Gold nanoparticles (AuNPs) are arguably the most promising in terms of application among the noble metal nanoparticles. As such, researchers have dedicated a considerable amount of energy towards the synthesis of novel gold nanoparticles with different morphology and size, which in turn affect its potential application. This study synthesized novel spherical-shaped AuNPs via green reduction of gold ion in an aqueous solution of HAuCl4.3H2O in the presence of trimethyl chitosan as a stabilizing agent and pressurized H2 gas as a reducing agent on an ice water. The size, morphology, chemical composition, chemical environment and optical activities were examined by scanning electron microscope (SEM), high-resolution transmission electron microscope (HR-TEM), x-ray photoelectron spectroscopy (XPS), and ultraviolet–visible spectroscopy (Uv–Visible), respectively. The average particle size of AuNPs is 37 nm while HR-TEM revealed a unique spherical morphology. The Tauc's plot calculation revealed a band gap of 5.0 eV. This unique morphology and optical local field enhancement in plasmonic nanocomposites could be suitable alternative for conducting devices and photocatalysis.

The rare decays, K+→π+νν¯, B+→π+νν¯ and D+→π+νν¯, are investigated in the frame work of nonstandard neutrino interactions (NSI). It is claimed that NSI are arising due to non-universality of the leptons and bounds on NSI parameters ϵll′uL are determined. For this purpose, the branching ratios (Br) of these processes with in the Standard Model (SM) and beyond the SM are calculated by applying the non-universality of the leptons. The NSI in K+→π+νν¯ and B+→π+νν¯ proceed with u quark in the loop while other two with d quark in the loop. Very stringent 1 σ level constrains on non-standard parameters (ϵττuL and ϵτl′uL) are pointed out.