High JC behavior in novel TiN-buffered Fe(Se,Te) coated conductors driven by secondary phase nano-inclusions
Abstract Iron-based superconductors (IBS) such as FeSe0.5Te0.5 (Fe(Se,Te)) are highly promising for applications in high magnetic fields and low temperatures, allowing their adoption in liquid helium at fields exceeding 20 T. In these regimes, while high-temperature superconductors (HTS) exhibit superior performance, IBS materials offer advantages, including a large critical grain-boundary angle that reduces the need for strict texturing, making them strong candidates for coated conductors. Fe(Se,Te) films can be deposited under less extreme conditions compared to HTS, simplifying manufacturing and making Fe(Se,Te)-based coated conductors a cost-effective alternative for large-scale production.
Recently, we demonstrated that a thin TiN film serves as an effective buffer layer, enabling the oriented growth of superconducting Fe(Se,Te) on biaxially textured Ni-W. This leads to a simple coated conductor architecture, fabricated using Pulsed Laser Deposition (PLD), based on a single electrically conducting buffer layer. The resulting tape exhibits normal-state resistivity comparable to that of the substrate, proving the electrical connection that allows the substrate itself to function as an intrinsic stabiliser. 
In this work, we analyse the microstructure of the TiN-based tape via TEM, elucidating the Fe(Se,Te) growth mechanism on the mismatched TiN buffer layer and investigating the micro- and nanostructure of the superconducting film. Depending on deposition conditions, the formation of a nanostructured hexagonal secondary phase was detected, contributing an effective pinning landscape. This results in high critical current densities ( J C ), exceeding 0.1 MA/cm² at 4.2 K in magnetic fields up to 17.5 T and around 3.2 MA/cm² at 4.2 K in self-field. The angular dependence of the critical current density reveals a quasi-isotropic behaviour, attributed to the presence of the nanosized secondary phase, contributing to uniformly distributed pinning centres within the superconducting matrix.
These findings represent significant advancements in process simplification and performance of Fe(Se,Te)-based coated conductors, further reinforcing the potential of IBS-coated conductors for applications.
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