This article deals with the development of the number of periodic solutions for ordinary differential equations. We investigated focal values for first-order non-autonomous differential equation for periodic solutions from a fine focus z = 0 . Periodic solutions with polynomial coefficients are executed for classes C 10 , 3 , C 10 , 4 , and C 10 , 5 . Limit cycles are found for both non-homogeneous and homogeneous polynomials with trigonometric coefficients for classes C 22 , 11 , C 24 , 12 and C 10 , 10 , respectively. We developed a formula ϰ 10 , which is not available in literature. By using our newly developed formula, we succeeded to find highest known multiplicity 10 for the classes C 10 , 3 , C 10 , 4 with algebraic and C 10 , 10 , C 24 , 12 with trigonometric coefficients. We present a variety of polynomial classes along with their bifurcation analysis which confirms the generality and authenticity of the method presented.