Negative Magnetic Permeability in the Visible Light Region

Microplasmas generated by a single split-ring resonator and a dual concentric split-ring resonator operating at the same frequency are compared. Argon is used as the working gas and held at a pressure of 0.5 Torr. The surface electric fields in the resonators were simulated to gain insight into the behavior of the fields in each device. Double Langmuir probes were used to measure the plasma density and electron temperature in a 2D plane 2 mm above the surface of the resonators. The single and the concentric ring resonators both had a maximum electron temperature in the discharge gap of 2.5 eV. The single and concentric split-ring resonators had the same maximum measured plasma density of 1.19 × 1017 m−3. Plots of the measured properties and comparisons with electric field simulations show the field coupling to the concentric ring and ignition produced in the secondary discharge gap. The concentric ring resonator has more spatially uniform temperature and density distributions relative to the single split-ring resonator.

An efficient compact-2D finite-difference time-domain method is presented for the numerical analysis of guided modes in waveguides that may include negative dielectric permittivity, negative magnetic permeability and negative refractive index materials. Both complex variable and real variable methods are given. The method is demonstrated for the analysis of channel-plasmon-polariton guided modes in triangular groves on a metal surface. The presented method can be used for a range of waveguide problems that were previously unsolvable analytically, due to complex geometries, or numerically, due to computational requirements of conventional three-dimensional finite-difference time-domain methods. A three-dimensional finite-difference time-domain algorithm that also allows analysis in the presence of bound or free electric and equivalent magnetic charges is presented and an example negative refraction demonstrates the method.

We reported Ce and its oxide-modified TiO2 nanotube arrays (TNTs) and their semiconductor properties. The TNTs were prepared by anodic oxidation on pure Ti and investigated by electrochemical photocurrent response analysis. Then, the TNT electrodes were deposited of Ce by cathodic reduction of Ce(NO3)3 6H2O. After deposition, the TNT electrodes were fabricated by anodic oxidation at E = 1.0 V(SCE) for various electricity as Ce-Ce2O3-CeO2 modification. The Ce-deposited TNTs (band gap energy Eg = 2.92 eV) exhibited enhanced photocurrent responses under visible light region and indicated more negative flat band potential (Efb) compared with the TNTs without deposition. After anodic oxidation, the mixed Ce and its oxide (Ce2O3-CeO2)-modified TNT photoelectrodes exhibited higher photocurrent responses under both visible and UV light regions than the TNTs without deposition. The photocurrent responses and Efb were found to be strongly dependent on the contents of Ce2O3 and CeO2 deposited on TNTs. A new characteristic of Eg = 2.1 ± 0.1 eV was investigated in the Ce2O3- and CeO2-modified photoelectrodes. X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were also employed to characterize various modified TNTs photoelectrodes.

Theoretical study on the electronic structure, optical and photocatalytic properties of type-II As/CdO van der Waals heterostructure

This paper had been comparing the performance of the normal patch antenna with single complimentary SRR patch antenna. Four different shapes of single complimentary split ring resonator structure had been incorporated into the microstrip patch antenna - square, circular, triangular, and rhombic. This simulation works had been done in CST Microwave Studio simulation software. The operating frequency of this antenna is 2.40 GHz for Wireless Local Area Network (WLAN) application. The parameters that considered in these works are return loss, resonant frequency, input impedance, gain, radiation pattern and bandwidth. The focusing parameter is to achieve the best gain performance that obtained from the single complimentary split ring resonator patch antenna. The addition of square SRR onto patch antenna will improve the gain from 6.334 dB to 6.508 dB.

Inspired by the dendritic geometry in nature, we designed the single dissymmetrical hexagonal split ring resonators (SRRs). The SRRs were fabricated on one side of the dielectric substrate using shadow mask/etching technique. By experiments and computer simulations, we have researched the microwave transmission behavior of the SRRs in the frequency band of 7—12 GHz. The results show that, for an individual hexagonal SRR, the resonance frequency is affected by the size of the SRR; for two SRRs, there are two resonance peaks in the transmittion curve when they are close to each other. For three SRRs or the radialized rings, the resonance frequency of the structure with high-level branches shifts towards lower values compared with that with no branches. The simulations are in agreement with the experimental results.

To improve photocatalytic activity of a coordination polymer (CP) in the visible light region, five different transition metal ions (Fe(3+), Cr(3+), Ru(3+), Co(2+) and Ni(2+)) were introduced into its framework through an ion-exchange process. Among all the resulting transition metal ion doped coordination polymers (TMI/CPs), the one doped with Fe(3+) took on the most excellent photocatalytic activity and the highest quantum yields in the visible light region, decomposing 94% Rhodamine B (RhB) in 8 hours. It can be attributed to the doping of Fe(3+), which reduced the band gap (Eg) of the original CP, facilitating photocatalysis of the obtained polymer. Compared with the coordination polymer with Fe(3+) as a dopant, products doped with other metal ions presented weaker photocatalytic activities in the visible light region, while under the irradiation of ultraviolet light, they showed favorable photocatalytic properties. The results suggest that to dope transition metal ions into the framework of CPs would be an ideal option for enhancing the photocatalytic activity of coordination polymers.

TiO2-TiN composite catalysts were prepared by oxidizing the TiN films in air at 350 °C. By adjusting the oxidation time to control the oxidation stage of TiN films, the optical band gap of the TiO2-TiN composites can be varied in a wide range from 1.68 eV to 3.23 eV. These composite films all showed red shift in photo-response towards the visible region, and depending on the optical band gap, some composite films exhibited good catalytic activity in the visible light region. This study provides a simple but effective method to prepare film photocatalyst working in visible light.

Visible light induced dye-sensitized photocatalytic hydrogen production over platinized TiO2 derived from decomposition of platinum complex precursor

A chiral and thermally irreversible photochromic fulgide derivative incorporating an (R)-binaphthol unit in its acid anhydride moiety was used for the photoswitching of the pitch length of cholesteric liquid crystals. Since the absorption maximum wavelengths of both thermally stable photoisomers are nearly in the UV region (quasi-stealth photochromism), it can be exposed to visible light without inducing photochromic reactions. Therefore, when the photoswitching molecule is added to a permanent cholesteric liquid crystal whose reflection light wavelength is in the visible region, the UV light-induced photochromic reaction of the photoswitching molecule changes the wavelength of the reflection light in the visible light region. We have succeeded in regulating the color of cholesteric liquid crystalline cells between red and blue upon UV light irradiation. Attempts to introduce this system in polymer dispersed cholesteric liquid crystals are also described.

The effect of polyethylene glycoldiacrylate complexation on type II photoinitiator and promotion for visible light initiation system

Pd and Pt modified N-doped titania nanoparticle powders were prepared by a facile sol-gel method. Nitrogen doping and metal modification were carried out simultaneously during the preparation pro- cess. The as-prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy and X-ray photoelectron spectroscopy (XPS). The visible light photocatalytic activities of the as prepared samples were evaluated by analyzing their effect on the photocatalytic decomposition of methyl orange (MO). The chemical state of the metal is the key factor determining the performance of metal modified N-doped titania. The Pd used to modify the N-doped titania (Pd-NT) in our study was of the PdOx(x≤2) species, which increased the absorbance in the visible light region, decreased the recombination of photo-generated electron-hole pairs, and resulted in a significant enhancement in the visible light photocatalytic activity. The Pt species used to modify the N-doped titania (Pt-NT) was mainly in the metallic state, which resulted in a decrease in the absorbance in the visible light region, and an increase in the recombination of photo-generated electron-hole pairs. Pt modification led to a deterioration in the visible light photocatalytic activity of the material.

Ag 2 O nanoparticles (NPs) were synthesized using colloidal solution of spherical polyelectrolyte brushes (SPB) as nano-reactors. In this work, the average diameter of Ag 2 O NPs was around 10 nm as determined by transmission electron microscopy (TEM). The composite NPs of Ag 2 O immobilized in SPB (Ag 2 O-SPB) showed significant absorption in the visible light region as confirmed by UV-Vis diffuse reflectance spectra (DRS), and their photoluminescence (PL) exhibited emission peak in the visible range. Ag 2 O-SPB has shown outstanding photocatalytic activity during degradation of methyl blue (MB) in the visible light. This work will open up a new way to prepare ideal Ag 2 O nano-catalyst for the remediation of wastewater using visible light.

The behavior of the state of liquid water is studied by means of changes of refractive indices of the visible light region based on the data of Tilton. A fairly simple model is assumed for the structure of liquid water. Lorentz-Lorenz's formula is employed for the molecular structure of liquid water. The visible light region is taken between the ultra-violet and the infra-red regions, and it is apart from the fundamental absorption bands or lines in both regions. Therefore, even though the contributions from the both regions to the behaviors of the refractive index may play a dominant role, but they can be treated in the simple form of Lorentz-Lorenz's formula. It is found that the behaviors of induced dipoles of liquid water are closely related with molecules and electron clouds. It is also found that when our improved theory is applied, many models of liquid water which have been proposed by many investigators can be understood consistently without any contradiction. It is shown that when ice t...

Nonmetallic materials with localized surface plasmon resonance (LSPR) have a great potential for solar energy harvesting applications. Exploring nonmetallic plasmonic materials is desirable yet challenging. Herein, an efficient nonmetallic plasmonic perovskite photoelectrode, namely, SrTiO3, with a periodically ordered nanoporous structure showing an intense LSPR in the visible light region is reported. The crystalline-core@amorphous-shell structure of the SrTiO3 photoelectrode enables a strong LSPR due to the high charge carrier density induced by oxygen vacancies in the amorphous shell. The reversible tunability in LSPR of the SrTiO3 photoelectrode was observed by oxidation/reduction treatment and incident angle adjusting. Such a nonmetallic plasmonic SrTiO3 photoelectrode displays a dramatic plasmon-enhanced photoelectrochemical water splitting performance with a photocurrent density of 170.0 μA cm-2 under visible light illumination and a maximum incident photon-to-current-conversion efficiency of 4.0% in the visible light region, which are comparable to the state-of-the-art plasmonic noble metal sensitized photoelectrodes.