- Research Article
- 10.1021/acsaelm.5c02633
Structure–Function Coupling in Pyridyl TriazoleCopolymers for Neuromorphic Synaptic Transistors
- Feb 12, 2026
- ACS Applied Electronic Materials
- Arash Ghobadi + 11 more +11
Organic ferroelectrictransistors are excellent candidates as low-costalternatives for synaptic devices. Specifically, interfaces with donor–acceptorsemiconducting polymers and copolymers of poly(vinylidene fluoride)(PVDF) are attractive for mimicking synaptic responses. By tailoringthe linking unit between the pyridyl triazole (PyTr) acceptors andthiophene donors, three copolymers are synthesized incorporating selenium-substitutedthiophene, benzothiadiazole, and fluorine-substituted thiophene linkers.Using the hexafluoropropylene copolymer of PVDF (PVDF-HFP) as thedielectric layer, the three PyTr semiconductors show p-type transportin transistor architectures with carrier mobilities between 0.1 and0.2 cm2 V–1 s–1. Thesynaptic plasticity is investigated by applying long-term pulsed voltagesat the gate electrode to emulate potentiation and depression processes.To assess their neuromorphic functionality, the synaptic responsesof the devices are tested for image recognition in a multilayer perceptronneural network. The copolymer with the benzothiadiazole linker achievedrecognition accuracy close to 80%, whereas the one with a fluorine-substitutedthiophene linker shows no synaptic behavior, highlighting the criticalrole of the semiconductor–dielectric interface. A detailedstudy of the interface trap density and morphology is performed toidentify how interfacial properties directly influence synaptic deviceperformance.
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