Quantum thermodynamics with local control.

Stochastic Modeling of Gene Regulation by Noncoding Small RNAs in the Strong Interaction Limit

The thermodynamic behavior of out-of-equilibrium quantum systems in finite-time dynamics encompasses the description of energy fluctuations, which dictates a series of system's physical properties. In addition, strong interactions in many-body systems strikingly affect the energy-fluctuation statistics along a non-equilibrium dynamics. By driving transient currents to oppose the precursor to metal-Mott insulator transition in a diversity of dynamical regimes, we show how increasing correlations dramatically affect the statistics of energy fluctuations and consequently the quantum work distribution of finite Hubbard chains. Statistical properties of such distributions, as its skewness, that changes dramatically across the transition, can be related to irreversibility and entropy production. Even close to adiabaticity, the quasi quantum phase transition hinders equilibration, increasing the process irreversibility, and inducing strong quantum features in the quantum work distribution. In the Mott-insulating phase the work fluctuation-dissipation balance gets modified, with the irreversible entropy production dominating over work fluctuations. The effect of an interaction-driven quantum-phase-transition on thermodynamics quantities and irreversibility has to be considered in the design of protocols in small scale devices for application in quantum technology. Eventually, such many-body effects can also be employed in work extraction and refrigeration protocols at quantum scale.

ABSTRACTWe present an efficient method to obtain bulk isothermal compressibilities () and Kirkwood–Buff (KB) integrals of single- and multicomponent liquids using fluctuations of the number of molecules obtained from small-sized molecular dynamics simulations. We write finite-size versions of the Ornstein–Zernike and the KB integral equations and include there finite size effects related to the statistical ensemble and the finite integration volumes required in computer simulations. Consequently, we obtain analytical expressions connecting and the KB integrals in the thermodynamic limit (TL) with density fluctuations in the simulated system. We validate the method by calculating various thermodynamic quantities, including the chemical potentials of SPC/E water as a function of the density, and of aqueous urea solutions as a function of the mole fraction. The reported results are in excellent agreement with calculations obtained by using the best computational methods available, thus validating the method as a tool to compute the chemical potentials of dense molecular liquids and mixtures. Furthermore, the present method identifies conditions in which computer simulations can be effectively considered in the TL.

We investigate the 2- and 3-state ferromagnetic Potts models on the simple cubic lattice using the tensor renormalization group method with higher-order singular value decomposition (HOTRG). HOTRG works in the thermodynamic limit, where we use the Zq symmetry of the model, combined with a new measure for detecting the transition, to improve the accuracy of the critical point for the 2-state model by two orders of magnitude, obtaining Tc = 4.51152469(1). The 3-state model is far more complex, and we improve the overall understanding of this case by calculating its thermodynamic quantities with high accuracy. Our results verify that the first-order nature of the phase transition and the HOTRG transition temperature benchmarks the most recent Monte Carlo result.

Temperature is a fundamental concept in thermodynamics. In macroscopic thermodynamics, systems possess their own intrinsic temperature which equals the reservoir temperature when they equilibrate. In stochastic thermodynamics for simple systems at the microscopic level, thermodynamic quantities other than temperature (a deterministic parameter of the reservoir) are stochastic. To bridge the disparity in the perspectives about temperature between the micro- and macroregimes, we assign a generic mesoscopic N-body system an intrinsic fluctuating temperature T in this work. We simplify the complicated dynamics of numerous particles to one stochastic differential equationwith respect to T, where the noise term accounts for finite-size effects arising from random energy transfer between the system and the reservoir. Our analysis reveals that these fluctuations make the extensive quantities (in the thermodynamic limit) deviate from being extensive. Moreover, we derive finite-size corrections, characterized by heat capacity of the system, to the Jarzynski equality. A possible violation of the principle of maximum work that scales with N^{-1} is also discussed. Additionally, we examine the impact of temperature fluctuations in a finite-size Carnot engine. We show that irreversible entropy production resulting from the temperature fluctuations of the working substance diminishes the average efficiency of the cycle as η_{C}-〈η〉∼N^{-1}, highlighting the unattainability of the Carnot efficiency η_{C} for mesoscopic heat engines even under the quasistatic limit. Our general framework paves the way for further exploration of nonequilibrium thermodynamics and the corresponding finite-size effects in a mesoscopic regime.

We discuss the orbital angular momentum (OAM) and the edge mass current in neutral fermionic superfluids with broken time reversal symmetry. Recent mean field studies imply that total OAM of a uniform superfluid depends on boundary conditions and is not a thermodynamic quantity. We point out that this does not conflict with thermodynamics, because there is no intensive external field conjugate to OAM with which a uniform superfluid is stable in the thermodynamic limit, in sharp contrast to the orbital magnetization in a non-superfluid system. We establish a simple physical picture for the sensitivity of OAM to boundaries by introducing the notion of "unpaired fermions" and "fermionic Landau criterion" within a mean field description. In order to go beyond the mean field approximation, we perform a density matrix renormalization group calculation and conclude that the mean field understanding is essentially correct.

We study bosons in a one-dimensional hard-wall box potential. In the case of contact interaction, the system is exactly solvable by the Bethe ansatz, as first shown by Gaudin in 1971. Although contained in the exact solution, the boundary energy in the thermodynamic limit for this problem is only approximately calculated by Gaudin, who found the leading order result at weak repulsion. Here we derive an exact integral equation that enables one to calculate the boundary energy in the thermodynamic limit at an arbitrary interaction. We then solve such an equation and find the asymptotic results for the boundary energy at weak and strong interactions. The analytical results obtained from the Bethe ansatz are in agreement with the ones found by other complementary methods, including quantum MonteCarlo simulations. We study the universality of the boundary energy in the regime of a small gas parameter by making a comparison with the exact solution for the hard rod gas.

An alternative approach to the quantum statistics of interacting particles is proposed. It consists of calculating the equilibrium thermodynamical quantities of the many-body system via the pair distribution function with the assumption that the particles interact with each other only through pair central forces. The proposed approach has some advantage over the usual treatment via the partition function in that the pair distribution function is easier to deal with than the partition function in certain circumstances particularly when the collective motion description of the system is desirable. This is because only the pair distribution function can be expressed directly in terms of the collective interaction which is closely connected with collective elementary excitation, such as a plasmon in the electron gas and a phonon in the hard-sphere Boson gas. The equation of state as well as the internal energy are obtained in the form of integrals of the pair distribution function. The close analogy between the pair distribution function and the two-body propagator, which appears in the quantum field theory, makes it possible to analyze the former by the use of Feynman diagrams identical with those usually introduced for the latter. The collective interaction, which is defined by the sum of the direct and the indirect interactions, is introduced as a particular partial sum of the perturbation series of the pair distribution function. This is used in rewriting the pair distribution function in terms of the collective interaction.It is shown that, while the simple chain approximation to the collective interaction in the electron gas is responsible for the transfer of a plasmon, the same approximation to the collective pseudo-interaction in the hard-sphere Boson system has a relation similar to that of transfer of a phonon, both cases occuring at low temperatures. The explicit calculation of the pair distribution functions for these systems at the absolute zero temperature is carried out up to the first order in the collective interaction (simple chain approximation.) These results are used to calculate the ground-state energies. For the electron gas the energy thus obtained confirms Gell-Mann-Bruckner's calculation of the correlation energy. For the hard-sphere Bosons the calculated energy reproduces the result of Lee, Huang, and Yang. The extension of the calculation to the finite temperature case is also indicated. In particular the classical Debye-Huckel equation of state for the electron gas is briefly discussed.

Understanding the dynamical consequences of quantum phase transitions on thermodynamical quantities, such as work statistics and entropy production, is one of the most intriguing aspect of quantum many-body systems, pinpointing the emergence of irreversibility to critical features. In this work, we investigate the critical fingerprints appearing in these key thermodynamical quantities for a mean-field critical system undergoing a finite-time cycle, starting from a thermal state at a generic inverse temperature. In contrast to non-zero dimensional many-body systems, the presence of a mean-field critical point in a finite-time cycle leads to constant irreversible work even in the limit of infinitely slow driving. This links with the fact that a slow finite-time cycle results in a constant amount of squeezing, which enables us to derive analytical expressions for the work statistics and irreversible entropy, depending solely on the mean-field critical exponents and the functional form of the control parameter near the critical point. We find that the probability of observing negative work values, corresponding to negative irreversible entropy, is inversely proportional to the time the system remains near to the critical point, and this trend becomes less pronounced the lower the temperature of the initial thermal state. Finally, we determine the irreversibility traits under squeezing generation at zero-temperature using the relative entropy of coherence.

Drawing on research in Oakland, California over a twenty-year period, Noguera considers how poverty and racial isolation have contributed to the problems confronted by schools in that district and other inner-city communities around the state. He illuminates the factors that hinder the development of social capital in low-income communities, and, in doing so, demonstrates why local control does not make it easier for school systems to address the academic needs of poor students. The wide variation in the ability of different communities to generate revenue and other support for schools at the local level creates inequalities in the learning conditions and opportunities that schools provide students. The design of the state’s public education system exacerbates these inequities. Specifically, the state’s current approaches to local control make it possible for advantaged parents and communities with a vested interest in the affairs of public schools to monitor conditions in their schools. However, this form of local control is inadequate as a mechanism for holding schools accountable in high poverty areas. Noguera concludes that in order to improve reform efforts and policy implementation, the state must enact measures to mitigate the effects of poverty and racial isolation. Rather than presuming that all schools can be treated the same, the state must develop strategies to build the social capital of parents and cultivate the civic capacity of communities in low-income areas. Without such measures, local control will remain little more than a guise through which the State can shirk its responsibility for insuring that all students have access to quality education.

Order–disorder transition in a linear system of anti-parallel magnetic dipoles with long-range interactions

Counterdiabatic (CD) driving presents a way of generating adiabatic dynamics at an arbitrary pace, where excitations due to nonadiabaticity are exactly compensated by adding an auxiliary driving term to the Hamiltonian. While this CD term is theoretically known and given by the adiabatic gauge potential, obtaining and implementing this potential in many-body systems is a formidable task, requiring knowledge of the spectral properties of the instantaneous Hamiltonians and control of highly nonlocal multibody interactions. We show how an approximate gauge potential can be systematically built up as a series of nested commutators, remaining well defined in the thermodynamic limit. Furthermore, the resulting CD driving protocols can be realized up to arbitrary order without leaving the available control space using tools from periodically driven (Floquet) systems. This is illustrated on few- and many-body quantum systems, where the resulting Floquet protocols significantly suppress dissipation and provide a drastic increase in fidelity.

A model of strongly interacting and correlated hadrons is developed. The interaction used contains a long range attraction and short range repulsive hard core. Using this interaction and various limiting situations of it, a study of the effect of bound states and Feshbach resonances is given. The limiting situations are a pure square well interaction, a delta-shell potential and a pure hard core potential. The limit of a pure hard core potential are compared with results for a spinless Bose and Fermi gas. The limit of many partial waves for a pure hard core interaction is also considered and result in expressions involving the hard core volume. This feature arises from a scaling relation similar to that for hard sphere scattering with diffractive corrections. The role of underlying isospin symmetries associated with the strong interaction of protons and neutrons in this two component model is investigated. Properties are studied with varying proton fraction. An analytic expression for the Beth Uhlenbeck continuum integral is developed which closely approximates exact results based on the potential model considered. An analysis of features associated with a unitary limit is given. In the unitary limit of very large scattering length, the ratio of effective range to thermal wavelength appears as a limiting scale. Thermodynamic quantities such as the entropy and compressibility are also developed. The effective range corrections to the entropy vary as the cube of this ratio for low temperatures and are therefore considerably reduced compared to the corrections to the interaction energy which varies linearly with this ratio. Effective range corrections to the compressibility are also linear in the ratio.

Phase transitions are not usually seen in the time domain. Here, we report on the finding of critical times at which a physical observable, in the thermodynamic limit, becomes nonanalytic as a function of time. We find that the coherence of a probe spin coupled to a many-body system vanishes at times in one-to-one correspondence to the Lee-Yang zeros of the partition function of the many-body system. In the thermodynamic limit, the Lee-Yang zeros form a continuum cut in the complex plane of fugacity and the probe spin coherence presents sudden death and birth at the critical times corresponding to the Yang-Lee singularities. These results provide new experimental possibilities in many-body physics.

We show that 2+1-dimensional Euclidean quantum gravity is equivalent, under some mild topological assumptions, to a Gaussian fermionic system. In particular, for manifolds topologically equivalent to $\Sigma_g\times\RrR$ with $\Sigma_g$ a closed and oriented Riemann surface of genus $g$, the corresponding 2+1-dimensional Euclidean quantum gravity may be related to the 3D-lattice Ising model before its thermodynamic limit.