PMMA/HfO2 Passivation for Improved Gate Bias Stability and Suppressed Electrical Degradation in Solution-Processed Indium-Gallium-Zinc Oxide Thin-Film Transistors
Solution-processed indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) have been widely researched for various applications due to their excellent electrical properties, such as high on/off current ratio, good uniformity and low processing temperature. However, intrinsic defects, such as oxygen vacancy (Vo) and weakly bonded oxygen result in instability of solution-processed IGZO TFTs. Additionally, the adsorption of oxygen and water vapor from ambient atmosphere onto the exposed channel layer is considered as major factors for the degradation of the exposed IGZO TFTs. Under positive bias stress (PBS), the adsorption of oxygen molecules on the back channel can cause the capture of electrons, resulting in enhanced carrier depletion and a positive threshold voltage shift (ΔV TH).Hafnium oxide (HfO₂), when deposited via a sol-gel process, is commonly used as a passivation layer for IGZO TFTs due to its ability to enhance device stability. The diffusion of Hafnium(IV) ions (Hf4+) into the back-channel region effectively suppresses oxygen vacancies (Vₒ), which are a major source of electrical instability. However, this suppression can lead to a reduction in carrier mobility due to reduced carrier density or scattering at the interface. Moreover, excessive diffusion of Hf4+ or residual species from the low temperature sol-gel process potentially introduce new trap states at interface, leading to a degradation of both carrier mobility and subthreshold swing (SS).This study aims to improve the stability of IGZO TFTs while maintaining electrical performance using an organic-inorganic passivation layer. The passivation layer consists of a poly(methyl methacrylate) (PMMA)/HfO₂ double-stacked structure, both deposited via spin-coating, with thicknesses of approximately 145 and 7 nm, respectively. The PMMA layer serves as a buffer layer, offering smooth and pinhole-free coverage, while preventing the direct contact between inorganic layer and IGZO surface. The upper HfO₂ layer, derived from a sol-gel process, serves as a dense inorganic barrier on the PMMA film. It further enhances the overall barrier properties by providing a high-density protective film. Moreover, the double-stacked structure of the passivation layer extends the effective diffusion path of oxygen and improves barrier performance compared to single layer.Under a PBS test for 1000 s, ΔV TH of IGZO TFTs without passivation, with a PMMA single layer and with PMMA/HfO2 passivation were 8.4, 3.7, and 1.0 V, respectively, as shown in Fig. 1. Consequently, IGZO TFTs with organic-inorganic passivation layer, fabricated employing mild spin-coating processes, demonstrated greater stability under PBS tests. Additionally, IGZO TFTs with PMMA/HfO₂ passivation exhibited no significant degradation in electrical performance, maintaining a field-effect mobility of 1.25 cm²/V, as shown in Table 1.To evaluate the interface quality and investigate the charge trapping phenomenon, hysteresis characteristics were investigated, by applying gate voltage sweeps in the forward and reverse directions. As shown in Fig. 2, the hysteresis width was 0.65 (no passivation), 0.30 (PMMA), and 0.18 V (PMMA/HfO₂), respectively. Additionally, SS values for the IGZO TFTs without passivation, with a PMMA single layer and with PMMA/HfO2 passivation were 0.220, 0.206, and 0.182 V/dec, respectively, as summarized in Table 1. This progressive decrease in SS demonstrates that the PMMA/HfO2 structure improves the interface quality. Notably, the SS values before and after PBS test remained nearly unchanged for each individual device, indicating that the bias stress did not induce additional interface defects. The ΔV TH under PBS test decreased significantly from 8.4 (no passivation) to 3.7 (PMMA) and further to 1.0 V (PMMA/HfO₂), indicating that ambient-induced charge trapping is the dominant cause of instability, rather than defect formation, which can result in increased SS value. The double-stacked structure effectively suppresses the adsorption of ambient species to provide superior barrier properties compared to the single-layer PMMA passivation, thereby enhancing the bias stress stability with maintaining the electrical characteristics. Figure 1
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