A New Nonlinear Viscoelastic Constitutive Equation for Predicting Yield in Amorphous Solid Polymers

This chapter deals with how to measure nonlinear viscoelastic functions and various nonlinear viscoelastic constitutive equations. Since there have been developed a number of constitutive equations which cannot be included in a single chapter, this chapter considers only a few popularly used ones, which are classified to four groups: the models based on mathematical approximations; the models obtained from the generalization of linear viscoelastic models; the models based on the simplification of polymer structure; and the Leonov model which is a class of constitutive equations based on irreversible thermodynamics.

The penetration of long gas bubble through a viscoelastic fluid in a capillary tube has been studied in order to investigate the influence of viscoelastic material properties on the hydrodynamic coating thickness and local flow kinematics. Experiments are conducted for three tailored ideal elastic (Boger) fluids, designed to exhibit similar steady shear properties but substantially different elastic material functions. This allows for the isolation of elastic and extensional material effects on the bubble penetration process. The shear and extensional rheology of the fluid is characterized using rotational and filament stretching rheometers (FSR). The fluids are designed such that the steady-state extensional viscosity measured by the FSR at a Deborah number (De) greater than 1 differs over three orders of magnitude (Trouton ratio = 103–106). The experiment set up to measure the hydrodynamic coating thickness is designed to provide accurate data over a wide range of capillary numbers (0.01 < Ca < 100). The results indicate that the coating thickness in this process increases with an increase in the extensionally thickening nature of the fluid. Experiments are also conducted using several different capillary tube diameters (0.1 < D < 1 cm), in order to compare responses at similar Ca but different flow De. Suitable scaling methods and nonlinear viscoelastic constitutive equations are explored to characterize the displacement process for polymeric fluids. Bubble tip shapes at different De are recorded using a CCD camera, and measured using an edge detection algorithm. The influence of the mixed flow field on the bubble tip shape is examined. Particle tracking velocimetry experiments are conducted to compare the influence of viscoelastic properties on the velocity field in the vicinity of the bubble tip. Local shear and extension rates are calculated in the vicinity of the bubble tip from the velocity data. The results provide quantitative information on the influence of elastic and extensional properties on the bubble penetration process in gas-assisted injection molding. The bubble shape and velocity field information provides a basis for evaluating the performance of constitutive equations in mixed flow.

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This paper investigates the dependence of the subharmonic response in a signal scattered by contrast agent microbubbles on ambient pressure to provide quantitative estimations of local blood pressure. The problem is formulated by assuming a gas bubble encapsulated by a shell of finite thickness with dynamic behavior modeled by a nonlinear viscoelastic constitutive equation. For ambient overpressure compatible with the clinical range, the acoustic pressure intervals where the subharmonic signal may be detected (above the threshold for the onset and below the limit value for the first chaotic transition) are determined. The analysis shows that as the overpressure is increased, all harmonic components are displaced to higher frequencies. This displacement is significant for the subharmonic of order 1/2 and explains the increase or decrease in the subharmonic amplitude with ambient pressure described in previous works. Thus, some questions related to the monotonic dependence of the subharmonic amplitude on ambient pressure are clarified. For different acoustic pressures, quantitative conditions for determining the intervals where the subharmonic amplitude is a monotonic or non-monotonic function of the ambient pressure are provided. Finally, the influence of the ambient pressure on the subharmonic resonance frequency is analyzed.

ABSTRACTWithout knowing the dynamic constitutive relation of materials under high strain rates, no wave propagation can be correctly analyzed. A Series of experimental and theoretical investigation at high strain rates revealed that the nonlinear viscoelastic behavior of polymers and the related composites are well described by the Zhu-Wang-Tang (ZWT) nonlinear viscoelastic constitutive equation. The impulsive reponse of ZWT materials consists of a rate independent nonlinear elastic response and a high frequency linear viscoelastic response. The dispersion and attenuation of nonlinear viscoelastic waves mainly depend on the effective nonlinearity and the high frequency relaxation time θ2. An “effective influence distance” or “effective influence time” is defined to characterize the wave propagation range where θ2 dominates the impact relaxation process.

Methods of quasi-static deformation and fracture analysis are developed for a class of nonlinear viscoelastic media and sample applications are given. Selection of the class of media is guided by actual rheological behavior of monolithic and composite materials as well as the need for simplicity to be able to understand the effect of primary material and continuum parameters on crack growth behavior. First, pertinent aspects of J integral and energy release rate theory for nonlinear elastic media are discussed. Nonlinear viscoelastic constitutive equations are then given, and correspondence principles which establish a simple relationship between mechanical states of elastic and viscoelastic media are developed. These principles provide the basis for the subsequent extension of J integral theory to crack growth in viscoelastic materials. Emphasis is on predicting mechanical work available at the crack tip for initiation and continuation of growth; some examples show how viscoelastic properties and the J integral affect growth behavior. Included is the problem of a crack in a thin layer having different viscoelastic properties than the surrounding continuum. The Appendix gives an apparently new constitutive theory for elastic and viscoelastic materials with changing microstructure (e.g. distributed damage) and indicates the conditions under which the fracture theory in the body of the paper is applicable.

Numerical simulation is one of the effective tools for the long-term stability assessment of underground structures. The reliability improvement of the numerical simulation requires precise constitutive equations to reproduce time-dependent behavior of rock such as loading-rate dependence, creep, and relaxation. These time-dependent behaviors of rock have nonlinearity between stress and strain rate and are influenced by surrounding environment. A number of constitutive equations have been proposed in previous studies; however, the equations based on the theory of linear viscoelasticity have difficulty reproducing accurately the time-dependent behavior of rock, and most of the equations based on the theory of viscoplasticity have been applied to the limited loading condition such as creep. In this article, nonlinear viscoelastic constitutive equations for rock proposed by the authors were introduced, and their exact solutions and application to experimental results were summarized. These equations can reproduce nonlinear time-dependent behavior and not only brittle but also ductile failures of rock and can be applied to the behavior under various loading conditions and experiment environment. In the equations, compliance or inelastic strain is assumed to be increased with time, but the functions and their combinations are of great variety. Hence, the differences of the solutions and applicability of the equations were detailed, and in addition future subjects were presented.

For the class of all discrete two-velocity models of the nonlinear Boltzmann equation consistent with theH-theorem an exact representation of the corresponding nonlinear constitutive equation will be derived. Applying the fractional calculus we derive, in addition, the nonlinear fractional Boltzmann equation as the starting point for the formulation of a nonlinear fractional constitutive equation which relates the densities and fluxes through an integro-differential equation. Linearization leads to the fractional version of Cattaneo's constitutive law. The model presented here may be regarded as a first step, towards the formulation of a fractional extended irreversible thermodynamics.

Considering the influence of temperature and strain variables on materials. According to the relationship of conjugate stress-strain, a complete and irreducible non-linear constitutive equation of isotropic hyperelastic materials is derived and the constitutive equations of 16 types of isotropic hyperelastic materials are given we study the transformation methods and routes of 16 kinds of constitutive equations and the study proves that transformation of two forms of constitutive equation. As an example of application, the non-linear thermo-elastic constitutive equation of isotropic hyperelastic materials is combined with the natural vulcanized rubber experimental data in the existing literature base on MATLAB, The results show that the fitting accuracy is satisfactory.

A comparison of second-order constitutive theories for hyperelastic materials

Material parameters related to deterministic models can have different values due to variation of experiments outcome. From a mathematical point of view, probabilistic modeling can improve this problem. It means that material parameters of constitutive models can be characterized as random variables with a probability distribution. To this end, we propose a constitutive models of rubber-like materials based on uncertainty quantification (UQ) approach. UQ reduces uncertainties in both computational and real-world applications. Constitutive models in elastomers play a crucial role in both science and industry due to their unique hyper-elastic behavior under different loading conditions (uni-axial extension, biaxial, or pure shear). Here our goal is to model the uncertainty in constitutive models of elastomers, and accordingly, identify sensitive parameters that we highly contribute to model uncertainty and error. Modern UQ models can be implemented to use the physics of the problem compared to black-box machine learning approaches that uses data only. In this research, we propagate uncertainty through the model, characterize sensitivity of material behavior to show the importance of each parameter for uncertainty reduction. To this end, we utilized Bayesian rules to develop a model considering uncertainty in the mechanical response of elastomers. As an important assumption, we believe that our measurements are around the model prediction, but it is contaminated by Gaussian noise. We can make the noise by maximizing the posterior. The uni-axial extension experimental data set is used to calibrate the model and propagate uncertainty in this research.

A bimodular nonlinear constitutive equation for rock

The famous bifurcation analysis performed by Flügge on compressed thin-walled cylinders is based on a series of simplifying assumptions, which allow to obtain the bifurcation landscape, together with explicit expressions for limit behaviours: surface instability, wrinkling, and Euler rod buckling. The most severe assumption introduced by Flügge is the use of an incremental constitutive equation, which does not follow from any nonlinear hyperelastic constitutive law. This is a strong limitation for the applicability of the theory, which becomes questionable when is utilized for a material characterized by a different constitutive equation, such as for instance a Mooney-Rivlin material. We re-derive the entire Flügge's formulation, thus obtaining a framework where any constitutive equation fits. The use of two different nonlinear hyperelastic constitutive equations, referred to compressible materials, leads to incremental equations, which reduce to those derived by Flügge under suitable simplifications. His results are confirmed, together with all the limit equations, now rigorously obtained, and his theory is extended. This extension of the theory of buckling of thin shells allows for computationally efficient determination of bifurcation landscapes for nonlinear constitutive laws, which may for instance be used to model biomechanics of arteries, or soft pneumatic robot arms.

In the finite deformation range, the numbers of orthotropic 2n order elastic constants are studied on the basis of tensor function and of its representation theorem. On the basis of elastic constant research, the elastic orthotropic constitutive equation is derived by using the tensor method. Based on orthotropic elastic constitutive equations an in-depth study on the constitutive theory of orthotropic nonlinear thermal elasticity is carried out, and by considering the deformation produced by the coupling of temperature and load, nonlinear orthotropic thermoelastic constitutive equation is further derived with representation of the tensor invariant and scalar invariant. The constitutive equations could be used very convenient to the application in reality.

In the analysis of weak solutions relevant to evolutionary flows of incompressible fluids with non-constant viscosity or with non-linear constitutive equation, it is in general an open question whether a globally integrable pressure exists if the flows are subject to no-slip boundary conditions. Here we overcome this deficiency by considering threshold boundary conditions stating that the fluid adheres to the boundary until certain critical value for the wall shear stress is reached. Once the wall shear stress exceeds this critical value, the fluid slips. The main ingredient in our approach is to look at this type of activated, stick-slip, boundary condition as an implicit constitutive equation on the boundary.