New Surface Modification Method of Bio-titanium Alloy by EB Polishing

Rare earth solution (RES) surface modification and air-oxidation methods were used to improve the interfacial adhesion of the carbon fiber reinforced polyimide (CF/PI) composite. The mechanical and tribological properties of the PI composites reinforced by the carbon fibers treated with different surface modification methods were comparatively investigated. Results showed that both the strength parameters (tensile and flexural) of the CF/PI composites improved remarkably due to RES treatment along with enhancement in friction and wear performance.

A new surface modification for bio-titanium alloy products by electron beam (EB) polishing is proposed. In this EB polishing method, high energy density EB can be irradiated without concentrating the beam. Therefore, large-area EB with a maximum diameter of 60mm can be used for instantaneously melting or evaporating metal surface. Experimental results made it clear that surface characteristics, such as repellency, corrosion resistance and coefficient of friction could be improved simultaneously with the surface smoothing in a few minutes under a proper condition. Therefore, EB polishing method has a possibility of high efficient surface smoothing and surface modification process for bio-titanium alloy.

The modern textile fibre treatments aim to obtain the required level of beneficial effect while attempting to confine the modification to the fibre surface. Recently, much attention has been focused on different physical methods of fibre surface modification, cold plasma treatment being considered as very useful. Moreover, there are efficient chemical methods available, such as peroxide, biopolymer and enzyme treatment. Some interesting combinations of these physical and chemical surface modification methods as means to modify fibre surface topography and thus controlling the surface-related properties of the fibre are presented in this paper. The properties obtained are discussed on the basis of the physico-chemical changes in the surface layer of the fibre, being assessed by wettability and contact angle measurements, as well as by FTIR-ATR and XPS analysis. The SEM and AFM technique are used to assess the changes in the fibre surface topography and to correlate these changes to the effectiveness, uniformity and severity of the textile fibre surface modification treatments.

Influence of Cu-, Fe-, Co-, and Mn-oxide nanoclusters on sensing behavior of SnO 2 films

Cellular adhesion on surface structures from PA 2200 made through Selective Laser Sintering (SLS) process can be improved by modifying the parts surface. In this paper, different methods for surface modification are presented. The PA 2200 samples were immersed in six different solvents. SEM images and surface roughness tests were performed in order to evaluate the surface modification both for the control group and for the tested groups. The obtained results clearly show that there is a significant difference between the roughness of the control (untreated) surface and each of the treated surfaces. Modifying by immersion, of the PA 2200 structures produced by Selective Laser Sintering process, brings original approaches concerning the use of those procedures in the increase of the surfaces quality.

The article is an overview of various materials used in power hydraulics for basic hydraulic actuators components such as cylinders, cylinder caps, pistons, piston rods, glands, and sealing systems. The aim of this review is to systematize the state of the art in the field of materials and surface modification methods used in the production of actuators. The paper discusses the requirements for the elements of actuators and analyzes the existing literature in terms of appearing failures and damages. The most frequently applied materials used in power hydraulics are described, and various surface modifications of the discussed elements, which are aimed at improving the operating parameters of actuators, are presented. The most frequently used materials for actuators elements are iron alloys. However, due to rising ecological requirements, there is a tendency to looking for modern replacements to obtain the same or even better mechanical or tribological parameters. Sealing systems are manufactured mainly from thermoplastic or elastomeric polymers, which are characterized by low friction and ensure the best possible interaction of seals with the cooperating element. In the field of surface modification, among others, the issue of chromium plating of piston rods has been discussed, which, due, to the toxicity of hexavalent chromium, should be replaced by other methods of improving surface properties.

The inherent π-π interfacial interaction between carbon nanotubes (CNTs) and polystyrene (PS) makes the CNT/PS composite a representative thermoplastic nanocomposite. However, the strong van der Waals force among CNTs poses challenges to achieving effective dispersion. This review provides an overview of various CNT functionalization methods for CNT/PS composites, encompassing covalent grafting with PS-related polymers and non-covalent modification. A focus in this section involves the pre-introduction surface modification of CNTs with PS or PS-related polymers, substantially enhancing both CNT dispersibility and interfacial compatibility within the PS matrix. Furthermore, a comprehensive summary of the mechanical, electrical, thermal, and electromagnetic shielding properties of CNT/PS nanocomposites is provided, offering an overall understanding of this material. The surface modification methods of CNTs reviewed in this paper can be extended to carbon material/aromatic polymer composites, assisting researchers in customizing the optimal surface modification methods for CNTs, maximizing their dispersibility, and fully unleashing the various properties of CNTs/polymer composites. Additionally, high-performance CNTs/PS composites prepared using appropriate CNT modification methods have potential applications in areas such as electronic devices, sensors, and energy storage and conversion.

The study discusses the methods of surface modification methods for AISAI 316 L steel and Ti6Al4V ELI titanium alloy, dedicated to complex design implants used in bone surgery. Results of structural tests have been presented along with those evaluating the physicochemical properties of the formed surface layers. Clinical feasibility of the surface layers has also been evaluated.The developed surface modification methods improved the resistance to pitting, crevice and stress corrosion and ensured better biocompatibility. Moreover, the layers formed are marked by plasticity. Results of the tests performed show applicability of the evaluated methods of surface modification in complex shape implants for the clinical use.

Surface modification with polyethylene glycol–corn trypsin inhibitor conjugate to inhibit the contact factor pathway on blood-contacting surfaces

The aim of this study was to investigate and compare the surface characteristics and initial bioactivity of ceria-stabilized zirconia/alumina nanocomposite (NANOZR) with those of yttria-stabilized zirconia (3Y-TZP) and pure titanium (CpTi) following the use of three surface modification methods; polishing, sandblasting/acid-etching (SB-E) and electrochemical deoxidation (ECD). Physical properties including surface morphology, chemical composition, X-ray diffraction, surface wettability, surface roughness, and hardness were measured. Osteoblast-like MC3T3-E1 cells were used to examine cell morphology and attachment to the surfaces of the materials. ECD treated NANOZR (NANOZR-E) showed a well-arranged, self-organized microporous surface structure with significantly low contact angles when compared with the other specimens (p < 0.05). NANOZR-E also demonstrated a slight decrease in monoclinic phase content (-4.4 wt %). The morphology and attachment of MC3T3-E1 cells on NANOZR-E were similar to those on polished and SBE-treated CpTi surfaces. Higher cell affinity was observed on NANOZR-E when compared with ECD treated 3Y-TZP. The findings of this study indicate the effectiveness of the novel technique, ECD, in the formation of a microporous surface on NANOZR when compared with both CpTi and 3Y-TZP. Moreover, this method also appears to improve the biological activity of NANOZR during the initial stage. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 2641-2652, 2017.

Thermal spray coatings are a method of surface modification in which various metallic and non-metallic materials are sprayed in molten, semi-molten, or even solid state on a prepared substrate. The coating material is present in two forms: wire or powder. The most common thermal spraying techniques include cold spray, electric arc spray, plasma spray, detonation gun spray, flame spray, and high-velocity oxy-fuel spray. The coating's thickness, which is calculated in millimeters or microns and has distinguishing features from the base material's surface, is acceptable in many industrial sectors and is ideal for on-site industrial applications. These processes also offer affordable solutions in many industrial sectors and are capable of providing surface modification approaches with enhanced surface properties comprising better texture and high mechanical strength in terms of hardness, scratch resistance, and porosity. This chapter presents the evolution of coatings developed during the last few decades using various coating processes and materials for the protection of service components. Coating measures are developed for use in thermal power plants, gas steam, and the automotive industry for the treatment of components, able to work in harsh environments of flue gases and chemicals.

This paper proposes a method of modification of Hypoid gear tooth surface for giving smooth motion under any magnitude of gear axial torque. In this method, the small displacement of gear axis is represented by a screw motion around an instantaneous axis. And the total amount of the deflections of loaded teeth is assumed to be proportional to the torque. The latter assumption is checked by referring to the another publishes. When the gear axes displace slightly to each other, ideal tooth surfaces envelop each other along to a contact line that corresponds to a deflection of gear axis, and give smooth motion. This paper proposes a calculation method of tooth profile modification on a contact line for any amount of contact ratio. As an adoption, the contact line of tooth surface and the motion errors are analyzed for a practical Hypoid gear, and amount of tooth surface modifications is shown for the coast side surface of gear tooth.

An original protocol of simultaneous surface modification and transfer from aqueous to organic phases of anatase TiO2 nanoparticles (NPs) using alkylphosphonic acids (PAs) is studied. The influence of the solvent, the nature and concentration of the PA, and the size, concentration, and aggregation state of the TiO2 NPs was investigated. Complete transfer was observed for linear alkyl chains (5, 8, 12, and 18 C atoms), even at very high sol concentrations. After transfer, the grafted NPs were characterized by (31)P solid-state MAS NMR. The dispersion state of NPs before and after phase transfer was monitored by dynamic light scattering (DLS). Small-angle neutron scattering (SANS) was used to characterize the structure of PA-grafted NPs in the organic solvent. Using a quantitative core-shell model cross-checked under different contrast conditions, it is found that the primary particles making up the NPs are homogeneously grafted with a solvated PA-layer. The nanometric thickness of the latter is shown to increase with the length of the linear carbon chain of the PA, independent of the size of the primary TiO2 NP. Interestingly, a reversible temperature-dependent aggregation was evidenced visually for C18PA, and confirmed by DLS and SANS: heating the sample induces the breakup of aggregates, which reassemble upon cooling. Finally, in the case of NPs agglomerated by playing with the pH or the salt concentration of the sols, the phase transfer with PA is capable of redispersing the agglomerates. This new and highly versatile method of NP surface modification with PAs and simultaneous transfer is thus well suited for obtaining well-dispersed grafted NPs.

To improve the therapeutic efficacy of anticancer agents and extend their application, mussel-inspired chemical modifications have attracted considerable attention. Surface modification based on polydopamine (PDA) has been a facile and versatile method to immobilize biomolecules on substrates for targeted drug delivery. To better analyze pharmaceutical differences between PDA-based surface modification and traditional synthesis methods, we prepared two kinds of folate (FA)-targeted nanoparticles (NPs) loaded with paclitaxel (PTX). The resultant PTX-PDA-FA NPs and PTX-FA NPs represented PDA and synthesis strategies, respectively. PTX-PDA-FA NPs and PTX-FA NPs have been characterized. The particle size of PTX-PDA-FA NPs was smaller than that of PTX-FA NPs. The two kinds of NPs both exhibited long-rod morphology, good colloidal stability and sustained slow drug release. Cytotoxicity in vitro was evaluated, and antitumor efficacy was investigated against 4T1 tumor-bearing mice. The tumor targeting therapeutic index of PTX-PDA-FA NPs and PTX-FA NPs showed equivalent superior specificity compared to nontargeted groups, which indicated that FA successfully attached to the surface of NPs by the PDA method and that the antitumor effect was equivalent to that of FA-modified NPs prepared by the chemical synthesis method. These results further indicated that PDA, as a simple and effective chemical surface modification platform, could be developed and applied in targeted delivery systems.

Metallization of polymer through a novel surface modification applying a photocatalytic reaction