Mechanical behavior of single-layer graphdiyne via supersonic micro-projectile impact

Highly effective energy dissipation system based on one-dimensionally arrayed short single-walled carbon nanotubes

Local impact resistance of curved sandwich panel with Miura-ori foldcore

Compressive solitary waves in black phosphorene

Energy Storage and conversion devices require an ion-exchange membrane to accomplish high transmission of charge-balancing ions and separation of anode and cathode electrolytes/gases from mixing. These critical functions of membranes play a pivotal role in ensuring device optimum performance and higher efficiency. Most conventional membranes suffer huge ionic and molecular species cross-permeation resulting in low energy efficiency and material degradation. In this work, hydrogen permeability and proton transmission through membrane electrode assemblies (MEAs) that contain a monolayer of hexagonal boron nitride, single-layer and bi-layer graphene were investigated in a gas-phase small-scale cell and a liquid cell. We found that the hydrogen crossover flux through MEAs with 2D materials was inhibited by at least a factor of 5 as compared to the one without. Single-layer graphene and boron nitride enabled high proton transmission, but bi-layer graphene inhibited proton conduction. Defect visualization of 2D materials by chemical treatment with a low ferric chloride concentration followed by imaging using a digital microscope revealed few atomic-scale defects in graphene. These findings suggest that a monolayer of 2D material may provide good selectivity for energy conversion and storage devices by blocking species crossover while allowing high proton transmission.

A detailed experimental investigation was carried out for the high‐velocity ballistic response of AA 1100‐H14 based carbon‐fiber metal laminates (FMLs). FMLs with different metal volume fractions and the same thickness of carbon‐epoxy fiber laminates were tested to examine the surface and internal damage. The ballistic performance parameters, namely % escalation in absorbed energy, specific energy absorbed, ballistic limit, specific perforation energy, first cracking energy, and global deformation profile, were studied and a comparison was drawn with pure carbons fiber reinforced epoxy composite laminates. Despite having greater thickness, pure carbon fiber‐reinforced epoxy composite laminates absorbed less impact energy than FMLs and failed catastrophically. For FMLs, the % escalation in the absorbed energy and the specific energy absorption kept increasing with the increasing impact velocity until the onset of perforation. Once the perforation started, both these parameters showed a decreasing trend. Thick FMLs absorbed a good amount of energy, leading to projectile recoil suffering minimal damage. The ballistic velocity, specific perforation energy, and first cracking energy on the front and rear face of FMLs layers showed an increasing trend. The minimum for the thinner and maximum for the thicker FMLs attributed to the large thickness and more metal volume fraction. Contrary to the large deformation of the impacting points, pure carbon fiber‐reinforced epoxy composite laminates showed very minimal deformation as compared to FMLs. The brittle nature of the epoxy resin resisted the deformation to a large extent leading to less energy absorption.Highlights High‐velocity ballistic response of AA 1100‐H14 based carbon‐FMLs was investigated. Ballistic performance parameters of FMLs were studied and was compared with carbons fiber reinforced composite laminates. The ballistic limit of FMLs showed a direct dependence its thickness and metal volume fraction. In the absence of any metallic layer, pure carbons fiber reinforced composite laminates absorbed less impact energy.

Iridoviruses, a group of double-stranded DNA viruses, pose a significant threat to various aquatic animals, causing substantial economic losses in aquaculture and impacting ecosystem health. Early and accurate detection of these viruses is crucial for effective disease management and control. Conventional diagnostic methods, including polymerase chain reaction (PCR) and virus isolation, often require specialized laboratories, skilled personnel, and considerable time. This highlights the need for rapid, sensitive, and cost-effective diagnostic tools for iridovirus detection. Single-layer graphene, a two-dimensional material with unique properties like high surface area, excellent electrical conductivity, and chemical stability, has emerged as a versatile platform for biosensing applications. This paper explores the potential of employing single-layer graphene in the development of a bionanosensor for the sensitive and rapid detection of iridoviruses. The aim of the present investigation is to develop a sensor by analyzing the vibrational responses of single-layer graphene sheets (SLGS) with attached microorganisms. Graphene-based virus sensors typically rely on the interaction between the virus and the graphene surface, which lead to changes in the frequency response of graphene. This change is measured and used to detect the presence of the virus. Its high surface-to-volume ratio and sensitivity to changes in its frequency make it a highly sensitive platform for virus detection. We employ finite element method (FEM) analysis to model the sensor's performance and optimize its design parameters. The simulation results highlight the sensor's potential for achieving high sensitivity and rapid detection of iridovirus. Bridged and simply supported with roller support boundary conditions applied at the ends of SLG structure. Simulations have been performed to see how SLG behaves when used as sensors. A single-layer graphene armchair SLG (5,5) with 50-nm length exhibits its highest frequency vibration at 8.66 × 106 Hz, with a mass of 1.2786 Zg. In contrast, a zigzag-SLG with a (18,0) configuration has its lowest frequency vibration at 2.82 × 105 Hz. This aids in comprehending the thresholds of detection and the influence of factors such as size, and boundary conditions on sensor effectiveness. These biosensors can be especially helpful in biological sciences and the medical field since they can considerably improve the treatment of patients, cancer early diagnosis, and pathogen identification when used in clinical environments.

Three-dimensional (3D) parts are widely gaining popularity in industries like automotive, aerospace, medical healthcare, consumer goods, and electronics. The properties and performance of these parts vary depending on the parameters chosen at the design and manufacturing stages. This study experimentally evaluates the impact of topology on energy absorption and structural stability of eight strut-based lattice topologies fabricated using Fused Deposition Modeling (FDM) with Polylactic Acid (PLA). Quasi-static compression tests were conducted in accordance with ASTM D695. Specific Energy Absorption (SEA), crush force efficiency (CFE), and newly defined metrics—Peak-to-Plateau Load Ratio (PPLR) and Structural Efficiency (SE)—were used to determine collapse behavior and load stability. All lattices were manufactured within a narrow relative density range (0.29–0.30) to ensure topology-driven assessment. The Double Octagon lattice showed superior performance, achieving a maximum SEA of 6653.18 J kg⁻¹ , total absorbed energy of 57.55 J, and the highest structural efficiency among the investigated configurations. Substantial energy dissipation and trustworthy collapse mechanisms were shown by the Hex Truss and Kelvin cell; however, the Face Centered and Face Diagonal structures showed comparatively lower energy absorption. The proposed PPLR metric quantifies initial peak load severity relative to sustained collapse response, complementing conventional SEA and CFE measures. The findings highlight the critical role of topology optimization in balancing stiffness, weight, and energy absorption in guiding lightweight crashworthy lattice design.

Dielectric and absorption properties of as-grown Bilayer and Single layer graphene at the microwave frequencies

The removal of surface residues from single-layer graphene (SLG), including poly(methyl methacrylate) (PMMA) polymers and Cl− ions, during the transfer process remains a significant challenge with regard to preserving the intrinsic properties of SLG, with the process often leading to unintended doping and reduced electronic performance capabilities. This study presents a rapid and efficient surface treatment method that relies on an aqueous sodium nitrite (NaNO2) solution to remove such contaminants effectively. The NaNO2 solution rinse leverages reactive nitric oxide (NO) species to neutralize ionic contaminants (e.g., Cl−) and partially oxidize polymer residues in less than 10 min, thereby facilitating a more thorough final cleaning while preserving the intrinsic properties of graphene. Characterization techniques, including atomic force microscopy (AFM), Kelvin probe force microscopy (KPFM), and X-ray photoelectron spectroscopy (XPS), demonstrated substantial reductions in the levels of surface residues. The treatment restored the work function of the SLG to approximately 4.79 eV, close to that of pristine graphene (~4.5–4.8 eV), compared to the value of nearly 5.09 eV for conventional SLG samples treated with deionized (DI) water. Raman spectroscopy confirmed the reduced doping effects and improved structural integrity of the rinsed SLG. This effective rinsing process enhances the reproducibility and performance of SLG, enabling its integration into advanced electronic devices such as organic light-emitting diodes (OLEDs), photovoltaic (PV) cells, and transistors. Furthermore, the technique is broadly applicable to other two-dimensional (2D) materials, paving the way for next-generation (opto)electronic technologies.

Natural protective materials offer unparalleled solutions for impact-resistant material designs that are simultaneously lightweight, strong, and tough. Particularly, the Bouligand structure found in the dactyl club of mantis shrimp and the staggered structure in nacre achieve excellent mechanical strength, toughness, and impact resistance. Previous studies have shown that hybrid designs by combining different bioinspired microstructures can lead to enhanced mechanical strength and energy dissipation. Nevertheless, it remains unknown whether combining Bouligand and staggered structures in nanofibrillar cellulose (NFC) films, forming a discontinuous fibrous Bouligand (DFB) architecture, can achieve enhanced impact resistance against projectile penetration. Additionally, the failure mechanisms under such dynamic loading conditions have been minimally understood. In our study, we systematically investigate the dynamic failure mechanisms and quantify the impact resistance of NFC thin films with DFB architecture by leveraging previously developed coarse-grained models and ballistic impact molecular dynamics simulations. We find that when nanofibrils achieve a critical length and form DFB architecture, the impact resistance of NFC films outperforms the counterpart films with continuous fibrils by comparing their specific ballistic limit velocities and penetration energies. We also find that the underlying mechanisms contributing to this improvement include enhanced fibril sliding, intralayer and interlayer crack bridging, and crack twisting in the thickness direction enabled by the DFB architecture. Our results show that by combining Bouligand and staggered structures in NFC films, their potential for protective applications can be further improved. Our findings can provide practical guidelines for the design of protective films made of nanofibrils.

This chapter discusses giant optical path length (OPL) from thin-layer molybdenum disulphide originated from their high refractive indices. Refractive optical components rely on the OPL to modify the phase front of an optical beam. It shows that high-index two-dimensional (2D) materials have extraordinary elastic interactions with light, enabled uniquely by the combination of their ultra-thin nature and high refractive indices. 2D layered materials have emerged as promising candidates for miniaturisation of optoelectronic devices, such as photo-detectors, light emitters, absorbers, edge non-linear optics and valleytronic devices, due to their strong inelastic interactions with light. The giant scattering efficiency in high-index 2D materials makes it possible to achieve sophisticated light manipulation based on collective scattering by nanostructured patterns. 2D optical components represents a significant advantage in manufacturing compared to conventional 3D optical components, because different functionalities can all be achieved in a 2D platform sharing the same fabrication processes and this will greatly facilitate large-scale manufacturing and integration.

Soft body armor composites are broadly utilized for individual security due to their light weight and flexible nature. However, they are not viable in halting high-velocity impact, particularly against impact at a near distance. Integrating shear thickening fluids (STFs) into these composites is a promising result of upgrading their impact resistance. This review article highlights the progress in improving the impact resistance of soft body armor composites due to the incorporation of STFs. It discusses the parameters affecting energy absorption, shear thickening fluid properties, rheological properties of STFs, mechanisms of energy dissipation during the impact, fabrication techniques of STF-fabric composites, ballistic test techniques, and challenges of ballistic performance evaluation and wearer consolation. This review paper incorporates previous research work for experimental and numerical simulation results. In general, the integration of STFs into soft body armor composites showed noteworthy guarantees in the impact resistance capabilities of soft body armor composites. The most frequent applications of soft body armor composites are security personnel, civilian applications, emergency response teams, private security, body guards, law enforcement, and the military.

Impact resistance and energy absorbing capability are of great interest in the design of composite sandwich structures. This paper experimentally studies damage, failure and energy absorption properties of foam core sandwich panels with aluminum and glass fiber reinforced plastic (GFRP) facesheets subjected to low velocity impact. Tests are performed using a drop weight impact tower at different impact velocities. The energy absorbing capabilities of aluminum and composite facesheet sandwich panels with PUR and PS foam core are evaluated by means of absorbed energy-time histories and by specific parameters as normalized absorbed energy, specific energy absorption, and crush force efficiency. Stiffer panels behave better at lower impact velocities, while more ductile ones do better if impact energy is increased.

The interaction between two-dimensional (2D) materials and light is rather weak due to their ultrathin thickness. In order for these emerging 2D materials to achieve performances that are comparable to those of conventional optoelectronic devices, the light-material interaction must be significantly enhanced. An effective way to enhance the interaction is to use optical resonances. Efficient light absorption has been demonstrated in a single layer of graphene based on a variety of resonators. However, the bandwidth of the absorption enhancement is always narrow, which limits its application for optoelectronic devices. In order to broaden the enhancement of light-material interaction, here we propose a multiple-resonator approach based on nanostructured graphene. These nanostructures having different geometry support resonances at different frequencies. Owing to their deep subwavelength sizes, graphene resonators can be closely packed in space, resulting in a high optical density of states, which enables the broadband light absorption.

Using an enhanced optically heterodyned optical Kerr effect method and a theoretical description of the interactions between an optical beam, a single layer of graphene, and its substrate, we provide experimental answers to questions raised by theoretical models of graphene third-order nonlinear optical response. In particular, we measure separately the time response of the two main tensor components of the nonlinear susceptibility, we validate the assumption that the out-of plane tensor components are small, and we quantify the optical impact of the substrate on the measured coefficients. Our method can be applied to other 2D materials, as it relies mainly on the small ratio between the thickness and the wavelength.