Multifunctional Hydrophobic Eutectogel for Addressing Coupled Mechanical, Thermal, and Electrical Requirements in Cryogenic Environments

The viscoelastic properties of crossbridges in rigor state are studied by means of application of small length changes, completed within 30 microseconds, to isometric skinned fibre segments of the iliofibularis muscle of the frog in relaxed and rigor state and measurement of the tension response. Results are expressed as a complex Young's modulus, the real part of which denotes normalized stiffness, while the imaginary part denotes normalized viscous mechanical impedance. Young's modulus was examined over a wide frequency range varying from 5 Hz up to 50 kHz. Young's modulus can be interpreted in terms of stiffness and viscous friction of the half-sarcomere or in terms of elastic changes in tension and recovery upon a step length change. The viscoelastic properties of half-sarcomeres of muscle fibre segments in rigor state showed strong resemblance to those of activated fibres in that shortening a muscle fibre in rigor state resulted in an immediate drop in tension, after which half of the drop in tension was recovered. The following slower phases of tension recovery--a subsequent drop in tension and slow completion of tension recovery--as seen in the activated state, do not occur in rigor state. The magnitude of Young's moduli of fibres in rigor state generally decreased from a value of 3.12 x 10(7) N m-2 at 40 kHz to 1.61 x 10(7) N m-2 at about 100 Hz. Effects of increased viscosity of the incubation medium, decreased interfilament distance in the relaxed state and variation of rigor tension upon frequency dependence of complex Young's modulus have been investigated. Variation of tension of crossbridges in rigor state influenced to some extent the frequency dependence of the Young's modulus. Recovery in relaxed state is not dependent on the viscosity of the medium. Recovery in rigor is slowed down at raised viscosity of the incubation medium, but less than half the amount expected if viscosity of the medium would be the cause of internal friction of the half-sarcomere. Internal friction of the half-sarcomere in the relaxed fibre at the same interfilament distance as in rigor is different from internal friction in rigor. It will be concluded that time necessary for recovery in rigor cannot be explained by friction due to the incubation medium. Instead, recovery in rigor expressed by the frequency dependence of the Young's modulus has to be due to intrinsic properties of crossbridges. These intrinsic properties can be explained by the occurrence of state transitions of crossbridges in rigor.(ABSTRACT TRUNCATED AT 400 WORDS)

Thermal shock resistance of magnesia–chrome refractories—experimental and criterial evaluation

We present a novel method of probing adhesion energies of solids, particularly polymers. This method uses the axi-symmetric deformation of a thin spincast polymer membrane brought into contact with a flat substrate to probe the work of adhesion. The use of a thin membrane minimizes uncertainty in the radius of contact, while the use of spincast films provides very smooth surfaces by means of a very simple method. The experimental profile of the deformed membrane shows good agreement with the expected logarithmic profile. The experimental setup enables the measurement of Young's modulus and the solid-solid work of adhesion for thin films. The value obtained for Young's modulus of polystyrene (PS) was found to be in agreement with other conventional measurement techniques. In addition, measurement of the work of adhesion at the PS/silicon oxide interface was possible. The apparatus is well suited to studying the dependence of Young's modulus, work of adhesion and fracture energy on membrane thickness, temperature, pulling rate, and ageing of the interface, and can readily be modified to study biologically relevant samples.

Electro-stiffening in polypyrrole films: Dependence of Young's modulus on oxidation state, load and frequency

Mechanical properties of ZnS nanowires and thin films are studied as a function of size and growth direction using all-atom molecular dynamics simulations. Using the stress-strain relationship we extract Young's moduli of nanowires and thin films at room temperature. Our results show that Young's modulus of [0001] nanowires has strong size dependence. On the other hand, $[01\overline{1}0]$ nanowires do not exhibit a strong size dependence of Young's modulus in the size range we have investigated. We provide a microscopic understanding of this behavior on the basis of bond stretching and contraction due to the rearrangement of atoms in the surface layers. The ultimate tensile strengths of the nanowires do not show much size dependence. To investigate the mechanical behavior of ZnS in two dimensions, we calculate Young's modulus of thin films under tensile strain along the [0001] direction. Young's modulus of thin films converges to the bulk value more rapidly than that of the [0001] nanowire.

Finite element modeling of single-walled carbon nanotubes

We use molecular dynamical software Material Studio^TM to investigate Young's moduli of Silicon nanowires along [001], [110] and [111] directions. Young's moduli for various directional and sized specimens are obtained via the energy-strain curves. The study suggests that the Young's modulus decreases as the thickness of the specimen decreases especially for the [001] direction, which display the peculiarity of anisotropy and size dependence. In comparison with the bulk silicon, the overall nanowires become soften for all the three directions. With respect to the results reported, similar trend is observed but magnitude of Young's modulus is not the same with each other. We analyze the dependence of Young's modulus on the size, surface structure and boundary conditions.

Temperature dependence ofin situfiber strength, effective interface shear stress, Young's modulus of matrix, and matrix fracture energy in a polymer-infiltrationpyrolysis (PIP)-processed two-dimensional plain-woven fabric carbon-coated Nicalon™ SiC fiber-reinforced SiC matrix composite was studied through a tensile test in air at 298 (room temperature), 800, and 1200 K.In situfiber strength and effective interface shear stress were determined by fracture mirror size and fiber pullout length measurements, respectively. The fiber strength was insensitive to test temperature up to 800 K but dropped significantly at 1200 K. Conversely, the interface shear stress showed a strong temperature dependence, decreasing at 800 K and drastically increasing at 1200 K. The temperature dependence of both values was reasonably explained. Temperature dependence of Young's modulus of matrix was derived from Young's modulus of the composite and fiber and ranged from ≈40 to ≈38 GPa. Matrix fracture energy was also determined from the transverse matrix cracking stress and ranged from ≈16 to ≈5.5 J/m2. Both Young's modulus of matrix and the matrix fracture energy showed only slight temperature dependence up to 800 K; however, both values decreased significantly at 1200 K.

Strategies for scheduling power plants producing both heat and electric energy

The linear elastic properties of a soft tissue exhibiting a unidirectional arrangement of reinforcing fibers may be described in terms of the five independent elastic stiffness coefficients C11, C13, C33, C44, and C66. In previous studies, ultrasonic measurements of these coefficients for formalin fixed specimens of bovine Achilles tendon and normal human myocardium were reported. In the present study these results are used to analyze the anisotropy of Young's modulus of these tissues. For formalin fixed tendon a value of 1.37 GPa is obtained for Young's modulus along the fiber axis of the tissue, and a value of 0.0706 GPa is obtained perpendicular to the fibers. For formalin fixed myocardium, values of 0.101 and 0.0311 GPa parallel and perpendicular to the fibers, respectively, are obtained. Based on the results for the angular dependence of Young's modulus from unidirectional specimens of myocardium, a model is introduced to estimate these features for the more complicated fiber architecture of the left ventricular wall.

Thin metal films are widely used in modern electro mechanical systems. The need for more integrated functionality and minimization of material and energy consumption leads to miniaturization of these systems. As a consequence, materials are processed on the micro- and nanometer scale. On this scale, material properties become a function of size. To predict performance and reliability, knowledge on the size dependence of material properties is imperative. In this work the unknown size dependence of the copper Young's modulus is determined by electrostatic pull-in experiments performed on bilayer copper-silicon nanocantilevers. The size effect is also predicted with a multi-scale (MS) method. In this method atomistic simulations predict the bulk elastic and surface properties of mono-crystalline silicon (Si) and poly-crystalline copper (Cu). These results are combined to represent the bilayer nanocantilevers of the experiment in a continuum model. The model is verified by comparison with a well documented size effect of the effective Si Young's modulus. It is shown that the experimental method can be used for determining the Young's modulus of thin Cu films in the 10 to 50 nm range. Both the experimental results and the MS simulation results show that there is a strong size effect present in Si and Cu.

Silicon carbide (SiC) is widely recognized as the leading candidate to replace silicon in micro-electro-mechanical systems devices operating in harsh environments. In this work, cantilevers and bridges in SiC are designed, fabricated and evaluated between room temperature (RT) and 600 °C. The active material is a cubic poly-SiC film deposited on a poly-Si layer which is separated from the Si substrate by a thermal oxide. From surface profiling and optical observations, it is deduced that an average residual strain of +5 × 10−4 is present in the 2.7 µm thick film, with a gradient of 2.5 × 10−4 µm−1. The structures are excited either mechanically or electrostatically. Their resonance frequency is measured by laser Doppler velocimetry and used to derive the Young's modulus and residual stress in the heteroepitaxial layer (330± 45 GPa and 200± 20 MPa, respectively). The temperature coefficient of Young's modulus is found to be −53± 2 ppm K−1 in the range RT to ∼ 300 °C, while an analytical expression is given for the temperature dependence of the Young's modulus between RT and 500 °C. The residual tensile stress is found to depend on temperature in a complex manner.

This paper demonstrates the investigations on the blade vibration of a radial inflow micro gas turbine wheel. Firstly, the dependence of Young's modulus on temperature was measured since it is a major concern in structure analysis. Secondly, turbine blades suffer many excitations during operation, such as pressure fluctuations (unsteady aerodynamic forces), torque fluctuations, etc. On the other hand, a turbine wheel has many kinds of vibration modes, typical ones being blade-hub (disk) coupled modes and blade-shaft (torsional) coupled modes. Model experiments and FEM (Finite Element Method) analysis were conducted to study the coupled vibration and to identify the modes, which are more likely to cause problems. It is demonstrated that Young's modulus depends on temperature greatly and the dependence should be considered in structure analysis. Anisotropy and scattering of the Young's modulus were not significant even at high temperature. The results of model experiments and FEM analysis show that torque fluctuations and uniform pressure fluctuations (the fluctuations acting on all the blades in the same phase) may excite resonance of blade-shaft (torsional) coupled modes. Impact excitations and propagating pressure fluctuations (the fluctuations propagating in the circumferential direction around the blades) may excite blade-hub (disk) coupled modes.

Young's modulus and internal friction of europium

Analysis and optimal design of layered composites with high stiffness and high damping