- Conference Article
- 10.1364/oam.1990.fff4
Enhancement of chiral assmmetry by multiple light reflection
- Jan 01, 1990
- M P Silverman + 1 more +1
The asymmetric response of a gyrotropic medium to left and right circularly polarized light, as manifested in specular reflection, provides (1) a sensitive test of the electrodynamics of chiral media and (2) a novel spectroscopic method particularly suitable for nontransparent chiral materials in microquanitites. The differential reflection of circularly polarized light, d = (IL-IR)/(IL+IR) (where IL and IR is the reflected-light flux of specialized polarizations), is ordinarily linearly proportional to the chiral parameter(s) and is of the order 105-10-6 for many materials. However, for total reflection near critical angle, d is a nonlinear function of the chiral parameter(s) and can exceed the above range by several orders of magnitude.1 This enhancement can be further increased by multiple reflection. For N passes at the critical angle from a weakly absorbing chiral sample, d is approximately N times greater than for a single pass. The enhancement factor is smaller than N to the extent that the incident angle departs from critical angle or N exceeds an optimal value. For sufficiently high N, the angular range of enhancement becomes too narrow to be of practical utility.
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