Effect of Temperature on the Reaction Products of Silicon in Fluorine-Based Plasmas
A key aspect in understanding silicon etching mechanisms is analyzing the characteristics of volatile reaction products, whose properties, particularly stoichiometry, vary significantly with temperature and fluorine coverage.These variations influence crucial etching attributes, such as reaction kinetics and the transition from isotropic to anisotropic etching.Temperature and fluorine coverage thus emerge as the primary determinants of the stoichiometry and complexity of reaction products.At low temperatures, the Langmuir-Hinshelwood mechanism dominates, where bimolecular reactions between adsorbed species produce SiF 4 as the major product.As temperature increases, thermal desorption becomes the primary mechanism, favoring the formation of SiF 2 and SiF.Similarly, fluorine coverage influences reaction pathways: under low coverage, SiF 4 is predominant, while higher coverage leads to more complex intermediates such as Si 2 F 6 and Si 3 F 8 through bimolecular or trimolecular reactions involving SiF 3 and SiF 2 .
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