Nonlinear Constitutive Equations

A new constitutive equation has been developed for describing the nonlinear viscoelastic properties, including yield, of polymer solids. The nonlinear viscoelastic constitutive equation is the logical extension of the standard three‐dimensional linear viscoelastic constitutive equation to include the effects of deformation‐induced changes in the thermodynamic state of the polymer on the rate of viscoelastic relaxation. The rate of viscoelastic relaxation depends upon the fraction of unoccupied lattice sites (i.e., holes) in the Simha‐Somcynsky statistical thermodynamic equation of state, and the hole fraction is a known function of the temperature, pressure, and specific volume. The nonlinear viscoelastic yield and postyield behavior are a direct consequence of the deformation‐induced dilation. All material constants contained in the constitutive equation can be determined from independent elastic, linear viscoelastic, and pressure‐volume‐temperature measurements—there are no adjustable constants. The constitutive equation has been solved for model viscoelastic materials in uniaxial extension and shear deformations where the applied strain rate is constant. It is shown that an experimentally realizable “shear” deformation is only isochoric in the linear viscoelastic limit. Yield and postyield softening are predicted in both uniaxial extension and experimental shear, and the predicted yield stress exhibits the appropriate strain rate and temperature dependence. The effects of using various finite strains measures in the nonlinear viscoelastic constitutive equation are analyzed.

For the class of all discrete two-velocity models of the nonlinear Boltzmann equation consistent with theH-theorem an exact representation of the corresponding nonlinear constitutive equation will be derived. Applying the fractional calculus we derive, in addition, the nonlinear fractional Boltzmann equation as the starting point for the formulation of a nonlinear fractional constitutive equation which relates the densities and fluxes through an integro-differential equation. Linearization leads to the fractional version of Cattaneo's constitutive law. The model presented here may be regarded as a first step, towards the formulation of a fractional extended irreversible thermodynamics.

The penetration of long gas bubble through a viscoelastic fluid in a capillary tube has been studied in order to investigate the influence of viscoelastic material properties on the hydrodynamic coating thickness and local flow kinematics. Experiments are conducted for three tailored ideal elastic (Boger) fluids, designed to exhibit similar steady shear properties but substantially different elastic material functions. This allows for the isolation of elastic and extensional material effects on the bubble penetration process. The shear and extensional rheology of the fluid is characterized using rotational and filament stretching rheometers (FSR). The fluids are designed such that the steady-state extensional viscosity measured by the FSR at a Deborah number (De) greater than 1 differs over three orders of magnitude (Trouton ratio = 103–106). The experiment set up to measure the hydrodynamic coating thickness is designed to provide accurate data over a wide range of capillary numbers (0.01 < Ca < 100). The results indicate that the coating thickness in this process increases with an increase in the extensionally thickening nature of the fluid. Experiments are also conducted using several different capillary tube diameters (0.1 < D < 1 cm), in order to compare responses at similar Ca but different flow De. Suitable scaling methods and nonlinear viscoelastic constitutive equations are explored to characterize the displacement process for polymeric fluids. Bubble tip shapes at different De are recorded using a CCD camera, and measured using an edge detection algorithm. The influence of the mixed flow field on the bubble tip shape is examined. Particle tracking velocimetry experiments are conducted to compare the influence of viscoelastic properties on the velocity field in the vicinity of the bubble tip. Local shear and extension rates are calculated in the vicinity of the bubble tip from the velocity data. The results provide quantitative information on the influence of elastic and extensional properties on the bubble penetration process in gas-assisted injection molding. The bubble shape and velocity field information provides a basis for evaluating the performance of constitutive equations in mixed flow.

Considering the influence of temperature and strain variables on materials. According to the relationship of conjugate stress-strain, a complete and irreducible non-linear constitutive equation of isotropic hyperelastic materials is derived and the constitutive equations of 16 types of isotropic hyperelastic materials are given we study the transformation methods and routes of 16 kinds of constitutive equations and the study proves that transformation of two forms of constitutive equation. As an example of application, the non-linear thermo-elastic constitutive equation of isotropic hyperelastic materials is combined with the natural vulcanized rubber experimental data in the existing literature base on MATLAB, The results show that the fitting accuracy is satisfactory.

Numerical simulation is one of the effective tools for the long-term stability assessment of underground structures. The reliability improvement of the numerical simulation requires precise constitutive equations to reproduce time-dependent behavior of rock such as loading-rate dependence, creep, and relaxation. These time-dependent behaviors of rock have nonlinearity between stress and strain rate and are influenced by surrounding environment. A number of constitutive equations have been proposed in previous studies; however, the equations based on the theory of linear viscoelasticity have difficulty reproducing accurately the time-dependent behavior of rock, and most of the equations based on the theory of viscoplasticity have been applied to the limited loading condition such as creep. In this article, nonlinear viscoelastic constitutive equations for rock proposed by the authors were introduced, and their exact solutions and application to experimental results were summarized. These equations can reproduce nonlinear time-dependent behavior and not only brittle but also ductile failures of rock and can be applied to the behavior under various loading conditions and experiment environment. In the equations, compliance or inelastic strain is assumed to be increased with time, but the functions and their combinations are of great variety. Hence, the differences of the solutions and applicability of the equations were detailed, and in addition future subjects were presented.

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This paper investigates the dependence of the subharmonic response in a signal scattered by contrast agent microbubbles on ambient pressure to provide quantitative estimations of local blood pressure. The problem is formulated by assuming a gas bubble encapsulated by a shell of finite thickness with dynamic behavior modeled by a nonlinear viscoelastic constitutive equation. For ambient overpressure compatible with the clinical range, the acoustic pressure intervals where the subharmonic signal may be detected (above the threshold for the onset and below the limit value for the first chaotic transition) are determined. The analysis shows that as the overpressure is increased, all harmonic components are displaced to higher frequencies. This displacement is significant for the subharmonic of order 1/2 and explains the increase or decrease in the subharmonic amplitude with ambient pressure described in previous works. Thus, some questions related to the monotonic dependence of the subharmonic amplitude on ambient pressure are clarified. For different acoustic pressures, quantitative conditions for determining the intervals where the subharmonic amplitude is a monotonic or non-monotonic function of the ambient pressure are provided. Finally, the influence of the ambient pressure on the subharmonic resonance frequency is analyzed.

ABSTRACTWithout knowing the dynamic constitutive relation of materials under high strain rates, no wave propagation can be correctly analyzed. A Series of experimental and theoretical investigation at high strain rates revealed that the nonlinear viscoelastic behavior of polymers and the related composites are well described by the Zhu-Wang-Tang (ZWT) nonlinear viscoelastic constitutive equation. The impulsive reponse of ZWT materials consists of a rate independent nonlinear elastic response and a high frequency linear viscoelastic response. The dispersion and attenuation of nonlinear viscoelastic waves mainly depend on the effective nonlinearity and the high frequency relaxation time θ2. An “effective influence distance” or “effective influence time” is defined to characterize the wave propagation range where θ2 dominates the impact relaxation process.

Methods of quasi-static deformation and fracture analysis are developed for a class of nonlinear viscoelastic media and sample applications are given. Selection of the class of media is guided by actual rheological behavior of monolithic and composite materials as well as the need for simplicity to be able to understand the effect of primary material and continuum parameters on crack growth behavior. First, pertinent aspects of J integral and energy release rate theory for nonlinear elastic media are discussed. Nonlinear viscoelastic constitutive equations are then given, and correspondence principles which establish a simple relationship between mechanical states of elastic and viscoelastic media are developed. These principles provide the basis for the subsequent extension of J integral theory to crack growth in viscoelastic materials. Emphasis is on predicting mechanical work available at the crack tip for initiation and continuation of growth; some examples show how viscoelastic properties and the J integral affect growth behavior. Included is the problem of a crack in a thin layer having different viscoelastic properties than the surrounding continuum. The Appendix gives an apparently new constitutive theory for elastic and viscoelastic materials with changing microstructure (e.g. distributed damage) and indicates the conditions under which the fracture theory in the body of the paper is applicable.

A comparison of second-order constitutive theories for hyperelastic materials

A bimodular nonlinear constitutive equation for rock

A simplified three‐dimensional viscoelastic equation, based on the Green–Rivlin theory, was used to characterize the nonlinear creep behavior of two food products, i.e., apple and potato. Uniaxial and triaxial creep tests were conducted to evaluate the nonlinear behavior of apple and potato flesh. Four material property functions in the nonlinear constitutive equation were determined using experimental results. The nonlinear constitutive equation was then used to predict the load response of both apple and potato flesh under various loading conditions. The nonlinear constitutive model calculated values compared favorably with the experimental data. Results show that the nonlinearity of apple flesh under the uniaxial creep loading was significant especially for extended loading time periods. The initial load response has a pronounced effect on the nonlinearity of potato flesh under the uniaxial creep loading.

In the analysis of weak solutions relevant to evolutionary flows of incompressible fluids with non-constant viscosity or with non-linear constitutive equation, it is in general an open question whether a globally integrable pressure exists if the flows are subject to no-slip boundary conditions. Here we overcome this deficiency by considering threshold boundary conditions stating that the fluid adheres to the boundary until certain critical value for the wall shear stress is reached. Once the wall shear stress exceeds this critical value, the fluid slips. The main ingredient in our approach is to look at this type of activated, stick-slip, boundary condition as an implicit constitutive equation on the boundary.

Numerical solution of the PTT constitutive equation for unsteady three-dimensional free surface flows

In a system of identical nonlinear dielectric inclusions immersed in a uniform linear dielectric medium the mean polarization on a macroscopic length scale is related to the Maxwell field by a nonlocal and nonlinear constitutive equation. The method of statistical averaging and cluster expansion is used to derive a formally exact expression for the constitutive equation. The resulting cluster integrals are shown to be absolutely convergent, i.e., independent of the shape of the macroscopic sample in the thermodynamic limit. For a suspension of spherical inclusions a selection of terms leads to a nonlinear Clausius-Mossotti relation. Expressions are derived for the correlation corrections to this mean-field result.