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Random walks and AC conductivity of disordered systems

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Abstract

The controversy about the precise form of the waiting time distribution for the first observed hop in the Scher and Lax description (1973) of AC hopping conductivity of disordered systems by a continuous time random walk (CTRW) on a lattice is resolved. Starting from an exact general definition of the above waiting time distribution for random walks in the actual disordered medium, the corresponding first hop waiting time distribution for the CTRW on a lattice is shown to coincide with the distribution of waiting times between consecutive hops, as assumed originally by Scher and Lax. The authors' analysis thus supports the correctness of the Scher and Lax theory of AC conductivity of disordered systems. The relation between the random walk equation for hopping in a random medium proposed by Scher and Lax and the more familiar rate equations for site-occupancy probabilities is also established.

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