Reply on RC1

Nitrogen dioxide (NO2) is an important trace-gas pollutant and climate agent whose presence also leads to spectral interference in ocean color retrievals. NO2 column densities have been retrieved with satellite UV-Vis spectrometers such as the Ozone Monitoring Instrument (OMI) and Tropospheric Monitoring Instrument (TROPOMI) that typically have spectral resolutions of the order of 0.5 nm or better and spatial footprints as small as 3.5 km × 5 km. These NO2 observations are used to estimate emissions, monitor pollution trends, and study effects on human health. Here, we investigate whether it is possible to retrieve NO2 amounts with lower spectral resolution hyper-spectral imagers such as the Ocean Color Instrument (OCI) that will fly on the Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) satellite set for launch in early 2024. OCI will have a spectral resolution of 5 nm and a spatial resolution of ∼1 km with global coverage in 1–2 days. At this spectral resolution, small scale spectral structure from NO2 absorption is still present. We use real spectra from the OMI to simulate OCI spectra that are in turn used to estimate NO2 slant column densities (SCDs) with an artificial neural network trained on target OMI retrievals. While we obtain good results with no noise added to the OCI simulated spectra, we find that the expected instrumental noise substantially degrades the OCI NO2 retrievals. Nevertheless, the NO2 information from OCI may be of value for ocean color retrievals, as our simulations suggest that it will be of similar or slightly better quality as compared with TROPOMI NO2 data at TROPOMI spatial resolution on a daily basis and will be available simultaneously. OCI retrievals can also be temporally averaged over time-scales of the order months to reduce noise and provide higher spatial resolution maps that may be useful for downscaling information provided by lower spatial resolution instruments such as OMI and TROPOMI, for high resolution emissions estimates, and other applications. In addition, we explore the possibility of using an extended fitting window for NO2 retrievals as compared with traditional approaches. We demonstrate that the use of an extended spectral fitting window can reduce random errors in a current state-of-the-art OMI NO2 SCD product. Machine learning approaches with extended fitting windows, once trained, can also substantially speed up NO2 spectral fitting algorithms as applied to OMI, TROPOMI, and similar instruments that are flying or will soon fly in geostationary orbit.

Sulfur dioxide (SO2) is released into the Earth’s atmosphere through natural and anthropogenic processes and the latter category amounts to the majority of the global SO2 emissions. Satellite SO2 observations have been used to monitor SO2 emissions at different regional and global scales and to detect large-point sources of SO2 emissions of diverse origins. In this study, we conducted atmospheric inversions at the global scale to estimate daily SO2 emissions at 1.26o×2.5o (latitude×longitude) spatial resolution over polluted regions for two years 2020 and 2021 using satellite SO2 total vertical column densities (TVCDs) obtained by the Sentinel 5p TROPOspheric Monitoring Instrument (TROPOMI) and AURA Ozone Monitoring Instrument (OMI). We used the global chemistry coupled transport model LMDz-INCA with 1.26o×2.5o (latitude×longitude) horizontal resolution and 79 hybrid σ-p vertical levels extending to the stratosphere to simulate the model SO2 TVCDs. The model uses a priori monthly global anthropogenic emission inventories from the open-source Community Emissions Data System (CDES). As the TROPOMI operational offline L2 SO2 data product has high noise levels, we used the TROPOMI COBRA SO2 data product in this study which has comparatively smaller noise. First, we evaluated the SO2 TVCDs from the LMDz-INCA model simulations for a reference year 2019 with the observed SO2 TVCDs from TROPOMI and OMI. The daily average (10-day running average) of the model simulated SO2 TVCDs over the major polluted regions like India, China, and the Middle East, and over less polluted regions like South Africa, and South America mostly follow the trend of the observed SO2 TVCDs from both TROPOMI and OMI. The model overestimates SO2 TVCDs over India and the Middle East and underestimates them over China, South Africa, and South America. For Europe and North America, the noise levels in the daily averaged TVCDs from both TROPOMI and OMI are too high for a meaningful comparison. In order to estimate anthropogenic SO2 emissions, we used a recently developed inversion approach (Zheng et al., 2020), which was previously used to estimate anthropogenic NOx emissions over China. We performed the model simulation for 2019 with 40% reduced anthropogenic SO2 emission to calculate the gridded local sensitivities of the TVCDs to the change in the anthropogenic SO2 emissions. The inversion approach combines these gridded local sensitivities and the relative change of the observed satellites and the modelled TVCDs to derive the relative change of anthropogenic SO2 emissions from the reference year 2019 to the inversion years 2020 and 2021. The estimated total SO2 emissions from TROPOMI and OMI observations for 2020 and 2021 are mostly higher compared to the reference year total emissions over the world and over the selected regions. The total SO2 emissions from TROPOMI and OMI observations at the common model grids for both inversion years are consistent with each other.

Abstract. The TROPOspheric Monitoring Instrument (TROPOMI), launched in October 2017 on board the Sentinel-5 Precursor (S5P) satellite, monitors the composition of the Earth's atmosphere at an unprecedented horizontal resolution as fine as 3.5 × 5.5 km2. This paper assesses the performances of the TROPOMI formaldehyde (HCHO) operational product compared to its predecessor, the OMI (Ozone Monitoring Instrument) HCHO QA4ECV product, at different spatial and temporal scales. The parallel development of the two algorithms favoured the consistency of the products, which facilitates the production of long-term combined time series. The main difference between the two satellite products is related to the use of different cloud algorithms, leading to a positive bias of OMI compared to TROPOMI of up to 30 % in tropical regions. We show that after switching off the explicit correction for cloud effects, the two datasets come into an excellent agreement. For medium to large HCHO vertical columns (larger than 5 × 1015 molec. cm−2) the median bias between OMI and TROPOMI HCHO columns is not larger than 10 % (< 0.4 × 1015 molec. cm−2). For lower columns, OMI observations present a remaining positive bias of about 20 % (< 0.8 × 1015 molec. cm−2) compared to TROPOMI in midlatitude regions. Here, we also use a global network of 18 MAX-DOAS (multi-axis differential optical absorption spectroscopy) instruments to validate both satellite sensors for a large range of HCHO columns. This work complements the study by Vigouroux et al. (2020), where a global FTIR (Fourier transform infrared) network is used to validate the TROPOMI HCHO operational product. Consistent with the FTIR validation study, we find that for elevated HCHO columns, TROPOMI data are systematically low (−25 % for HCHO columns larger than 8 × 1015 molec. cm−2), while no significant bias is found for medium-range column values. We further show that OMI and TROPOMI data present equivalent biases for large HCHO levels. However, TROPOMI significantly improves the precision of the HCHO observations at short temporal scales and for low HCHO columns. We show that compared to OMI, the precision of the TROPOMI HCHO columns is improved by 25 % for individual pixels and by up to a factor of 3 when considering daily averages in 20 km radius circles. The validation precision obtained with daily TROPOMI observations is comparable to the one obtained with monthly OMI observations. To illustrate the improved performances of TROPOMI in capturing weak HCHO signals, we present clear detection of HCHO column enhancements related to shipping emissions in the Indian Ocean. This is achieved by averaging data over a much shorter period (3 months) than required with previous sensors (5 years) and opens new perspectives to study shipping emissions of VOCs (volatile organic compounds) and related atmospheric chemical interactions.

This study gives a systematic comparison of the Tropospheric Monitoring Instrument (TROPOMI) version 1.2 and Ozone Monitoring Instrument (OMI) QA4ECV tropospheric NO2 column through global chemical data assimilation (DA) integration for the period April−May 2018. DA performance is controlled by measurement sensitivities, retrieval errors, and coverage. The smaller mean relative observation errors by 16 % in TROPOMI than OMI over 60° N−60° S during April−May 2018 led to larger reductions in the global root mean square error (RMSE) against the assimilated NO2 measurements in TROPOMI DA (by 54 %) than in OMI DA (by 38 %). Agreements against the independent surface, aircraft-campaign, and ozonesonde observation data were also improved by TROPOMI DA compared to the control model simulation (by 12−84 % for NO2 and by 7−40 % for ozone), which were more obvious than those by OMI DA for many cases (by 2−70 % for NO2 and by 1−22 % for ozone). The estimated global total NOx emissions were 15 % lower in TROPOMI DA, with 2−23 % smaller regional total emissions, in line with the observed negative bias of the TROPOMI version 1.2 product compared to the OMI QA4ECV product. TROPOMI DA can provide city scale emission estimates, which were within 10 % differences with other high-resolution analyses for several limited areas, while providing a globally consistent analysis. These results demonstrate that TROPOMI DA improves global analyses of NO2 and ozone, which would also benefit studies on detailed spatial and temporal variations in ozone and nitrate aerosols and the evaluation of bottom-up NOx emission inventories.

Abstract. The TROPOspheric Monitoring Instrument (TROPOMI) is the only payload of the Sentinel-5 Precursor (S5P), which is a polar-orbiting satellite mission of the European Space Agency (ESA). TROPOMI is a nadir-viewing spectrometer measuring in the ultraviolet, visible, near-infrared, and the shortwave infrared that provides near-global daily coverage. Among other things, TROPOMI measurements will be used for calculating the UV radiation reaching the Earth's surface. Thus, the TROPOMI surface UV product will contribute to the monitoring of UV radiation by providing daily information on the prevailing UV conditions over the globe. The TROPOMI UV algorithm builds on the heritage of the Ozone Monitoring Instrument (OMI) and the Satellite Application Facility for Atmospheric Composition and UV Radiation (AC SAF) algorithms. This paper provides a description of the algorithm that will be used for estimating surface UV radiation from TROPOMI observations. The TROPOMI surface UV product includes the following UV quantities: the UV irradiance at 305, 310, 324, and 380 nm; the erythemally weighted UV; and the vitamin-D weighted UV. Each of these are available as (i) daily dose or daily accumulated irradiance, (ii) overpass dose rate or irradiance, and (iii) local noon dose rate or irradiance. In addition, all quantities are available corresponding to actual cloud conditions and as clear-sky values, which otherwise correspond to the same conditions but assume a cloud-free atmosphere. This yields 36 UV parameters altogether. The TROPOMI UV algorithm has been tested using input based on OMI and the Global Ozone Monitoring Experiment-2 (GOME-2) satellite measurements. These preliminary results indicate that the algorithm is functioning according to expectations.

Abstract. Nitrogen dioxide (NO2) is one of the main data products measured by the Tropospheric Monitoring Instrument (TROPOMI) on the Sentinel-5 Precursor (S5P) satellite, which combines a high signal-to-noise ratio with daily global coverage and high spatial resolution. TROPOMI provides a valuable source of information to monitor emissions from local sources such as power plants, industry, cities, traffic and ships, and variability of these sources in time. Validation exercises of NO2 v1.2–v1.3 data, however, have revealed that TROPOMI's tropospheric vertical column densities (VCDs) are too low by up to 50 % over highly polluted areas. These findings are mainly attributed to biases in the cloud pressure retrieval, the surface albedo climatology and the low resolution of the a priori profiles derived from global simulations of the TM5-MP chemistry model. This study describes improvements in the TROPOMI NO2 retrieval leading to version v2.2, operational since 1 July 2021. Compared to v1.x, the main changes are the following. (1) The NO2-v2.2 data are based on version-2 level-1b (ir)radiance spectra with improved calibration, which results in a small and fairly homogeneous increase in the NO2 slant columns of 3 % to 4 %, most of which ends up as a small increase in the stratospheric columns. (2) The cloud pressures are derived with a new version of the FRESCO cloud retrieval already introduced in NO2-v1.4, which led to a lowering of the cloud pressure, resulting in larger tropospheric NO2 columns over polluted scenes with a small but non-zero cloud coverage. (3) For cloud-free scenes a surface albedo correction is introduced based on the observed reflectance, which also leads to a general increase in the tropospheric NO2 columns over polluted scenes of order 15 %. (4) An outlier removal was implemented in the spectral fit, which increases the number of good-quality retrievals over the South Atlantic Anomaly region and over bright clouds where saturation may occur. (5) Snow/ice information is now obtained from ECMWF weather data, increasing the number of valid retrievals at high latitudes. On average the NO2-v2.2 data have tropospheric VCDs that are between 10 % and 40 % larger than the v1.x data, depending on the level of pollution and season; the largest impact is found at mid and high latitudes in wintertime. This has brought these tropospheric NO2 closer to Ozone Monitoring Instrument (OMI) observations. Ground-based validation shows on average an improvement of the negative bias of the stratospheric (from −6 % to −3 %), tropospheric (from −32 % to −23 %) and total (from −12 % to −5 %) columns. For individual measurement stations, however, the picture is more complex, in particular for the tropospheric and total columns.

<p>We present the total column water vapor (TCWV) retrieval for the TROPOspheric Monitoring Instrument (TROPOMI) observations in the blue band. The retrieval was first developed to retrieve TCWV from Global Ozone Monitoring Experience 2 (GOME-2). We have modified the settings of the retrieval to adapt it for TROPOMI observations. The TROPOMI TCWV retrieval algorithm consists of two major steps. The first step is the retrieval of water vapor slant columns by applying the differential optical absorption spectroscopy (DOAS) technique to TROPOMI observations in the blue band. The retrieved water vapor slant columns are then converted to vertical columns using air mass factors (AMFs). An iterative optimization has been developed to dynamically find the optimal a priori water vapor profile for AMF calculation. The dynamic search algorithm makes use of the fact that the vertical distribution of water vapor is strongly correlated to the total column amount. This makes the algorithm better suited for climate studies compared to typical satellite retrievals with static a priori or vertical profile information from the chemistry transport model (CTM). Details of the TCWV retrieval are presented. The TCWV retrieval algorithm is applied to TROPOMI observations. The results are validated by comparing to Ozone Monitoring Instrument (OMI), GOME-2 and Special Sensor Microwave Imager Sounder (SSMIS) satellite observations. TCWV derived from TROPOMI observations agree well with the other data sets with Pearson correlation coefficient (R) ranging from 0.94 to 0.99. The correlation is slight better during winter time of the northern hemisphere. Small discrepancies are found among TROPOMI, OMI, GOME-2 and SSMIS observations. The discrepancies are mainly due to differences in measurement time and cloud filtering. More detailed validation against ground based sun-photometer observations are presented separately in this session*.</p><p> </p><p>*see the respective abstract by Katerina Garane.</p>

Nitrogen oxides (NOx) are air pollutants critical to ozone and fine particle production in the troposphere. Here, we present fuel‐based emission inventories updated to 2018, including for mobile source engines using the Fuel‐based Inventory of Vehicle Emissions (FIVEs) and oil and gas production using the Fuel‐based Oil and Gas (FOG) inventory. The updated FIVE emissions are now consistent with the NEI17 estimates differing within 2% across the contiguous US (CONUS). Tropospheric NO2 columns modeled by the Weather Research and Forecasting with Chemistry model (WRF‐Chem) are compared with those observed by TROPOspheric Monitoring Instrument (TROPOMI) and Ozone Monitoring Instrument (OMI) during the summer of 2018. Modeled NO2 columns show strong temporal and spatial correlations with TROPOMI (OMI), identified with biases of −3% (−21%) over CONUS, and +8% (−6%) over point sources plus urban regions. Taking account of the negative bias (∼20%) in early version of TROPOMI over polluted regions, WRF‐Chem shows good performance with updated FIVE and FOG emissions. Our model tends to under‐predict the tropospheric NO2 columns over background and rural regions (bias of −21% to −3%). Through model sensitivity analyses, we demonstrate the important roles of emissions from soils (11.7% average over CONUS), oil and gas production (4.1%), wildfires (10.6%), and lightning (2.3%) with greater contributions at regional scales. This work provides a roadmap for satellite‐based evaluations for emission updates from various sources.

The Ozone Monitoring Instrument (OMI) was launched on July 15, 2004, with an expected mission lifetime of 5 years. After more than 17 years in orbit the instrument is still functioning satisfactorily, and in principle can continue doing so for many years more. In order to continue the datasets acquired by OMI and the Microwave Limb Sounder the mission was extended up to at least 2023. Actions have been taken to ensure the proper functioning of the OMI instrument operations, the data processing, and the calibration monitoring system until the eventual end of the mission. For the data processing a new level 0 to level 1b data processor was built based on the recent developments for Tropospheric Monitoring Instrument (TROPOMI). With corrections for the degradation of the instrument now included, it is feasible to generate a new data collection to supersede the current collection 3 data products. This paper describes the differences between the collection 3 and collection 4 data. It will be shown that the collection 4 L1b data is a clear improvement with respect to the previous collections. By correcting for the gentle optical and electronic aging that has occurred over the past 17 years, OMI's ability to make trend-quality ozone measurements has further improved.

The Ozone Monitoring Instrument (OMI) was launched on July 15, 2004, with an expected mission lifetime of 5 years. After more than 17 years in orbit the instrument is still functioning satisfactorily, and in principle can continue doing so for many years more. In order to continue the datasets acquired by OMI and the Microwave Limb Sounder the mission was extended up to at least 2023. Actions have been taken to ensure the proper functioning of the OMI instrument operations, the data processing, and the calibration monitoring system until the eventual end of the mission. For the data processing a new level 0 to level 1b data processor was built based on the recent developments for Tropospheric Monitoring Instrument (TROPOMI). With corrections for the degradation of the instrument now included, it is feasible to generate a new data collection to supersede the current collection 3 data products. This paper describes the differences between the collection 3 and collection 4 data. It will be shown that the collection 4 L1b data is a clear improvement with respect to the previous collections. By correcting for the gentle optical and electronic aging that has occurred over the past 17 years, OMI's ability to make trend-quality ozone measurements has further improved.

Abstract. The Ozone Monitoring Instrument (OMI) was launched on 15 July 2004, with an expected mission lifetime of 5 years. After more than 17 years in orbit the instrument is still functioning satisfactorily and in principle can continue doing so until the expected decommissioning of its platform Aura in 2025. In order to continue the datasets acquired by OMI and the Microwave Limb Sounder, the mission was extended up to at least 2023. Actions have been taken to ensure the proper functioning of the OMI operations, the data processing, and the calibration monitoring system until the eventual end of the mission. For the data processing a new level-0 (L0) to level-1b (L1b) data processor was built based on the recent developments for the TROPOspheric Monitoring Instrument (TROPOMI). With corrections for the degradation of the instrument now included, it is feasible to generate a new data collection to supersede the current collection-3 data products and reprocess the data of the entire mission up to now. This paper describes the differences between the collection-3 and collection-4 data. It will be shown that the collection-4 L1b data comprise a clear improvement with respect to the previous collections. By correcting for the gentle optical and electronic aging that has occurred over the past 17 years, OMI's ability to make trend-quality ozone measurements has further improved.

Spaceborne NO2 column observations from two high‐resolution instruments, Tropospheric Monitoring Instrument (TROPOMI) on board Sentinel‐5 Precursor and Ozone Monitoring Instrument (OMI) on Aura, reveal unprecedented NO2 decreases over China, South Korea, western Europe, and the United States as a result of public health measures enforced to contain the coronavirus disease outbreak (Covid‐19) in January–April 2020. The average NO2 column drop over all Chinese cities amounts to −40% relative to the same period in 2019 and reaches up to a factor of ~2 at heavily hit cities, for example, Wuhan, Jinan, while the decreases in western Europe and the United States are also significant (−20% to −38%). In contrast with this, although Iran is also strongly affected by the disease, the observations do not show evidence of lower emissions, reflecting more limited health measures.

Combining the near-daily Ozone Monitoring Instrument (OMI) and Tropospheric Monitoring Instrument (TROPOMI) measurements of solar spectra, we construct line indices (line-core to line-flanks ratios) for various transitions (mainly Fe i) in the 300–2390 nm spectral domain. The indices are supplemented by the wavelength-binned fluxes from OMI and Total and Spectral Solar Irradiance Sensor (TSIS-1). To study the short-term (solar-rotational) patterns, we normalize the indices and fluxes to the minimum-activity epoch, then de-trend them with 81 day running means. Comparisons of the de-trended TSIS-1 and OMI fluxes with the NASA-NOAA-LASP SSI (NNLSSI1) model show excellent agreement, to (0.5–2.2) × 10−4 in the normalized and de-trended data. The data are subjected to a multiregression analysis against quantities representing the facular brightening and the sunspot darkening. The de-trended line indices and average fluxes show different sensitivities to these two solar magnetic-activity manifestations, with the fluxes being far more susceptible to the sunspot component. The de-trended line indices experience a rapid drop of activity levels towards longer wavelengths, albeit with a large rebound in the short-wave infrared (SWIR) domain that is caused by the ubiquitous, temperature-sensitive CO transitions. The wavelength-dependent activity also falls, however much slower, in the de-trended average fluxes. Qualitatively similar behavior is captured by semiempirical models.

<strong class="journal-contentHeaderColor">Abstract.</strong> Since 2017 the Tropospheric Monitoring Instrument (TROPOMI) onboard ESA&rsquo;s Copernicus Sentinel-5 satellite (S5-P) has provided the operational Carbon Monoxide (CO) data product with daily global coverage on a spatial resolution of 5.5 &times; 7 km² (7&times; 7 km² before August 2019). The European Centre for Medium-Range Weather Forecasts (ECMWF) plans to assimilate the retrieved total columns and the corresponding vertical sensitivities in the Copernicus Atmosphere Monitoring Service Integrated Forecasting System (CAMS-IFS) to improve forecasts of the atmospheric chemical composition. The TROPOMI data will primarily constrain the vertical integrated CO field (VCD) of CAMS-IFS but to a lesser extent also its vertical CO distribution as well. For clear-sky conditions, the vertical sensitivity of the TROPOMI CO data product is useful throughout the atmosphere but for cloudy scenes it varies due to cloud shielding and light scattering. To assess the profile information, we deploy a posteriori profile retrieval that combines individual TROPOMI CO column retrievals with different vertical sensitivities to obtain a vertical CO profile that is then a representative average for the chosen spatial and temporal domain. We demonstrate the approach on three CO pollution cases. For the so called &ldquo;Rabbit Foot Fire&rdquo; in Idaho on the 12 August 2018, we estimate a CO profile showing the pollution at an altitude of about 5 km in good agreement with airborne in-situ measurements of the Biomass Burning fluxes of trace gases and aerosols (BB-FLUX) field campaign. The distinct CO enhancement in a plume aloft, decoupled from the ground, is sensed by TROPOMI but is not present in the CAMS-IFS model. For a large-scale event, we analyzed the CO pollution from Siberian wildfires that took place from 14 to 18 August 2018. The TROPOMI data is estimating the height of the pollution plume over Canada at 7 km in agreement with CAMS-IFS. However, CAMS-IFS underestimates the enhanced CO vertical column densities sensed by TROPOMI within the plume by more than 100 ppb. Finally, we study the seasonal biomass burning in the Amazon. During the burning season (1&ndash;15 August 2019) the CO profile retrieved from the TROPOMI measurements agrees well with the one of CAMS-IFS with a similar vertical shape between ground and 14 km altitude. Hence, our results indicate that assimilating TROPOMI CO retrieval with different vertical sensitivities e.g., under clear-sky and cloudy conditions provide information about the vertical distribution of CO.

Satellite-derived products are essential for monitoring aquatic ecosystems. This study presents a first assessment of the capabilities of the hyperspectral Ocean Colour Instrument (OCI) onboard of NASA’s recently launched Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) satellite. OCI delivers spectral observations from 340 to 895 nm with bandwidth at 5 nm resolution and spectral steps of 2.5 nm sampling, marking a major advance in ocean colour monitoring. Because the launch is recent and the premises very encouraging, an early assessment of its performance both against existing sensors and in-situ data in complex coastal waters is of great interest for validating its capabilities. This work is focused on the coastal waters of southern Portugal, analysing three sampling areas off Sagres, Portimão and Armona Island. PACE/OCI Level-2 chlorophyll-a (Chl-a) products from multiple dates between February 2024 and July 2025 were extracted and compared with coincident opportunistic in-situ Chl-a measurements collected from water samples across various CIMA projects. To contextualize the performance of the new hyperspectral sensor, a parallel comparison was conducted using standard reduced resolution Level-2 Chl-a products (CHL_OC4Me, CHL_NN) from the multispectral Sentinel-3 Ocean and Land Colour Instrument (S-3/OLCI), which has a comparable spatial resolution with PACE/OCI, approximately 1.2 km. An array of statistical metrics (e.g. Median Absolute Percentage, MdAPD, and Coefficient of Determination, R²) was applied to evaluate the agreement between satellite-derived and in-situ Chl-a concentrations. Preliminary results, based on the available matchup dataset, indicate that PACE/OCI estimations show a closer alignment with in-situ measurements compared to those from S-3/OLCI in the study region, as evidenced by the higher R² and lower log-transformed MdAPD. This improved performance suggests that the hyperspectral capability of OCI sharpens the algorithmic quantification of the phytoplankton signal, using NASA’s combined OCx and Colour Index approach, within the optically complex conditions characteristic of coastal and oceanic waters. Despite the limited temporal coverage (the PACE was launched in the first months of the 2024) and the scarce number of matchups between the opportunistic in-situ data and the corresponding satellite data, this early analysis underscores the promising potential of PACE/OCI for delivering more accurate Chl-a estimates in marine coastal environments. The study provides a first overview on the potential of PACE/OCI in Portuguese coastal waters, and in general on the feasibility of hyperspectral observation, for future research and applications of ocean colour data in contexts like regional coastal management and Blue Economy sectors.