- Research Article
- 10.46813/2026-161-199
DIFFUSION EFFECT OF PLASMA-SPRAYED TI-N COATINGS IN COPPER ALLOY DIE CASTING MOLDS
- Jan 30, 2026
- Problems of Atomic Science and Technology
- V.a Sharagov + 3 more +3
The effectiveness of thin plasma coatings with titanium nitride (TiN) applied by the method of condensation in ion baths (IB) on the working surface of molds under the pressure of copper alloys (steel 4Kh5MFS and 5KhNM) was investigated. It has been shown that coating with a thickness of up to 5 m significantly increases the durability of molds: before the first regrinding by 1.5–2.5 times (3–5 thousand cycles versus 2 thousand without coating), and the core life before failure by 5–6 times (not less than 12 thousand cycles). It has been established that after removing the coating (when regrinding to a depth of ≥20 µm), the drying function is preserved due to the diffusion of titanium in the near-surface steel balls during thermal cycling. Titanium, which diffuses, creates dispersed inclusions of a foldable structure (Ti-N and Ti-V-N) with a size of 2…10 μm, which plays the role of the essential phase, moving between the dislocation and the moving support of the thermal fatigue. The microhardness of the surface ball after operation and regrinding increases up to 750…800 MPa (versus 450…480 MPa for uncoated steel). The phenomenon of the mechanism of “self-adhesive” value for the structure of cerated diffusion of titanium and the creation of non-metallic inclusions of optimal size has not been described before in the literature with ionplasma coatings and is still new approach to increasing the resource of molds for casting under the pressure of aggressive copper alloys.
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