Transient dynamics of open quantum systems

Information scrambling refers to the phenomenon in which local quantum information in a many-body system becomes dispersed throughout the entire system under unitary evolution. It has been extensively studied in closed quantum systems, where it is quantified by operator size growth, revealing deep connections between condensed matter physics, high-energy physics, and quantum information. However, when extending the study of operator size dynamics to open quantum systems, two different definitions of operator size distributions emerge. These definitions are based on different treatments of the bath. In this work, we aim to establish a unified picture for operator size dynamics in open quantum systems, using the solvable Brownian SYK models at generic system size. In particular, we provide the conditions under which the signature of scrambling transition — discovered using one particular definition — appears in operator size dynamics under the other definition. Additionally, we extend previous studies by exploring finite-size effects that are not captured by the scramblon theory. Our results provide a refined understanding of operator size dynamics in open quantum systems.

A new approach to theory and simulation of the non-Markovian dynamics of open quantum systems is presented. It is based on identification of a parameter which is uniformly bounded on wide time intervals: the occupation of the virtual cloud of quanta. By ‘virtual’ we denote those bath excitations which were emitted by the open system, but eventually will be reabsorbed before any measurement of the bath state. A useful property of the virtual cloud is that the number of its quanta is expected to saturate on long times, since physically this cloud is a (retarded) polarization of the bath around the system. Therefore, the joint state of open system and virtual cloud (we call it dressed state) can be accurately represented in a truncated basis of Fock states, on a wide time scale. At the same time, there can be an arbitrarily large number of the observable quanta (which survive up to measurement), especially if the open system is under driving. However, it turns out that the statistics of the bath-measurement outcomes is classical (in a suitable measurement basis): one can employ a Monte Carlo sampling of these outcomes. Therefore, it is possible to efficiently simulate the dynamics of the observable quantum field. In this work we consider the bath measurement with respect to the coherent states, which yields the Husimi function as the positive (quasi)probability distribution of the outcomes. The joint evolution of the dressed state and the corresponding outcome is called the dressed quantum trajectory. The Monte Carlo sampling of these trajectories yields a stochastic simulation method with promising convergence properties on wide time scales.

This paper discusses several methods for describing the dynamics of open quantum systems, where the environment of the open system is infinite-dimensional. These are purifications, phase space forms, master equation and liouville equation forms. The main contribution is in using Feynman-Kac formalisms to describe the infinite-demsional components.

The repeated interaction model provides a framework for emulating and analyzing the dynamics of open quantum systems. We explore here the dynamics generated by this protocol in a system that is simultaneously coupled to two baths through noncommuting system operators. One bath is made to couple to nondiagonal elements of the system, thus it induces dissipative dynamics, while the other couples to diagonal elements, and by itself it generates pure dephasing. By solving the problem analytically exactly, we show that when both baths act concurrently, a strong systembath coupling gives rise to nonadditive effects in the dynamics. A prominent signature of this nonadditivity is the characteristic slowing down of population relaxation, driven by the influence of the dephasing bath. Beyond dynamics, we investigate the thermodynamic behavior of the model. Previous studies, using quantum master equations, showed that strong system-bath coupling created bath-cooperativity in this model, allowing heat exchange to the dephasing (diagonally coupled) bath. We find instead that, under the repeated interaction scheme, heat flows exclusively to the dissipative bath (coupled through nondiagonal elements). Our results highlight the need for a deeper understanding of the types of open quantum system dynamics and steady-state phenomena that emerge within the repeated interaction framework and the relation of this protocol to other common open quantum system techniques.

Non-Markovian open quantum systems represent the most general dynamics when the quantum system is coupled with a bath environment. The quantum dynamics arising from many important applications are non-Markovian. Although for special cases, such as Hamiltonian evolution and Lindblad evolution, quantum simulation algorithms have been extensively studied, efficient quantum simulations for the dynamics of non-Markovian open quantum systems remain underexplored. The most immediate obstacle for studying such systems is the lack of a universal succinct description of their dynamics. In this work, we fulfill the gap of studying such dynamics by (1) providing a succinct representation of the dynamics of non-Markovian open quantum systems with quantifiable error, and (2) developing an efficient quantum algorithm for simulating such dynamics with cost $${\mathcal {O}}(t\, \textrm{polylog}(t/\epsilon ))$$ for evolution time t and precision $$\epsilon $$ . Our derivation of the succinct representation is based on stochastic Schrödinger equations, which could lead to new alternatives to deal with open quantum systems as well.

We present a general analysis of the role of initial correlations between the open system and an environment on quantum dynamics of the open system.

We define quantum chaos and integrability in open quantum many-body systems as a dynamical property of single stochastic realizations, referred to as quantum trajectories. This definition relies on the predictions of random matrix theory applied to the subset of the Liouvillian eigenspectrum involved in each quantum trajectory. Our approach, which we name (SSQT), enables a natural distinction between transient and steady-state quantum chaos as general phenomena in open setups. We test the generality and reliability of the SSQT criterion on several dissipative systems, further showing that an open system with a chaotic structure can evolve towards either a chaotic or integrable steady state. We apply our theoretical framework to two driven-dissipative bosonic systems. First, we study the driven-dissipative Bose-Hubbard model, a paradigmatic example of a quantum simulator, clarifying the interplay of integrability, transient, and steady-state chaos across its phase diagram. Our analysis shows the existence of an emergent dissipative quantum chaotic phase, whereas the classical and semiclassical limits display an integrable behavior. In this regime, chaos arises from the quantum and classical fluctuations associated with the dissipation mechanisms. Second, we investigate dissipative quantum chaos in the dispersive readout of a transmon qubit: a measurement technique ubiquitous in superconducting-based quantum hardware. Through the SSQT, we distinguish several regimes where the performance of the measurement instrument can be connected to the integrable or chaotic nature of the underlying driven-dissipative bosonic system. Our work offers a general understanding of the integrable and chaotic dynamics of open quantum systems and paves the way for the investigation of dissipative quantum chaos and its consequences on state-of-the-art noisy intermediate-scale quantum devices.

Relaxation and decoherence processes are key features of the dynamics of open quantum systems [1]. In the standard approach one tries to develop appropriate master equations for the open system's reduced density matrix ρS which is given by the partial trace taken over the environmental variables coupled to the open system. Invoking the weak-coupling assumption one can formulate in many cases of physical interest a Markovian quantum master equation for the reduced density matrix, expressing the dynamical laws for the irreversible motion of the open system.

Instability of equilibrium states for coupled heat reservoirs at different temperatures

The dynamics of open quantum systems is formulated in terms of a probability distribution on the underlying Hilbert space. Defining the time-evolution of this probability distribution by means of a Liouvillemaster equation the time-dependent wave function of the system becomes a stochastic Markov process in the sense of classical probability theory. It is shown that the equation of motion for the two-point correlation function of the random wave function yields the quantum master equation for the statistical operator. Stochastic simulations of the Liouville-master equation are performed for a simple example from quantum optics and are shown to be in perfect agreement with the analytical solution of the corresponding equation for the statistical operator.

In general, nuclei and electrons in condensed matter and/or molecules are entangled, due to the prevailing (electromagnetic) interactions. As a matter of fact, the "environment" interacting with a microscopic system of interest (e.g. a proton) causes the destruction of the entanglement. This process, called decoherence, has until now prevented experimenters from directly accessing atomic and/or nuclear entanglement effects in real experiments. However, our neutron and electron Compton scattering experiments from protons (H-atoms) in several condensed systems and molecules at ambient conditions demonstrated a new striking effect, i.e. an "anomalous" decrease of scattering intensity from protons, which seem to become partially "invisible" to the neutrons. This effect, which has no interpretation within conventional neutron scattering theory, is proposed to be caused by the non-unitary time evolution (due to decoherence) during the ultrashort, but finite, time-window of the neutron-proton scattering process. Due to the large energy (several eV) and momentum (20-200 Å−1) transfers of these experiments the collisional time between the probe particle and a struck proton is 100–1000 attoseconds long. It is shown that, due to this short timescale, the scattering process must be theoretically treated within quantum dynamics of open quantum systems. New experimental neutron Compton scattering results from a single crystal KHCO3 are presented. They provide the first direct evidence for a connection between the momentum distribution and the "anomalous" scattering intensity of H. Additionally, recent experiments with electron-atom Compton scattering at momentum transfers are mentioned, which reveal the presence of this effect even in scattering from single H2 molecules in the gas phase. Theoretical discussions "from first principles" are presented, also in relation to the quantum Zeno effect, which underline the crucial role of decoherence in the considered experiments. The experimental results and their qualitative interpretation show that epithermal neutrons being available at spallation sources (e.g. ISIS/UK, SNS/USA or ESS/Sweden), and electron spectrometers with large scattering angles, provide tools for investigating new physical and chemical phenomena in the sub-femtosecond timescale.

We introduce simple diagrams and rules to calculate the exact time-local master equation for an arbitrary open quantum system interacting with a bath. In it, the time-convolutionless generator is expanded in the system-bath coupling to all orders, and the $n\mathrm{th}$-order contribution is expressed by the superoperators generated from the system operator in the system-bath coupling and the associated $n$-point nonequilibrium correlation functions of the environment operators. This theory generalizes previous attempts to obtain the time-convolutionless generator and provides a general framework to study the non-Markovian, nonequilibrium dynamics of open quantum systems.

Recently, a "unified" quantum master equationwas derived and shown to be of the Gorini-Kossakowski-Lindblad-Sudarshan form. This equationdescribes the dynamics of open quantum systems in a manner that forgoes the full secular approximation and retains the impact of coherences between eigenstates close in energy. We implement full counting statistics with the unified quantum master equationto investigate the statistics of energy currents through open quantum systems with nearly degenerate levels. We show that, in general, this equationgives rise to dynamics that satisfy fluctuation symmetry, a sufficient condition for the Second Law of Thermodynamics at the level of average fluxes. For systems with nearly degenerate energy levels, such that coherences build up, the unified equation is simultaneously thermodynamically consistent and more accurate than the fully secular master equation. We exemplify our results for a "V" system facilitating energy transport between two thermal baths at different temperatures. We compare the statistics of steady-state heat currents through this system as predicted by the unified equationto those given by the Redfield equation, which is less approximate but, in general, not thermodynamically consistent. We also compare results to the secular equation, where coherences are entirely abandoned. We find that maintaining coherences between nearly degenerate levels is essential to properly capture the current and its cumulants. On the other hand, the relative fluctuations of the heat current, which embody the thermodynamic uncertainty relation, display inconsequential dependence on quantum coherences.

Stochastic evolution underpins several approaches to the dynamics of open quantum systems, such as random modulation of Hamiltonian parameters, the stochastic Schrödinger equation (SSE), and the stochastic Liouville equation (SLE). These approaches replace the explicit system–environment coupling with an effective system‐only dynamics, where dissipative behavior emerges from ensemble averaging. Stochastic Hamiltonians, in particular, have long served as phenomenological tools in physical chemistry to include environmental effects without recourse to an explicit microscopic derivation. In this work, we aim at a self‐contained and accessible presentation of these approaches to further elaborate on their common roots in essential concepts of stochastic calculus and to delineate the conditions under which they are equivalent. We also discuss how different formulations naturally lead to different numerical time‐integration schemes, better suited for either classical simulation platforms, based on finite‐difference approximations, or quantum algorithms, that employ random unitary maps. Our analysis aims at providing a unified perspective and actionable recipes for classical and quantum implementations of stochastic evolution in the simulation of open quantum systems.

The dynamical behavior of open quantum systems plays a key role in many applications of quantum mechanics, examples ranging from fundamental problems, such as the environment-induced decay of quantum coherence and relaxation in many-body systems, to applications in condensed matter theory, quantum transport, quantum chemistry and quantum information. In close analogy to a classical Markov process, the interaction of an open quantum system with a noisy environment is often modelled by a dynamical semigroup with a generator in Lindblad form, which describes a memoryless dynamics leading to an irreversible loss of characteristic quantum features. However, in many applications open systems exhibit pronounced memory effects and a revival of genuine quantum properties such as quantum coherence and correlations. Here, recent results on the rich non-Markovian quantum dynamics of open systems are discussed, paying particular attention to the rigorous mathematical definition, to the physical interpretation and classification, as well as to the quantification of memory effects. The general theory is illustrated by a series of examples. The analysis reveals that memory effects of the open system dynamics reflect characteristic features of the environment which opens a new perspective for applications, namely to exploit a small open system as a quantum probe signifying nontrivial features of the environment it is interacting with. This article further explores the various physical sources of non-Markovian quantum dynamics, such as structured spectral densities, nonlocal correlations between environmental degrees of freedom and correlations in the initial system-environment state, in addition to developing schemes for their local detection. Recent experiments on the detection, quantification and control of non-Markovian quantum dynamics are also discussed.