Photonic-crystal distributed-feedback quantum cascade lasers

Quantum cascade lasers are unipolar semiconductor lasers based on intersubband transitions in heterostructures. These lasers, which have demonstrated continuous wave operation at room temperature in the mid-infrared spectral range, are well suited for the realization of compact, ultra-sensitive, trace-gas sensors based on absorption spectroscopy. Up to now, only distributed feedback (DFB) single-mode devices have been used for such applications. DFB quantum cascade lasers have proven to be effective for gas sensing, but their relatively narrow tuning range, smaller or equal to about 1% of the wavelength, makes them not very versatile and limits their usefulness for spectroscopic investigations. In this thesis we developed broadly tunable external cavity quantum cascade lasers. The main advantage of these sources compared with DFBs is their broader tuning range, which is limited only by the spectral bandwidth of the gain element. We particularly studied broad gain bandwidth active regions based on bound-to-continuum designs. With that kind of active region, we have demonstrated a tuning range equal to 15% of the center wavelength at ~ 10 m, which was three times broader than the best values reported in the literature at that time, as well as good performance in pulsed mode at room temperature. Using a strain-compensated bound-to-continuum design emitting near 5.2 m, we have demonstrated for the first time continuous-wave operation of an external cavity quantum cascade laser on a thermoelectric cooler. The tuning range was comparable to that of pulsed devices, but with a much better side-mode suppression ratio and a much narrower linewidth. This continuous-wave device has successfully been applied to the spectroscopy of nitric oxide in collaboration with Prof. Tittel's Laser Science Group at Rice University. High resolution absorption spectra of that gas could be acquired over a large wavelength range. We also studied heterogeneous cascade structures, that is quantum cascade structures in which the various stages emit at several different wavelengths, as a way to increase further the tuning range of external cavity quantum cascade lasers. A pulsed laser tunable from 8.2 to 10.4 m, that is over 24% of the center wavelength has been realized using an active region composed of two substacks of bound-to-continuum designs. We conclude on the feasibility of room temperature, continuous-wave, broadly-tunable external cavity quantum cascade lasers in the mid-infrared spectral range. These devices will be useful for the analysis of multi-component gases, for high resolution spectroscopic investigations in fundamental science, and for the detection of heavy molecules with broad absorption features which DFB quantum cascade lasers cannot scan entirely.

We present the design and the performance of midinfrared distributed feedback (DFB) quantum cascade lasers (QCLs) made of strain balanced Ga <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1-x</sub> As/Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">y</sub> In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1-y</sub> As material on InP substrates for sensing CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> , N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O, and NO in the middle wavelength range of mid-IR from 4 to 6 μm. We present the performances of our DFB QCLs at three different aspects: high power, low threshold power consumption, and wide wavelength coverage. We demonstrated a continuous wave (CW) DFB QCL with an output power of 220mW at 20°C, a CW DFB QCL with low threshold voltage of 8V and low-divergent far-field angles of 27.5° × 32.9° by reducing the number of quantum cascaded stages, a CW DFB QCL with a low threshold power consumption of 0.7W by reducing doping density in the active core, and DFB QCLs wide wavelength coverage of 325 cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">-1</sup> , 16.9% of center wavelength at 5.2 μm, within one wafer by changing the grating period. 12 DFB QCL chips have being aged for 3000 h under 25°C and a constant quasi-CW current of 0.37 A. No decrease in power was observed.

Complex-coupled edge-emitting photonic crystal distributed feedback quantum cascade lasers at λ ∼ 7.6 μm

Two-segment distributed feedback (DFB) GaAs/AlGaAs bound-to-continuum quantum cascade lasers emitting at ∼10.8 µm were fabricated and investigated. Reversible switching between two different DFB modes by current injection control yielding sidemode suppression ratios up to >23 dB is reported. Two different devices were fabricated for which the distance between the different DFB modes is 1.5 and 2.5 cm−1, respectively, and quasi-continuous tuning over a range of >9 cm−1 (105 nm) between 120 and 250 K was observed.

We report on the development of λ ~ 4.7 μm continuous-wave (CW) operation of surface grating distributed feedback (DFB) quantum cascade lasers (QCLs). A high wall plug efficiency (WPE) of 7% is obtained at 15°C from a single facet producing over 0.85 W of CW output power. The threshold current density of DFB QCL is as low as 1.19 kA/cm at 15°C and 2.29 kA/cm at 90°C in CW mode. Single-mode operation with side mode suppression ratio above 25 dB is observed in the working temperature of 15°-95°C.

Nitrogen oxides (NOx), including nitric oxide (NO) and nitrogen dioxide (NO2) play important roles in determining the photochemistry of the ambient atmosphere, controlling the production of tropospheric ozone, affecting the concentration levels of the hydroxyl radical, and forming acid precipitation. A sensor system capable of simultaneous measurements of NO and NO2 by using a commercial 76 m astigmatic multi-pass gas cell (MPGC) was developed in order to enable fastresponse NOx detection. A continuous wave (CW), distributed-feedback (DFB) quantum cascade laser (QCL) and a CW external-cavity (EC) QCL were employed for targeting a NO absorption doublet at 1900.075 cm-1 and a NO2 absorption line at 1630.33 cm-1, respectively. Both laser beams were combined and transmitted through the MPGC in an identical optical path and subsequently detected by a single mid-infrared detector. A frequency modulation multiplexing scheme was implemented by modulating the DFB-QCL and EC-QCL at different frequencies and demodulating the detector signal with two Labview software based lock-in amplifiers to extract the corresponding second-harmonic (2f) components. Continuous monitoring of NO and NO2 concentration levels was achieved by locking the laser frequencies to the selected absorption lines utilizing a reference cell filled with high concentrations of NO and NO2. The experimental results indicate minor performance degradation associated with frequency modulation multiplexing and no cross talk between the two multiplexed detection channels. The performance of the reported sensor system was evaluated for real time, sensitive and precise detection of NO and NO2 simultaneously.

A sensor system capable of simultaneous measurements of NO and NO2 was developed using a wavelength modulation-division multiplexing (WMDM) scheme and multi-pass absorption spectroscopy. A continuous wave (CW), distributed-feedback (DFB) quantum cascade laser (QCL) and a CW external-cavity (EC) QCL were employed for targeting a NO absorption doublet at 1900.075 cm−1 and a NO2 absorption line at 1630.33 cm−1, respectively. Simultaneous detection was realized by modulating both QCLs independently at different frequencies and demodulating the detector signals with LabView-programmed lock-in amplifiers. The sensor operated at a reduced pressure of 40 Torr and a data sampling rate of 1 Hz. An Allan–Werle deviation analysis indicated that the minimum detection limits of NO and NO2 can reach sub-ppbv concentration levels with averaging times of 100 and 200 s, respectively.

In this paper, we present the theoretical investigation of index-coupled distributed feedback (DFB) laser with tilted single mode ridge waveguides. By tilting part of the ridge waveguide in various degrees, DFB laser with manifold effective grating periods can be realized. The structure is analyzed using couple mode theory in matrix form based on threshold analysis. Important parameters of DFB laser like resonant frequency and threshold gains are obtained by solving the eigen-equation. The results indicate not only that the lasing frequency is modulated by the waveguide titling angle, but also large Gain Margin (GM) can be achieved at the threshold condition which enhance the stable single mode operation in index-coupled DFB laser.

We present the electrical and optical characterization and theoretical modeling of the transient behavior of regular 4.5-μm single-mode emitting distributed feedback (DFB) quantum cascade lasers (QCLs). Low residual capacitance together with a high-frequency optimized three-terminal coplanar waveguide configuration leads to modulation frequencies up to 23.5 GHz (optical) and 26.5 GHz (electrical), respectively. A maximum 3-dB cut-off value of 6.6 GHz in a microwave rectification scheme is obtained, with a significant increase in electrical modulation bandwidth when increasing the DC-current for the entire current range of the devices. Optical measurements by means of FTIR-spectroscopy and a heterodyne beating experiment reveal the presence of a resonance peak, due to coupling of the lasing DFB- with its neighboring below-threshold Fabry-Pérot-(FP-)mode, when modulating around the cavity roundtrip frequency. This resonance is modeled by a 2-mode Maxwell-Bloch formalism. It enhances only one sideband and consequently leads to the first experimental observation of the single-sideband regime in such kind of devices.

Mid infra-red absorption spectrometry based on continuous-wave distributed feedback (DFB) quantum cascade laser (QCL) is more and more widely used for trace gas detection and pollution monitoring. The main advantages of this technique are high sensitivity, high selectivity and a potential for extreme compactness. Various examples of trace gas detection for atmospheric detection will be presented in this paper. Commercial QCLs available on the shelves were first implemented. A cryogenic QCL emitting at 6.7 μm was used to demonstrate the detection of water vapor and its isotopes. A room-temperature QCL was then used to simultaneously detect methane and nitrous oxide at 7.9 μm. Recently, we have developed a room-temperature top grating DFB QCL designed around 4.5 μm for the demonstration of N2O detection in the ppb range. Atmospheric applications of these spectrometers will be presented. The improvements of QCL performances make it now possible to develop instruments that are more and more compact and therefore compatible with in situ applications.

Distributed feedback (DFB) lasers are used extensively as optical sources within fiber optic telecommunications systems. These semiconductor lasers are valued for their single optical mode operation which enables their use in high bit rate digital and broadband analog transmission systems. We discuss requirements imposed upon DFB lasers used in such applications. We briefly review and illustrate general techniques for modeling DFB laser operation by comparison of measured and modeled device characteristics below and above lasing threshold. We focus on the phenomenon of spatial hole burning which substantially affects operation of all DFB lasers, especially those tailored to produce high fiber coupled power from a single mirror facet. We illustrate insights gained by measurement and modeling of DFB lasers using as an example the particular case of analog transmission of multichannel video signals.

In this paper we present an experimental analysis of the effect of RF modulation injection current in DFB and FP lasers nearthe first period doubling bifurcation (PDB). By increasing the amplitude of the modulation frequency at the onset of PDB thefirst results of a virtual Hopf phenomenon like behavior has been observed in both types of lasers. We characterized thisobservation by increasing the amplitude of the current modulation where two peaks appear in the spectrum, approaching oneto the other until fmally merging the onset of period doubling bifurcation as predicted by theory. The same virtual Hopfbehavior was observed when we set the amplitude modulation at a fixed value and we sweep the frequency modulation at theonset of the PDB point.Keywords: Laser Diode, Nonlinear Dynamics, Period Doubling Bifurcations. 1. INTRODUCTION Nonlinear dynamics in diode lasers has been the subject of many theoretical and experimental investigations in the lastdecade as they show a rich variety of irregular behavior in their route to chaos1. A single frequency diode laser is commonlystudied by a rate equation model which describes the time evolution of the photon and carrier densities. In these equations,the inclusion of an additional degree of freedom as modulation of the injection current, external light injection or opticalfeedback is needed for nonlinear dynamics to appear2.To our knowledge, the nonlinear behavior in semiconductor diode lasers has been extensively studied by many authors usingdelayed optical feedback and strong current modulation. In the former, the observed route to chaos was through successivesubharmonic bifurcations or by quasi periodic route3'4. In the strong current modulation case the period sequence wastruncated by period tripling before the onset of chaos5'6.On the other hand, the onset of a period doubling bifurcation point in many physical systems brings to nonlinear phenomenasuch as: 1) small signal amplification, 2) shift and suppression of the bifurcation point and 3) the emergence of a closelyspaced set of peaks in the frequency response7.In semiconductor lasers the parametric amplification was observed by Harth and co-workers8'9 which was analyzed byWiesenfeld few years after'°. In the study developed by Wiesenfeld in ref. 10, semiconductor lasers were proposed as goodcandidate to study the rich variety of nonlinear phenomena near period doubling bifurcations. A recent study has shown thatthe effect of Langevin noise in period doubling semiconductor lasers has a virtual Hopf ur12 previously predicted byWiesenfeld'34 as a virtual Hopf phenomenon in systems undergoing a period doubling bifurcations in the presence ofexternal noise.In the present study we have experimentally investigated the nonlinear dynamics of diode lasers in the period doublingbifurcation point. We study the influence of the amplitude modulation in Distributed Feedback (DFB) lasers near perioddoubling bifurcations. In Fabry-Perot (FP) lasers we performed as well the same study as DFB lasers and the analysis of thefrequency modulation near period doubling bifurcation. So in section II we described the experimental procedure for theonset of the first period doubling bifurcation performed in commercial DFB and FP InGaAsP diode lasers at 1,3 tm emission

We demonstrate surface-grating distributed feedback quantum cascade lasers (QCLs) with a watt-level power output at 4.75 μm. A device with a 5 mm cavity length exhibits an output power of 1.1 W in room-temperature cw operation. Single-mode operation with a side mode suppression ratio of 30 dB is obtained in the working temperature of 15–105 °C. A double-lobed far field with negligible beam steering is observed. The significance of this demonstration lies in its simplicity and readiness to be applied to standard QCL wafers with the promise of high-power performances.

We propose a new kind of distributed feedback (DFB) semiconductor laser based on the sampled Moire grating (SMG) integrated with a grating reflector (GR). Coupling coefficient along the laser cavity can be controlled, and $\pi $ phase shift ( $\pi $ -PS) can be introduced by SMG. The GR, which is a uniform sampled grating, can provide light reflection instead of high reflection (HR) facet coating. Thus, the front and rear facets are both coated with anti-reflection coatings (AR/AR) to avoid the influence of random grating phase at the HR facet. Therefore, more output power, better single longitudinal mode (SLM) operation, and higher wavelength precision can be simultaneously achieved, compared with traditional DFB lasers with AR/HR facet coatings. As an example, an 8-channel DFB laser array based on the proposed structure has been simulated. The proposed laser may benefit the applications requiring both high output power and wavelength precision, such as wavelength division multiplexing (WDM) transmission systems and gas sensors.

A great improvement in the high-speed characteristics for compressively strained multi-quantum-well (MQW) distributed-feedback (DFB) lasers with self-aligned constricted mesa structures is described. Negative wavelength detuning is an important factor in making possible the extraction of potential advantages for the compressively strained MQW DFB lasers. A 17-GHz bandwidth, which is the highest among the 1.5- mu m MQW DFB lasers, is demonstrated. A wavelength chirp width of 0.42 nm at 10 Gb/s is obtained due to a reduced linewidth enhancement factor that has a magnitude of less than 2. Nonlinear damping K factor in a DFB laser with 45-nm negative detuning has drastically decreased to 0.13 ns, about half of that for unstrained MQW lasers. This is mainly due to an enhanced differential gain as large as 6.9*10/sup -12/ m/sup 3//s. The estimated intrinsic maximum bandwidth is 68 GHz. >