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  • https://doi.org/10.1103/physreva.64.052509Copy DOI Icon

Useful alternative to the multipole expansion of1/rpotentials

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Abstract

Few-body problems involving Coulomb or gravitational interactions between pairs of particles, whether in classical or quantum physics, are generally handled through a standard multipole expansion of the two-body potentials. We discuss an alternative based on a compact, cylindrical Green's function expansion that should have wide applicability throughout physics. Two-electron "direct" and "exchange" integrals in many-electron quantum systems are evaluated to illustrate the procedure which is more compact than the standard one using Wigner coefficients and Slater integrals.

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