Planar chiral metamaterials for biosensing applications

Optical chirality is highly demanded for biochemical sensing, spectral detection, and advanced imaging, however, conventional design schemes for chiral metamaterials require highly computational cost due to the trial-and-error strategy, and it is crucial to accelerate the design process particularly in comparably simple planar chiral metamaterials. Herein, we construct a bidirectional deep learning (BDL) network consists of spectra predicting network (SPN) and design predicting network (DPN) to accelerate the prediction of spectra and inverse design of chiroptical response of planar chiral metamaterials. It is shown that the proposed BDL network can accelerate the design process and exhibit high prediction accuracy. The average process of prediction only takes ∼15 ms, which is 1 in 40000 compared to finite-difference time-domain (FDTD). The mean-square error (MSE) loss of forward and inverse prediction reaches 0.0085 after 100 epochs. Over 95.2% of training samples have MSE ≤ 0.0042 and MSE ≤ 0.0044 for SPN and DPN, respectively; indicating that the BDL network is robust in the inverse deign without underfitting or overfitting for both SPN and DPN. Our founding shows great potentials in accelerating the on-demand design of planar chiral metamaterials.

Chiral metamaterial absorbers are instrumental in a wide array of applications, encompassing multifaceted optoelectronic devices, information-encrypting metamaterials, and thermal-controlled imaging and detection systems. In this study, we showcase a Ꞩ-shaped chiral metamaterial integrated with a vanadium dioxide substrate, which enables dynamic tuning of terahertz (THz) dual-band circular dichroism (CD). This absorber boasts spin-selective absorption, stemming from the selective excitation of the plasmon polaron mode on its horizontal microrod. Notably, right-handed circularly polarized light (CPL) experiences near-perfect absorption at resonance, whereas left-handed circular polarization is absorbed to a much lesser degree, yielding pronounced CD. This exceptional chiral selectivity facilitates dual-band CD effects, with peak values reaching 0.814 and 0.784. Furthermore, by manipulating the conductivity of vanadium dioxide, we can dynamically adjust both the CD and absorption peaks of the chiral metamaterial. The maximum modulation depth of the CD response can attain values as high as 0.807 and 0.776. Our work presents a novel design strategy for the active control and modulation of CPL, thereby expanding the horizons of metamaterial absorber applications within the THz spectrum.

Circular dichroism (CD) of chiral metamaterials is of significant interest for bio-sensing and molecular chemistry applications. In this study, using the gammadion shape as an example, the CD effect of gammadion-shaped chiral metamaterials is investigated. We view the gammadion as four Γ-shaped structures. The CD effect of the gammadion is induced by the conductive and magneto-inductive coupling between the weak and strong magnetic fields of the Γ-shaped structures. A large CD effect can be achieved because the magnetic fields excited by the conductive and magneto-inductive coupling show the same and opposing directions for right- and left-handed circular-polarized waves, respectively. This allows analysis of the origin of plasmonic modes in the CD spectrum. We can change the CD effect by changing the conductive and magneto-inductive coupling of the magnetic fields. The CD properties can be tuned by changing either the number of Γ-shaped structures or the layer spacing. These results may guide the design of chiral metamaterials at terahertz frequencies for achieving large CD effects. Furthermore, this approach can be applied to other complex planar structures to gain further insight on the origin of CD modes.

In this article, recent progress and development of terahertz chiral metamaterials including stereometamaterials are thoroughly reviewed. This review mainly focuses on the fundamental principles of design and arrangement of meta-atoms in metamaterials exhibiting chirality with various asymmetry and symmetry and 2D and 3D configuration. Related optical and propagation properties in chiral metamaterials, such as optical activity, circular dichroism, and negative refraction for each different chiral metamaterials, are compared and investigated. Finally, comparison between chiral metamaterials with stereometamaterials in terms of the polarization selective operation along with the similarity and the distinction is addressed as well.

We present two kinds of novel nanoimprint lithography techniques based on SU-8 photoresist with single layer and tri-layer approaches. The imprint templates with high aspect ratio were first fabricated by electron beam lithography (EBL) and reactive ion etch (RIE), and then duplicated by the SU-8/SiO <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</inf> /PMMA tri-layer technique we developed. Imprint properties such as pressure and temperature are determined to fabricate different nanostructures with various imprint depth. The developed processes, which provide us the capability to fabricate both imprinted nanostructures on resist and transferred nanopatterns on substrate with high volume and low cost, are further applied in producing high density gratings, planar chiral photonic metamaterials, and nanofluidics channels.

In this paper, a multi-band chiral metamaterials (CMMs) based on complementary cross-wire structure is proposed and studied numerically. The finite element method (FEM) method was used to simulate the EM properties of the designed structure. Numerical results indicate that the giant optical activity and multiband negative refractive index can be realized in terahertz region. The proposed CMMs may have some potential applications in novel terahertz device.Particle size of bayerite (d50) was about 24 μm. Al2O3was obtained after calcination at 1050 °C for 1.5 h.

Chiral metamaterials represent a special type of artificial structures that cannot be superposed to their mirror images. Due to the lack of mirror symmetry, cross-coupling between electric and magnetic fields exist in chiral mediums and present unique electromagnetic characters of circular dichroism and optical activity, which provide a new opportunity to tune polarization and realize negative refractive index. Chiral metamaterials have attracted great attentions in recent years and have given rise to a series of applications in polarization manipulation, imaging, chemical and biological detection, and nonlinear optics. Here we review the fundamental theory of chiral media and analyze the construction principles of some typical chiral metamaterials. Then, the progress in extrinsic chiral metamaterials, absorbing chiral metamaterials, and reconfigurable chiral metamaterials are summarized. In the last section, future trends in chiral metamaterials and application in nonlinear optics are introduced.

A chiral metamaterial based on a double-layer twisted Y shape structure is presented that achieves obvious circular dichroism and giant optical rotation at different frequencies. When a y-polarized wave is incident to this chiral metamaterial, circular dichroism with a great difference between the transmission coefficients for the circularly polarized waves is obtained at 12.28 GHz. Meanwhile, 90° optical rotation is observed at 12.70 GHz, where the incident y-polarized wave is transformed into its cross-polarization with a transmission coefficient of -1.15 dB. Surface current distributions are calculated to demonstrate the coupling between the electric and magnetic fields.

We propose a new uniaxial chiral metamaterial which is composed of four crescent shaped split-ring resonators mutually twisted by 90° and patterned on opposite sides of a dielectric substrate. It illustrates a strong optical activity and circular dichroism in the range from 5 GHz to 10 GHz. The presented design can be fabricated more easily due to its efficient metallic structures. Furthermore, chirality value of this proposed chiral metamaterial is large enough the optical applications. This study also shows that the proposed crescent shaped chiral metamaterials have good responses when compared with other studied samples in literature. All validations are performed by computer simulation program CST Microwave Studio in the 5–10 GHz frequency range.

In recent years, considerable research has been carried out relative to the electromagnetic (EM) propagation and refraction characteristics in metamaterials with emphasis on the origins of negative refractive index. Negative refractive index may be introduced in metamaterials via different methods; one such is the con- dition whereby the Poynting vector of the EM wave is in opposition to the group velocity in the material. Alternatively, negative refractive index also occurs when the group and phase velocities in the medium are in opposition. The latter phenomenon has been extensively investigated in the literature, including recent work involving chiral metamaterials with material dispersion up to the first order. This paper examines the pos- sible emergence of negative refractive index in dispersive chiral metamaterials with material dispersion up to the second order. The motivation is to determine if using second- as opposed to first-order dispersion may lead to more practical negative index behavior. A spectral approach combined with a slowly time-varying phasor analy- sis is applied, leading to the analytic derivation of EM phase and group velocities, and the resulting phase and group velocities and the corresponding phase and group indices are evaluated by selecting somewhat arbitrary dispersive parameters. The results indicate the emergence of negative index (via negative phase indices along with positive group indices, as reported in the literature) or negative index material (NIM) behavior over infor- mation bandwidths in the low RF range. The second-order results are not significantly better than those for first-order results based on the theoretical analysis; however, greater parametric flexibility exists for the second-order system leading to the higher likelihood of achieving NIM over practical frequency bands. The velocities and indices computed using the Lorentzian and Condon models yield an NIM bandwidth around 200 − 400 Mrad∕sec, about 2 orders of magnitude higher than that for the parametric approach; more impor- tantly, NIM is found not to occur in the first order when using practical models. © 2015 Society of Photo-Optical

In this paper, a dualband chiral metamaterial (CMM) based on cross-wire structure is proposed and studied numerically. It exhibits dual-band giant optical activity and negative refractive index in terahertz region. The surface current distributions are calculated to explain original physics. The further numerical results show that the efiective frequency bands of the CMMs can be independent adjusted easily by changing the structure geometrical parameter. The designed dual-band terahertz CMMs ofier ∞exibility in the investigation of novel terahertz device application.

Terahertz angle-insensitive 90° polarization rotator using chiral metamaterial

A complementary Y-shaped chiral metamaterial (CYCMM) is proposed for the realization of giant optical activity and circular polarization with strong circular dichroism (CD) simultaneously for terahertz (THz) waves. It is demonstrated that the proposed CYCMM can achieve 90° linear polarization rotation around 2.13 THz and a giant CD effect at 2.38 THz through full-wave simulations. The mechanism of the giant CD effect and optical activity is illustrated by simulated surface current distribution. Due to strong optical activity and the CD effect, the proposed CYCMM is useful for the development of integrated terahertz spectroscopic and imaging devices.

A model-agnostic data enhancement (MADE) algorithm is proposed to comprehensively investigate the circular dichroism (CD) properties in the higher-order diffracted patterns of two-dimensional (2D) chiral metamaterials possessing different parameters. A remarkable feature of MADE algorithm is that it leverages substantially less data from a target problem and some training data from another already solved topic to generate a domain adaptation dataset, which is then used for model training at no expense of abundant computational resources. Specifically, nine differently shaped 2D chiral metamaterials with different unit period and one special sample containing multiple chiral parameters are both studied utilizing the MADE algorithm where three machine learning models (i.e, artificial neural network, random forest regression, support vector regression) are applied. The conventional rigorous coupled wave analysis approach is adopted to capture CD responses of these metamaterials and then assist the training of MADE, while the additional training data are obtained from our previous work. Significant evaluations regarding optical chirality in 2D metamaterials possessing various shape, unit period, width, bridge length, and separation length are performed in a fast, accurate, and data-friendly manner. The MADE framework introduced in this work is extremely important for the large-scale, efficient design of 2D diffractive metamaterials and more advanced photonic devices.

In this paper, a terahertz chiral metamaterial (CMM) with complementary U-shaped structure assembly is proposed. The results exhibit that the strong circular dichroism, giant optical activity, and negative refraction could be obtained by numerical simulation and effective EM scattering parameters retrieval method.