In the present work, characterization of sintering behavior of Tungsten heavy alloy has been done through powder metallurgy route using Spark plasma sintering (SPS). Fine powder of Tungsten (<30 ?m) was separately mixed with Ni, Co, Fe, Mo and Cu each with 1 weight%. Spark Plasma Sintering (SPS) technique (1200?C, 20 MPa pressure with 1 min holding time) was used to sinter the mixed powders. The maximum density was observed in W-Ni followed by Co, Fe, Cu, Mo and with least in pure tungsten sample. Optical microscopy as well SEM was done to determine the microstructure and grain coarsening. Due to the short heating time very less grain coarsening was observed. Vickers hardness test was conducted which resulted in maximum hardness in case if W-1Fe SPS sample.

Mechanical shock of zircon based ceramic induced by cavitation erosion testing was investigated in this study. Several parameters were followed in order to determine level of material degradation during the cavitation erosion testing. Mass loss was taken as a conventional criterion for material degradation, while the level of surface degradation was evaluated by image and thermal imaging analyses. Results show high cavitation resistance of zircon ceramics and their suitability when vigorous cavitation erosion environment is expected.

In this paper layered and gradient structures of Ni-Al SHS system were adopted to manufacture Ni-Al/diamond composites. The effect of the layered and the diamond mesh gradient structures of Ni-Al/diamond on the SHS process and the microstructure of the composites were investigated. It is found that with the increasing of the number of layers, the combustion wave velocity is decreased. The combustion wave velocity for diamond mesh size gradient structure of Ni-Al SHS is faster than that for the layered structure. A well bonding can be formed between diamond and the matrix in layered and gradient structure Ni-Al/diamond composites due to the melt of Ni-Cr brazing alloy.

The acoustic emission (AE) and fractoluminescence (FL) techniques were applied to study the impact damage in sintered powders of SiO2, SiC and Al2O3 and their single crystal counterparts. The measured AE intensities and FL amplitudes are proportional to the energy release in events of microcrack nucleation and chemical bond breakage, respectively. In crystals, the AE method showed the random energy release in crystals, and the scaling energy distributions in powders. The FL method evidenced the self-similar energy distributions in α-SiO2 and α-SiC due to nanostructural heterogeneity inherent even to homogeneous solids, while luminescence from α-Al2O3 was specific for the random process.

In this study, four unique groups of nano-cemented carbides with 8 wt.% Co and trace amount of Mo and VC have been successfully synthesized. The effect of Mo and VC has been investigated comprehensively on both the microstructure and mechanical behavior of nano-cemented carbide. The results show that Mo significantly increases hardness but decreases the fracture toughnesses and VC slightly increases hardness and strongly increases fracture toughness of nano-cemented carbide. It is found that the optimum Mo and VC contents are both 0.5 wt.%. The average WC grain size is about 370 nm. The hardness is about 2350 HV30 and the fracture toughness is about 11.2 MPam-1/2.

Nanostructured nickel-iron-tungsten alloys were produced by electrodeposition from an ammoniacal citrate bath. The tungsten content of the alloy ranged from 0.8 wt.% to 11 wt.%, and the crystal grain size of the FCC phase of the solid solution of iron and tungsten in nickel was between 14 nm and 3.3 nm. The amorphous phase content of the alloy increases with decreasing crystal grain size. As the amorphous phase content increases, the magnetization, electrical conductivity and hardness of the alloy decrease. Annealing the alloy to crystallization temperature results in structural relaxation during which the alloy undergoes short-range ordering in conjunction with decreases in the density of chaotically distributed dislocations and internal microstrain level, which increases the exchange integral value, the electronic density of states at the Fermi level, the mean free path of electrons, the ordering and the mean size of cluster in the sliding plane and results in more uniform orientation of dipole moments of certain nanoparticles. These changes: a) increase the mobility of magnetic domain walls, facilitate the orientation of domains in the external magnetic field and cause an increase in magnetization; b) cause a decrease in electrical resistance, and c) impede the sliding of grain boundaries and increase the hardness of the alloy. Annealing the alloys at temperatures above 400?C results in amorphous phase crystallization and larger crystal grains of the FCC phase, along with a decrease in the density of chaotically distributed dislocations and a decrease in internal microstrain level. The formation of larger crystal grains reduces the hardness of the alloy, decreases its specific electrical resistance and impedes both the orientation of certain magnetic domains and the shift of walls of already oriented domains, thus inducing a decrease in magnetization. The heat released during the milling of Ni87.3Fe11.3W1.4 alloy with FCC-phase crystal grains 8.8 nm in average size causes amorphous phase crystallization, FCC crystal grain growth and an increase in magnetization. Alloys with relatively high tungsten content (11 wt. %) have an inhomogeneous composition, a high proportion of the amorphous phase and FCC crystal grains with an average size of 3.3 nm. This microstructure results in magnetic domains that have different and relatively low thermal stabilities and relatively low degrees of magnetization.

Frenkel's liquid-phase sintering mechanism has essential influence on the sintering of materials, however, by which only the initial 10% during isothermal sintering can be well explained. To overcome this shortage, Nikolic et al. introduced a mathematical model of shrinkage vs. sintering time concerning the activated volume evolution. This article compares the model established by Nikolic et al. with that of the Frenkel's liquid-phase sintering mechanism. The model is verified reliable via training the height and diameter data of cordierite glass by Giess et al. and the first-order partial differential equation. It is verified that the higher the temperature, the more quickly the value of the first-order partial differential equation with time and the relative initial effective activated volume to that in the final equibrium state increases to zero, and the more reliable the model is.

Porous SiC/Cordierite Composite Material with graphite content (10%) was synthesized. Evaluation of Young modulus of elasticity and thermal shock behavior of these samples was presented. Thermal shock behavior was monitored using water quench test, and non destructive methods such are UPVT and image analysis were also used for accompaniment the level of destruction of the samples during water quench test. Based on the level of destruction graphical modeling of critical number of cycles was given. This approach was implemented on discussion of the influence of the graphite content on thermal stability behavior of the samples.

As the only bioactive material that can bond with both hard tissues and soft tissues, bioactive glass has become much important in the field of tissue engineering. 13-93 bioactive glass scaffolds were fabricated via selective laser sintering (SLS). It was focused on the effects of laser sintering on microstructure and mechanical properties of the scaffolds. The experimental results showed that the sintered layer gradually became dense with the laser power increasing and then some defects occurred, such as macroscopic caves. The optimum compressive strength and fracture toughness were 21.43?0.87 MPa and 1.14?0.09 MPa.m1/2, respectively. In vitro bioactivity showed that there was the bone-like apatite layer on the surface of the scaffolds after soaking in simulated body fluid (SBF), which was further evaluated by Fourier transform infrared spectroscopy (FTIR). Moreover, cell culture study showed MG-63 cells adhered and spread well on the scaffolds, and proliferated with increasing time in cell culture. These indicated excellent bioactivity and biocompatibility of nano 13-93 glass scaffolds.

Powder mixture of 50 mass % of barium titanate (BaTiO3) and 50 mass % of iron (Fe) was prepared by solid-state reaction technique, i.e. ball milled in air for 60 min, 80 min, 100 min, 120 min and 150 min. During mechanochemical activation it was observed the iron powder transitsion to iron oxides. Depending on the activation time the content of iron oxides FeO, Fe2O3 and Fe3O4 varies. Simultaneously, with the content change of the activated system, magnetic properties change as well. The XRD analysis of milled samples shown that as the activation time increase, the iron oxide percentage increases to, whereby the percentage of BaTiO3 in a total sample mass decreases. The percentage of iron oxides and BaTiO3 in annealed samples changes depending on annealing temperature. The thermomagnetic measurements performed by Faraday method shown that the powder mixture milled for 100 minutes exhibit maximum magnetization prior to annealing. The increase of magnetization maximum was observed after annealing at 540?C with all milled samples, and at room temperature it has enhancement from 10 % to 22 % depending on the activation time. The samples milled for 100 min and 150 min and then sintered at 1200w?C exhibit magnetoelectric properties.