paper, some new approaches are described, and their potential to large-scale vehicle application is assessed.</div>