Recyclable Photopolymers for Sustainable 3D Printing

Hofmeister effect-inspired Ti3C2Tx MXene-based robust, multifunctional hydrogels

A systematic trend analysis of 3D printing techniques used in specific soft robotic elements

Casting silicone elastomers into 3D printed molds has seen a surge of applications in soft robots, soft manipulators, microfluidics, wearable technologies and stretchable sensors. In such devices, buried fluid channels are used to transport fluids, as fluidic actuators and as sensors with liquid metal. However, it is difficult to demold structures with buried channels or overhangs. As a solution, using sacrificial molds made of dissolvable materials has been proposed. In this paper, we evaluate different commercially available 3D printing materials as dissolvable mold materials. We tested dissolving prints made of high-impact polystyrene (HIPS), acrylonitrile butadiene styrene (ABS), polyvinyl butyral (PVB) and polyvinyl alcohol (PVA) in limonene, acetone, isopropanol/ethanol and water, respectively. We further studied the effect of magnetic stirring and ultrasonic bath on the dissolution times. Finally, we fabricated buried channels using different mold materials and silicone elastomers. The results show that at least ABS, PVB and PVA can be used as mold materials. In particular, PVA is a promising material as it is soluble in water. The studied method simplifies the fabrication of soft devices, allowing the fabrication of overhangs and buried channels in a single casting step.

Liquid crystal elastomers (LCEs) are active soft matter-based materials with strong stimulus responsiveness and reversible, large-shape morphing capabilities. LCEs have demonstrated broad and growing applications in soft robotics, wearable devices, artificial muscles, and optical machines. The actuation intelligence and advanced functionality of LCEs depend on the smartness and properties of structures. In this review, we discuss recent advances in structure-induced intelligence of LCEs, specifically the integration of structural properties with the alignment and processing of LCEs. The structural design principles for three categories consisting of common structures (film, fiber, and tubule), smart structures (origami, kirigami, mechanical metamaterial, topology, and topography), and complex structures (monolithic and integrated) are presented. Various alignment controls of LCEs, including mechanical, surface, field-assisted, and shear alignment, are capable of inducing structural properties. The coupling and collaboration mechanisms of the LCE structures and the generated functions are discussed. The review concludes with perspectives on current challenges and emerging opportunities.

Direct-ink-writing 3D-printed bioelectronics

Printed electronics on elastomer substrates have found wide applications in wearable devices and soft robotics. For everyday usage, additional requirements exist for the robustness of the printed flexible electrodes, such as the ability to resist scratching and damage. Therefore, highly robust electrodes with self‐healing, and good mechanical strength and stretchability are highly required and challenging. In this paper, a cross‐linking polyurea using polydimethylsiloxane as the soft segment and dynamic urea bonds is prepared and serves as a self‐healing elastomer substrate for coating and printing of silver nanowires (AgNWs). Due to the dynamic exchangeable urea bond at 60 °C, the elastomer exhibits dynamic exchange of the cross‐linking network while retaining the macroscopic shape. As a result, the AgNWs are partially embedded in the surface of the elastomer substrate when coated or printed at 60 °C, forming strong interfacial adhesion. As a result, the obtained stretchable electrode exhibits high mechanical strength and stretchability, the ability to resist scratching and sonication, and self‐healing. This strategy can be applied to a variety of different conducting electrode materials including AgNWs, silver particles, and liquid metal, which provides a new way to prepare robust and self‐healing printed electronics.

Flexible electronic devices have garnered increasing attention for their applications in wearable devices, biomedical systems, soft robots, and flexible displays. However, the current sensors face limitations regarding low sensitivity, poor stability, and inadequate adhesion bonding between stimuli‐responsive functional materials and flexible substrates. To overcome these challenges and enable the further development of sensor devices, surface modification of stimuli‐responsive materials with amyloid aggregates has emerged as a promising approach to enhance functionality and create superior multifunctional sensors. This review presents recent research advancements in the flexible sensors based on protein amyloid aggregation. The article begins by explaining the basic principles of protein amyloid aggregation, followed by outlining the process of preparing 1D to 3D amyloid‐based composite materials. Finally, it discusses the utilization of protein amyloid aggregation as a surface modification technique for developing flexible sensors. Based on this foundation, we identify the shortcomings associated with protein amyloid aggregate composites and propose possible solutions to address them. We believe that comprehensive investigations in this area will expedite the development of high‐performance flexible sensors with high sensitivity, high structural stability, and strong interface adhesion, especially the implantable flexible sensors for health monitoring.

In the contemporary era, novel manufacturing technologies like additive manufacturing (AM) have revolutionized the different engineering sectors including biomedical, aerospace, electronics, etc. Four-dimensional (4D) printing aka AM of smart materials is gaining popularity among the scientific community, which has the excellent ability to make soft structures such as soft robots, actuators, and grippers. These soft structures are developed by applying various stimuli such as pH, temperature, magnetic field, and many combinations onto soft materials. Stimuli in 3D printing permit various shape-morphing behaviors such as bending, twisting, folding, swelling, rolling, shrinking, origami, or locomotion. A wide variety of soft magnetic structures can be fabricated through the incorporation of soft or hard magnetic particles into soft materials resulting in magneto-active soft materials (MASMs). With this integration, magneto-thermal coupling actuation allows diverse magneto-deformations, facilitating the development of personalized devices that are capable of enhanced deformation. In this review, guidelines are provided on the 3D printing for MASMs such as magneto-active polymers (MAPs), magneto-active composites, and magneto-active hydrogels (MAHs) on the booming development of various smart and flexible devices such as soft robots, wearable electronics, and biomimetic devices. Moreover, 3D-printed soft robotics have an outstanding capacity to adapt to complicated situations for many advanced actuating applications. Finally, some current challenges and emerging areas in this exciting technology have been proposed. Lastly, it is anticipated that technological advancements in developing smart and intelligent magneto-active structures will have a significant impact on the design of real-world applications.

The rapid and reversible adhesion between solids is of great significance, particularly in fields such as biomedicine, intelligent machines, and bioelectronic sensors. Hydrogels, as soft materials, play a vital role in reversible adhesion. To achieve a wider range of applications, it is essential to enhance the intelligence of hydrogels. However, the preparation of reversible adhesive hydrogels with remote control, reversible adhesion, rapid response, and no residue remains a challenge in the field. Herein, we developed a light-controlled reversible adhesive hydrogel by integrating temperature-controlled reversible adhesion with the photothermal response capabilities of Fe3O4. The hydrogel can adhere/desorb reversibly under temperature control and allows for remote adhesion control using infrared light. Under infrared light irradiation, surface water causes carboxylic acid groups to migrate to the surface, thereby shielding the catechol groups. This results in insufficient adhesive groups at the interface to form interactions with opposing surfaces. Without infrared light irradiation, the adhesive functional groups are exposed, allowing interaction forces to form between the surface with the adhesion groups and the opposing surfaces. This smart hydrogel holds significant potential for future applications in wound dressings, wearable devices, and soft robots.

Developments in additive manufacturing have enabled the fabrication of soft machines that can safely interface with humans, creating new applications in soft robotics, wearable technologies, and haptics. However, designing custom inks for the 3D printing of soft materials with Young’s modulus less than 100 kPa remains a challenge due to highly coupled structure-property-process relationship in polymers. Here, we show a three-stage material chemistry process based on interpenetrating silicone double networks and ammonium bicarbonate particles that decouples the transient behavior during processing from the final properties of the material. Evaporation of ammonium bicarbonate particles at the final stage creates gaseous voids to produce foams with a low effective Young’s modulus in the 25 kPa −90 kPa range. Our photoirradiation-assisted direct ink writing system demonstrates the ability to maintain high resolution while enabling controlled loading of ammonium bicarbonate particles. The resultant multi-material possesses programmed porosity and related properties such as density, stiffness, Shore hardness, and ultimate strength in a monolithic object. Our multi-hardness synthetic hand and self-righting buoyant structure highlight these capabilities.

A microfluidic printhead with integrated hybrid mixing by sequential injection for multimaterial 3D printing

Organogels are polymer networks extended by a liquid organic phase, offering a wide range of properties due to the many combinations of polymer networks, solvents, and shapes achievable through 3D printing. However, current printing methods limit solvent choice and composition, which in turn limits organogels' properties, applications, and potential for innovation. As a solution, a method for solvent‐independent printing of 3D organogel structures is presented. In this method, the printing step is decoupled from the choice of solvent, allowing access to the full spectrum of solvent diversity, thereby significantly expanding the range of achievable properties in organogel structures. With no changes to the polymer network, the 3D geometry, or the printing methodology itself, the choice of solvent alone is shown to have an enormous impact on organogel properties. As demonstrated, it can modulate the thermo‐mechanical properties of the organogels, both shifting and extending their thermal stability range to span from ‐30 to over 100 °C. The choice of solvent can also transition the organogels from highly adhesive to extremely slippery. Finally, the method also improves the surface smoothness of prints. Such advances have potential applications in soft robotics, actuators, and sensors, and represent a versatile approach to expanding the functionality of 3D‐printed organogels.

For years the way of producing a flow profile for Inspection Chambers and Manholes could be divided into 3 methods: Injection moulding, Roto moulding and Hand assembling. For the standard orientations, for example straight through and cross, the IM profile integrated with a base is by far the best option. But for nonstandard configurations; different orientations, inlet heights and inlet sizes, the only option is to hand weld them together from injection moulded parts, pipes and plates. This is a time- consuming way of producing with high production cost and often aesthetic-wise of a challenging level. This is not necessary anymore after the introduction of 3D printing as a new production method for flow profiles in chambers and manholes. 3D printing is in many industries an accepted production method which can produce parts of high quality and high accuracy. The printing systems have faced a huge development in the last 10 years and prints are often close to perfection. The only disadvantage of these printing systems is the maximum size of the print. But since the introduction of 3D robot printing, products with a diameter of 1 meter can be printed without any problem. 3D robot printers were up to recently, used for prototypes, one- off products and art objects. Now a production area is created on which multiple products can be produced in a row without human interference. The most common materials used for 3D printing are ABS and PLA. These materials have good adhesion, almost no shrinkage and a good appearance. Unfortunately, these materials are not common in our industry. We need PP, PE or PVC. While our manholes and inspection chambers are from PP, we also need PP flow profiles. The advantage of using a 3D robot printer is that it uses granulates instead of filaments or special powder. This makes the material cost part almost equal to injection moulding. Another advantage is also that recycled material can be used. Own scrap can be used but also waste from other markets. The main reason that flows profiles are ideal for 3D printing is that nonstandard flow profiles are very labour-intensive. So, 3D printing really helps out here. Besides that, there is a lot of freedom in design. This helps to design in such a way, that the final profile is hydraulically optimal. This prevents the overflowing of manholes during heavy rain showers. Of course, these products should fulfil all requirements of the EN13598-2. Even though major development steps have been made in 3D printing during the last 5 years, 3D robot printing is still in the exploring phase and we find many hurdles on our way. This paper will show how our industry can use 3D printing and what are the pros and cons.

<p indent=0mm>Artificial muscle is a bio-inspired soft actuator that generates large output force and displacement with flexibility and compliance and can interact with humans and biological environments. Due to low load capacity, high hysteresis, and short life cycle of existing artificial muscles, a new kind of twisted and coiled artificial muscles based on polymer fibers, such as nylon, has been developed and called twisted and coiled polymer fiber (TCPF). This artificial muscle is capable of straining more than 40%, which has a load capacity of up to 100 times higher than that of a human muscle, has energy density of up to <sc>5.3 kW/kg,</sc> and it is a hot topic in current research. This study reviews the development of state-of-the-art TCPF, focusing on fabrication and actuation mechanism, new materials and structures, improvements on actuation strategy, and applications in soft robotics. Current states are summarized and discussed for future development directions.

From Responsive Molecules to Interactive Materials.