This paper concerns the viscoelastic properties and the resulting structure of colloidal systems with short-range attractions in the regime where the volume fraction f is small. Unlike the high ϕ regime, which is well understood in terms of mode-coupling theory (MCT), the low ϕ regime is still the subject of a debate based on different concepts such as percolation, diffusion-limited colloidal aggregation (DLCA), jamming, or cluster mode-coupling approach. Prior to the analysis of three examples of attractive systems at low ϕ values, a summary of concepts relevant to understanding the formation and properties of such attractive particles is discussed in the present study. Afterwards, we re-analyze the behaviour at a low ϕ of i) suspensions of carbon black (CB) particles, ii) suspensions of poly(methyl methacrylate) (PMMA) hard spheres with a depletion attraction induced by the addition of polystyrene (PS), and iii) suspensions of amino acid organogelator molecules which form rod-like objects. The rheological properties of these systems have been studied in detail and their response has been interpreted as being due either to a solid network discussed in relation to the jamming state diagram or to a suspension formed by jamming of clusters. Our analysis shows that these three systems are in fact cluster fluids and that their solid-like response corresponds to a change in their viscoelastic response, the elastic component G' becoming greater than the viscous component G" at low frequencies. Due to the presence of weak interparticle interactions in the tens range from 1 to 15 kBT, a liquid-like state is reversibly achieved at high frequencies, as indicated by the crossover of G' and G" as a function of frequency for a given concentration. Moreover, all these attractive particle systems at low ϕ show for both moduli a master curve which characterizes these cluster fluids and allows for the classification of these attractive particle systems.

Microalgae are microorganisms that are rich in bioactive compounds, including pigments, proteins, lipids, and polysaccharides. These compounds can be utilized for a number of biomedical purposes, including drug delivery, wound healing, and tissue engineering. Nevertheless, encapsulating microalgae cells and microalgae bioactive metabolites is vital to protect them and prevent premature degradation. This also enables the development of intelligent controlled release strategies for the bioactive compounds. This review outlines the most employed encapsulation techniques for microalgae, with a particular focus on their biomedical applications. These include ionic gelation, oil-in-water emulsions, and spray drying. Such techniques have been widely explored, due to their ability to protect sensitive compounds from degradation, enhance their stability, extend their shelf life, mask undesirable tastes or odours, control the release of bioactive compounds, and enable targeted delivery to specific sites within the body or environment. Moreover, a patent landscape analysis is also provided, allowing an overview of the microalgae encapsulation technology development applied to a variety of fields, including pharmaceuticals, cosmetics, food, and agriculture.