Quantum cascade laser frequency comb at λ ~ 5.3 μm with double-plasmon waveguide design

We demonstrate what we believe to be a novel method for dispersion compensation in short-wavelength quantum cascade lasers (QCLs) for frequency comb operations. The addition of two highly doped InP plasmon layers below and above the active region, and the precise control of the distance between them and their dimensions, enables the engineering of waveguide structures with small group velocity dispersion around any central wavelength between 4 and 6 µm, while keeping the optical losses low. Based on this design, we show a highly-efficient frequency comb operation at 5.3 µm that exhibits up to 350 mW of output power, and operates in coherent comb mode up to 50°C. This result paves the way for robust fabrication of efficient, short-wavelength QCL frequency combs.

The present study proposes a terahertz quantum cascade laser frequency comb (THz QCL FC) with a semi-insulated surface plasma waveguide characterized by a low threshold current density, high power and a wide current dynamic range. The gain dispersion value and the nonlinear susceptibility were optimized based on the combination of a hybrid bound-to-continuum active region with a semi-insulated surface plasmon waveguide. Without any extra dispersion compensator, stable frequency comb operation within a current dynamic range of more than 97% of the total was revealed by the intermode beat note map. Additionally, a total comb spectral emission of about 300 GHz centered around 4.6 THz was achieved for a 3 mm long and 150 µm wide device. At 10 K, a maximum output power of 22 mW was obtained with an ultra-low threshold current density of 64.4 A·cm-2.

The effect of spatial hole burning on mode proliferation has been shown both theoretically and experimentally to be important for frequency comb operation in quantum cascade lasers (QCLs). It is therefore of great interest to investigate the frequency comb operation from integrated ring cavities where this effect is absent. Here we report a mid-infrared quantum cascade laser based on a buried heterostructure ring cavity that exhibits unidirectional lasing with a frequency comb spectrum displaying a predominantly s e c h 2 profile over a bandwidth of ∼ 10 − 1 . A single beat note with 3 dB linewidth of < 900 H z was observed over the last 85% of the whole current dynamic range. To further verify the frequency comb operation, a multiheterodyne experiment was carried out using a standard Fabry–Pérot QCL comb as a reference laser. This measurement allowed the retrieval of the spectral phases, indicating an operation with strong amplitude modulation.

Stable operation is one of the most important requirements for a laser source for high-precision applications. Many efforts have been made to improve the stability of lasers by employing various techniques, e.g., electrical and/or optical injection and phase locking. However, these techniques normally involve complex experimental facilities. Therefore, an easy implementation of the stability evaluation of a laser is still challenging, especially for lasers emitting in the terahertz (THz) frequency range because the broadband photodetectors and mature locking techniques are limited. In this work, we propose a simple method, i.e., relative phase locking, to quickly evaluate the stability of THz lasers without a need of a THz local oscillator. The THz laser system consists of a THz quantum cascade laser (QCL) frequency comb and a single-mode QCL. Using the single-mode laser as a fast detector, heterodyne signals resulting from the beating between the single-mode laser and the comb laser are obtained. One of the heterodyne beating signals is selected and sent to a phase-locked loop (PLL) for implementing the relative phase locking. Two kinds of locks are performed by feeding the output error signal of the PLL, either to the comb laser or to the single-mode laser. By analyzing the current change and the corresponding frequency change of the PLL-controlled QCL in each phase-locking condition, we, in principle, are able to experimentally compare the stability of the emission frequency of the single-mode QCL (fs) and the carrier envelope offset frequency (fCEO) of the QCL comb. The experimental results reveal that the QCL comb with the repetition frequency injection locked demonstrates much higher stability than the single-mode laser. The work provides a simple heterodyne scheme for understanding the stability of THz lasers, which paves the way for the further locking of the lasers and their high-precision applications in the THz frequency range.

The frequency comb which is characterized by equally-spaced frequency lines with high mode coherence has received much attention since its first demonstration in near-infrared and optical frequency range. In the terahertz frequency range, the electrically-pumped terahertz quantum cascade laser (THz QCL) based on semiconductors is an ideal candidate for achieving frequency comb operation in a frequency range between 1 THz and 5 THz. The group velocity dispersion (GVD) is a key factor for the frequency comb. A higher GVD can pull the frequencies from their equidistant values and limit the comb bandwidth. Therefore the laser dispersion needs to be compensated for in order to make the total GVD sufficiently low and flat, such as using a Gires-Tournois interferometer (GTI) or the double chirped mirror (DCM). However, a successful design still depends on the knowledge of the total GVD in the laser. In this paper, we show how to calculate the GVD in metal-metal waveguide THz QCLs by taking into account the dispersions from the GaAs material, the waveguide, and the laser gain, which conduces to the understanding of the frequency comb behavior. The waveguide loss is modelled by the finite element method. The loss due to intersubband absorption is calculated by Fermi's gold rule. All the losses, i.e., waveguide loss, mirror loss, and intersubband absorption loss, are summed up to calculate the clamped gain. The material loss can be calculated by using the reststrahlen band model. Because of these losses and gain, the refractive index needs to be replaced by a complex refractive index. The real part of the complex refractive index is the refractive index, which can be calculated from the Kramers-Kronig relationship that connects the loss or gain with the refractive index. Then the GVD introduced by the material loss, waveguide loss, and clamped gain can be finally calculated. The results show that the total GVD of THz QCL is approximately –8 × 10<sup>5</sup>~8 × 10<sup>5</sup> fs<sup>2</sup>/mm which is strongly determined by the clamped gain. Finally, the developed numerical model is employed to study the dispersion compensation effect of a GTI mirror which is coupled into a QCL gain cavity. The design of the THz QCL based on GTI structure is more flexible and feasible than that of the DCM. The result shows that by carefully designing the geometry of GTI, the dispersion of a THz QCL can be compensated for, thus achieving the broadband terahertz frequency combs.

We present our recent development of short wavelength quantum cascade lasers (QCLs) made of strain balanced GaxIn1-xAs/AlyIn1-yAs material on InP substrates. We demonstrate room temperature continuous-wave (CW) lasing of the fundamental lateral mode at four wavelengths of 4.6, 4.0, 3.8, and 3.5 μm. We obtained 60-mW CW output power at 10 °C and 3.55-μm wavelength, which is the shortest CW lasing wavelength demonstrated at room temperature by a QCL, to the best of our knowledge. We also performed a life test on λ = 4.6 μm QCL chips. To date, we have accumulated the life test data for more than 11 000 and 4100 h under two aging conditions, 20°C and 0.85-A constant current, and 60°C and 1-A constant current, respectively.

Multi-species detection of analytes in gas-phase by dual-comb spectroscopy using quantum cascade laser frequency combs is demonstrated. These chip-scale, electrically-pumped, semiconductor light sources are highly appealing for portable multi-component chemical spectroscopic sensors.

Miniaturized frequency comb sources across hard-to-access spectral regions, i.e. mid- and far-infrared, have long been sought. Four-wave-mixing based Quantum Cascade Laser combs (QCL-combs) are ideal candidates, in this respect, due to the unique possibility to tailor their spectral emission by proper nanoscale design of the quantum wells. We demonstrate full-phase-stabilization of a QCL-comb against the primary frequency standard, proving independent and simultaneous control of the two comb degrees of freedom (modes spacing and frequency offset) at a metrological level. Each emitted mode exhibits a sub-Hz relative frequency stability, while a correlation analysis on the modal phases confirms the high degree of coherence in the device emission, over different power-cycles and over different days. The achievement of fully controlled, phase-stabilized QCL-comb emitters proves that this technology is mature for metrological-grade uses, as well as for an increasing number of scientific and technological applications.

It was recently demonstrated that broadband quantum cascade lasers can operate as frequency combs. As such, they operate under direct electrical pumping at both mid‐infrared and THz frequencies, making them very attractive for dual‐comb spectroscopy. Performance levels are continuously improving, with average powers over 100mW and frequency coverage of 100 cm ‐1 in the mid‐infrared region. In the THz range, 10mW of average power and 600 GHz of frequency coverage are reported. As a result of the very short upper state lifetime of the gain medium, the mode proliferation in these sources arises from four‐wave mixing rather than saturable absorption. As a result, their optical output is characterized by the tendency of small intensity modulation of the output power, and the relative phases of the modes to be similar to the ones of a frequency modulated laser. Recent results include the proof of comb operation down to a metrological level, the observation of a Schawlow‐Townes broadened linewidth, as well as the first dual‐comb spectroscopy measurements. The capability of the structure to integrate monothically nonlinear optical elements as well as to operate as a detector shows great promise for future chip integration of dual‐comb systems.

Quantum cascade laser frequency combs are nowadays well-appreciated sources for infrared spectroscopy. Here their applicability for free-space optical communication is demonstrated. The spontaneously-generated intermodal beat note of the frequency comb is used as carrier for transferring the analog signal via frequency modulation. Exploiting the atmospheric transparency window at 4 µm, an optical communication with a signal-to-noise ratio up to 65 dB is realized, with a modulation bandwidth of 300 kHz. The system tolerates a maximum optical attenuation exceeding 35 dB. The possibility of parallel transmission of an independent digital signal via amplitude modulation at 5 Mbit/s is also demonstrated.

Mid-infrared (MIR) quantum cascade laser (QCL) frequency combs are an appealing technology for dual-comb spectroscopy as they cover strong absorption bands of many relevant molecules in the MIR region and enable measurements with sub-microsecond time-resolution permitting novel insights into dynamical processes [1] . The comb properties can be directly controlled through the QCL driving current, the chip temperature or by electrical injection of the repetition frequency [2] . Nevertheless, full mutual stabilization of a QCL dual-comb spectrometer (DCS) has not yet been reported. In this work, we demonstrate a DCS with full mutual stabilization in a master-follower (MF) scheme (also known as master-slave) and the coherent averaging of its signal.

We present a planarized double metal waveguide platform for THz quantum cascade laser frequency combs with a wide top metallization, extending above the surrounding low-loss BCB polymer. Compared to a standard double metal waveguide, improvements in waveguide losses, RF and thermal properties are observed. Tapered waveguide devices display a field-enhancing effect, improving comb performance due to the enhanced four wave mixing process. These devices feature strong free-running beatnotes up to nearly -30 dBm and comb operation at high temperatures up to 115 K in continuous wave.

Dual-comb spectroscopy of trace chemicals using mid-infrared quantum cascade laser frequency combs: recent advances and field applications

We demonstrate full stabilization of a mid-infrared quantum cascade laser frequency comb via radiofrequency injection with amplitude modulation. The stability of comb repetition frequency and offset frequency are both improved by an order of magnitude.

We demonstrate the implementation of external cavity optical feedback to improve coherence and promote generation of harmonic states by a mid-infrared quantum cascade laser frequency comb. In particular, we present a Vernier-like scheme to realize harmonic comb states that increase the repetition rate of the comb by a factor of up to 6 and broaden spectral coverages from 46 cm-1 to 92 cm-1. Intermode beatnote and dual comb characterization indicate that the coherence of the comb has greatly improved for sub-optimal devices when the comb is operated in these harmonic states. This approach to control the generation of harmonic states and improve comb performance can be readily incorporated to various sensing systems and has great potential in spectroscopic measurements that require high repetition rates and/or broad optical bandwidth.