This study investigates the tribological and electrochemical corrosion behavior of laser-clad nickel–aluminum bronze (NAB) coatings reinforced with WC particles (0, 8, 16 wt.%). Through microstructural characterization and phase analysis, it was found that in the NAB coating containing 16% WC, the WC particles and carbides were uniformly distributed, serving as a reinforcing scaffold. During the friction and wear process, they effectively reduced the contact area between the counter ball and the NAB matrix to a certain extent, smoothing the wear process and resulting in a more stable friction coefficient. Electrochemical testing demonstrates that WC addition significantly enhances corrosion resistance: NAB + 8%WC exhibits a low corrosion current density (icorr), the highest polarization resistance, and the densest protective film. The dual mechanisms—grain boundary blocking and ion channel obstruction—reduce selective Al/Fe leaching and minimize Cl− penetration. The 8% WC formulation optimizes the electrochemical performance, providing excellent corrosion resistance in a simulated marine environment.

Steel-fiber-reinforced concrete (SFRC), as a composite engineering material, exhibits excellent physical and mechanical properties, making it widely applied in civil engineering, construction, water conservancy, transportation, and port industries. To date, significant progress has been made in the research of plain and single-hook (3D) steel-fiber-reinforced concrete both domestically and internationally. With advancements in technology, multi-end hooked 4D and 5D steel fibers have emerged, offering more end hooks and a higher tensile strength. These fibers possess a stronger anchorage capacity with the matrix, and SFRC with multi-end hooked fibers exhibits superior tensile and flexural properties. However, research on multi-end hooked (4D and 5D) steel-fiber-reinforced concrete is still in its early stages, particularly regarding the axial tensile stress–crack width constitutive relationship. The accuracy and rationality of this constitutive relationship directly affect the reliability and precision of structural design. Therefore, in this study, a novel σ-w constitutive relationship model for steel-fiber-reinforced concrete and an axial tensile stress–crack width testing method for SFRC are proposed, based on 16 sets of uniaxial tensile tests. This model considers the comprehensive effects of the concrete matrix, fiber bridging, fiber volume fraction, fiber shape factor (effects of the number of hooked ends), aspect ratio, and crack width.

Femtosecond laser processing has emerged as a promising post-deposition method for tailoring the properties of dielectric thin films, offering localized modification without thermal damage. This study investigates the effect of sub-ablative femtosecond laser irradiation on the nonlinear optical response of a TiO2 single-layer coating deposited on soda-lime glass by electron-beam evaporation. The coating was modified using 35 fs pulses at 800 nm delivered at a repetition rate of 1 kHz and a fluence of 0.083 J/cm2 while varying the number of pulses per spot. The effective nonlinear refractive index (n2,eff) and effective nonlinear absorption coefficient (βeff) were measured using the z-scan technique with femtosecond excitation. The as-deposited TiO2 coating exhibited a negative effective nonlinear refractive index, signifying a self-defocusing nonlinear response, while femtosecond laser irradiation leads to pronounced changes in the effective nonlinear parameters. An increase in the magnitude of both effective nonlinear coefficients and a reversal of the sign of the effective nonlinear refractive index are experimentally observed after irradiation with higher pulse numbers. These findings provide experimental evidence that sub-ablative femtosecond laser processing can be used as a post-deposition tool to control the nonlinear optical response of TiO2 thin films.

Transparent conductive SnO2 films, promising for application in electronic engineering, were obtained by sol–gel synthesis via mixing SnCl2∙2H2O and NH4F solutions, followed by deposition onto glass substrates by centrifugation and heat treatment at 450 °C. The physicochemical processes of SnO2 crystallization in water–alcohol solutions of SnCl2 were analyzed depending on the concentration of the crystallization initiator NH4F and the alcohols used. The sol–gel processing of the thin films was investigated using a Latin square approach. Three factors affecting the film formation conditions were varied at three levels to determine the best combination of film properties involving the maximum transparency and lowest specific electrical resistance. The effect of solvent type (ethanol, 1-butanol and isopropanol), the amount of introduced fluorine (5, 10, and 15 at. %) and the number of deposited layers (10, 15, and 20) on the composition, morphology, crystallization features, transparency and specific surface resistance of the synthesized thin films was studied. The obtained films of ~200–340 nm thickness exhibited ~78%–95% transparency in the visible spectrum range and specific surface resistance (ρs) from ~109 to >1012 Ω/sq. The optimal combination of thin (~250 μm) SnO2<Sn> film target performances including transparency 84% and specific surface resistance ~109 Ω/sq. was achieved in the case of their preparation in isopropanol with an average concentration of NH4F (10 at. % F) and spin-on deposition of 20 layers.

The bottleneck of service stability of perovskite solar cells is rooted in the mechanical failure of its active layer materials at the micro scale. In order to deeply understand this process, the nano-indentation mechanical response of all-inorganic perovskite CsPbBr3 under pre-stress was studied by molecular dynamics simulation at the atomic scale. The core of this research work is to systematically reveal the quantitative influence of prestress, an inevitable initial stress state in the preparation and service of practical devices, on the near-surface mechanical behavior of materials. Firstly, the stress–strain response of the CsPbBr3 model at 300 K, 350 K, and 400 K was verified. The temperature dependence of its mechanical properties and the consistency with the experimental values confirmed the reliability of the force field and simulation method. In addition, by applying a series of uniaxial pre-strains, we analyzed the influence of prestress on the evolution of the force-depth curve and indentation strain during nano-indentation. The results show that the introduction of pre-strain will induce the material to have a significant “softening effect” and systematically reduce its ability to resist the intrusion of the indenter. More importantly, this study quantitatively reveals the asymmetric influence of prestress direction: tensile prestress leads to more serious softening than compressive prestress with the same amplitude, indicating that materials are more prone to plastic deformation under tensile preload. This work clarifies the key regulation function of prestress on the mechanical properties of perovskite thin films and provides a crucial theoretical basis for constructing accurate cross-scale mechanical models and designing perovskite photoelectric devices with high reliability and fatigue resistance.

This study aimed to develop and characterize novel 3D-printed chitosan methacryloyl (CSMA) hydrogel-functionalized nano-hydroxyapatite/polycaprolactone (nHA/PCL) scaffolds for controlled release of bone marrow mesenchymal stem cell-exosomes (BMSC-Exos), with the objective of enhancing osteogenic and angiogenic capabilities in vitro. We fabricated a biomimetic, highly porous scaffold composed of nHA/PCL using high-temperature fused deposition modeling. An interfacial bioactive layer was formed via ultraviolet-induced crosslinking of CSMA hydrogel on the scaffold and loaded bone marrow mesenchymal stem cell-exosomes. We characterized the composite scaffold to evaluate its physicochemical properties, cytocompatibility, cell migration ability, osteogenic capacity, and angiogenic capacity. The 3D-printed 20%nHA/PCL scaffold has a porosity of approximately 75%, with its surface containing four elements: carbon, oxygen, calcium, and phosphorus. The compressive strength is (13.76 ± 1.33) MPa. The CSMA hydrogel exhibits good injectability and degrades slowly over time. Exosomes with a negative charge are released slowly within the extracellular matrix hydrogel. The contact angle of the scaffold material is below 90 degrees, and the hemolysis rate is below 5%. In vitro assays demonstrated that the nHA/PCL-CSMA-Exos composite exhibited excellent biocompatibility, markedly enhanced cell proliferation and migration, and robust pro-angiogenic and osteogenic activity. The fabricated nHA/PCL-CSMA-Exos composite scaffolds demonstrated excellent physicochemical properties, biocompatibility, and cell migration ability, promoting angiogenesis, bone tissue formation and mineralization.

This paper provides a systematic review of urushiol-based antibacterial coatings for lacquer art applications, focusing on three key dimensions: molecular mechanisms, durability, and safety. Natural lacquer films form a dense three-dimensional network through laccase-catalyzed oxidative cross-linking, endowing them with excellent mechanical properties and corrosion resistance, while the catechol structure in urushiol confers broad-spectrum antibacterial potential. The article elaborates on the synergistic antibacterial mechanisms of urushiol, including covalent reactions with bacterial proteins via quinone intermediates, induction of oxidative stress, and metal ion chelation. It also reveals the dynamic change pattern of coating antibacterial activity over time, characterized by “high initial efficiency- gradual mid-term decline—long-term stabilization,” a process influenced collectively by side-chain unsaturation, degree of curing, and environmental factors such as temperature, humidity, and light exposure. From an application perspective, this review examines modification approaches such as silver/titanium dioxide composite systems, structurally regulated sustained-release strategies, and anti-adhesion surface designs, while pointing out current limitations in artistic compatibility, long-term durability, and safety assessment. Particularly in scenarios involving food contact and cultural heritage preservation, migration risks from unreacted urushiol monomers and metal nanoparticles, as well as the inherent sensitization potential of urushiol, remain critical challenges for safe application. Accordingly, this paper proposes the establishment of a holistic research framework covering “material design–process control–performance evaluation” and advocates for the development of functional coating systems with low migration, high biocompatibility, and preserved aesthetic value. Such advances are essential to promote the sustainable development and safe application of urushiol-based antibacterial coatings in fields such as cultural heritage conservation, daily-use utensils, and high-end decorative arts.

High-speed rotating machinery often demands bearings with superior load capacity and thermal stability. Here, a four-chamber radial hydrodynamic sliding bearing using supercritical carbon dioxide (S-CO2) as a lubricant is investigated to address these requirements. The work is carried out on the ANSYS Workbench 2024 R1 platform. Computational fluid dynamics (CFD) and structural mechanics are combined to build a fluid–structure interaction (FSI) numerical model. The model accounts for real-gas thermophysical property variations. S-CO2 properties are dynamically retrieved using the REFPROP database and MATLAB curve fitting. Unlike previous studies that mainly focused on hydrostatic structures and general parameters, this research examines hydrodynamic lubrication behavior under ultra-high-speed conditions. It systematically analyzes the effects of rotational speed on oil film pressure distribution, load capacity, friction coefficient, and housing deformation. It also investigates cavitation characteristics in a specific speed range. Simulation outcomes reveal that higher rotational speeds lead to an increase in both oil film load capacity and peak pressure. In particular, when the speed rises from 4000 r/min to 12,000 r/min, the maximum positive pressure increases from about 10 MPa to approximately 10.4 MPa. Meanwhile, the negative pressure region becomes significantly larger, which raises the cavitation risk and indicates a less stable lubrication state at very high speeds. These results confirm that lubrication simulations incorporating real-gas effects can reliably represent the operating behavior and provide useful guidance. It also provides new theoretical support for the design optimization and engineering application of S-CO2-lubricated bearings in high-speed machinery.

With the wide application of Ni-Al high-temperature materials, the research on their performance has increasingly attracted attention. To further advance the development of Ni-Al high-temperature materials, it is necessary to conduct an in-depth analysis of the brittleness mechanism of Ni-Al intermetallic compounds and elucidate the fundamental nature of their brittleness. In this study, the tensile mechanical behavior and microscopic mechanism of single crystals NiAl (B2) and Ni3Al (L12) at different temperatures were systematically studied by molecular dynamics simulations. It is revealed that although the mechanical properties of both NiAl and Ni3Al degrade with increasing temperature, their deformation mechanisms exhibit fundamental differences. The high-temperature strength of NiAl is attributed to stable plastic flow dominated by 1/2 <111> screw dislocation. The early softening of Ni3Al is associated with the formation of stacking fault formation, the phase transition to the HCP, and the slip of various incomplete dislocations (e.g., 1/6 <112> Shockley dislocation). Atomic strain analysis shows that regions of high strain exhibit a strong spatial correlation with the phase-transformed domains. This study reveals the distinct deformation mechanism of the two alloy phases at the atomic scale, providing a key theoretical basis for the rational selection of Ni-Al alloy in specific high-temperature applications.

The increasing demand for sustainable food systems has sparked interest in sustainable and safe food systems, which has intensified global interest in strategies that can reduce losses, maintain quality, and decrease the environmental footprint of packaging [...]