Solid oxide fuel cells (SOFCs), as highly efficient energy conversion devices, are anticipated to play a significant role in the realization of a low-carbon society. ENE-FARM type S (EF), equipped with SOFC stack, has been commercialized since 2012 by Osaka Gas. To further expand the market of EF, higher electrical efficiency, higher durability, lower cost of SOFC stack, and downsizing of EF are needed. For realizing these issues, two model changes were conducted in 2016 and 2020. The SOFC stack installed in the current EF, which is composed of Anode-supported SOFC (ASC), has established durability of over 12 years. For further widespread adoption in the EF market, we have focused on Metal-supported SOFCs (MSC), which have the potential to reduce costs by using fewer expensive ceramics.However, the use of a metal substrate in MSCs introduces unknown degradation phenomena that differ from those in ASCs. These phenomena include the degradation of the metal substrate and the interfacial reaction between the metal substrate and anode due to interdiffusion from the metal substrate and anode. Understanding and addressing the degradation phenomena originating from a metal substrate are significant challenges for the commercialization of MSCs. In this study, we investigated the degradation phenomena of MSCs, especially at the metal substrate/anode interface.The degradation phenomena are influenced by evaluation conditions such as durability time, temperature, and gas composition. The concentration of water vapor at the fuel gas outlet is much higher than at the fuel gas inlet throughout electrochemical reactions. To confirm the differences in the degradation phenomena due to gas composition, two MSC pieces were prepared. MSCs were fabricated at a lower temperature compared to ASCs, utilizing ceramic electrodes and electrolytes on a 16 cm2 ferritic stainless-steel substrate. Single cell tests were conducted using air at the cathode and fuel at the anode. The operating conditions for the evaluation were as follows: current density was varied from 0 to 0.42 A/cm², with H₂/H₂O used as the anode gas at two different dew points (DP). Test 1 was conducted at a DP of 30°C, and Test 2 was conducted at a DP of 88°C, while air served as the cathode gas. Both the anode gas and air flow rates were fixed during the evaluation. The operation was conducted with a fuel utilization factor (Uf) of approximately 10% and an air utilization factor (Ua) of approximately 20% at 0.42 A/cm².Figure 1 shows the results of the durability tests of 16 cm2-MSC cells conducted at 800°C. The change in voltage from the initial value is denoted as ΔV. The reduction in voltage on the fuel outlet side was approximately 25 mV greater than that on the fuel inlet side after 1000 hours. During these durability tests, the IR and electrode overvoltage (η) were measured by the current interruption method. The open circuit voltage remained stable without significant changes throughout the 1000 hours durability tests for both the fuel inlet and outlet sides. Figure 2 shows the results of IR and η during the durability tests conducted at 800°C. The observed reduction in voltage was attributed to increases in both IR and η, with similar increments noted for both the fuel inlet and outlet sides in relation to IR. It was found that no abnormally high resistance layer formation or significant increase in oxidation layer occurred on the outlet side after 1000 hours at 800°C.The more pronounced voltage drop observed at the outlet side is primarily due to a more significant increase in η. Considering that the evaluation was conducted under uniform conditions, except for the water vapor concentration on the anode gas side, it is plausible that the factors contributing to the increase in η are associated with the sintering or poisoning of the anode. These findings suggest that the reduction in reaction area and decreased gas diffusivity are significant contributors to the observed effects. In the presentation, we will discuss the insights derived from the electrochemical measurement results along with detailed cross-sectional analyses conducted after the durability tests. Figure 1
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