- Research Article
- 10.1021/acsphotonics.5c02766
Tri-Mode Multicolor Composite Fibers for All-Season Self-Adaptive Thermoregulation
- Jan 23, 2026
- ACS Photonics
- Guohao Xia + 7 more +7
Addressing the substantial energy consumption from building heating and cooling is critical for climate change mitigation. Passive daytime radiative cooling (PDRC) offers a highly promising zero-energy strategy to mitigate global warming; however, it encounters several key limitations, including susceptibility to overcooling, constrained environmental adaptability, and challenges in manufacturability. Herein, we develop a trimode multicolor thermochromic canopy with distinct microsphere-rich and pore-rich zones in orthogonal polytetrafluoroethylene (PTFE) fibrous membranes. This design achieves programmable multitemperature spectral responses, including high mid-infrared emissivity (0.94) in the atmospheric transparency window, competitive near-infrared reflectance (93.7%), and visible light modulation capability of 30.44% via polychromic thermochromic microcapsules (TMs). Promisingly, our PTFE/TM composite enables three autonomous operational modes, yielding a maximum subambient daytime cooling of 7.6 °C in hot conditions, heating of 5.4 °C in cold conditions, and a stable intermediate state at comfortable temperatures. The composite also exhibited excellent durability and superhydrophobicity. EnergyPlus simulations confirm the significant global potential, showing substantial annual energy savings and CO2 emission reductions across diverse climates, outperforming static cooling materials by effectively avoiding overcooling penalties. This work provides a viable zero-energy pathway for mitigating urban heat island effects and promoting climate-resilient building thermal regulation.
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