Thermal properties and effect of elevated temperatures on the residual properties of lithium slag blended concrete
Abstract This study evaluates the thermal properties and effects of elevated temperatures on the residual properties of concretes containing lithium slag (LS) at cement replacement levels of 20%, 40%, and 60%. The results indicate that LS reduced the thermal conductivity of concrete by 1.08%, 4.47%, and 14.31% for using 20%, 40%, and 60% LS, respectively, while decreasing thermal diffusivity with the addition of LS. Conversely, volumetric heat capacity increased from 1.85 MJ/m 3 ·K (control) to 1.87, 1.92, and 2.06 MJ/m 3 ·K, indicating enhanced heat‐retention capability with the increase of LS content. In the elevated temperature tests, the 20%–40% LS concretes showed finer cracks compared to those in the control and 60LS concretes. No spalling was observed up to 800°C. Mass loss increased with the increase of temperature, reaching 7.2% at 600°C for the 60LS mix, whereas the 20%–40% LS concretes showed slightly lower mass losses than the control. Residual compressive strength also decreased with the increase of temperature, with the 20%–40% replacement retaining higher strength up to 600°C, while the 60% LS concrete experienced the highest strength loss. Ultrasonic pulse velocity results indicated progressive internal degradation, with a notable drop at 800°C. TGA confirmed enhanced thermal stability in the 20%–40% LS concretes through reduced Ca(OH) 2 decomposition and increased formation of stable hydration products. The SEM analysis showed denser microstructures in the 40LS mix compared to higher porosity in the control and 60LS concretes. Overall, the 20%–40% LS concretes demonstrated superior thermal resistance and high‐temperature performance.
Read more