To facilitate the management of detonators, an automatic spotting system is proposed for detonator coded characters based on convolutional neural networks. The system contains a multi-scale detection network, a multi-label recognition network and a post-processing layer. An improved fully convolution network (FCN) is designed as the multi-scale detection network to obtain the accurate response map of the detonator image. Two subnetworks are parallel integrated into the FCN to perform a coarse-to-fine detection. An improved Jaccard loss function with a regularization term is defined to train the FCN. The region of interest (ROI) of the detonator image is achieved when the response map is post-processed by the post-processing layer. Finally, a modified multi-label network is used to recognize the detonator coded characters in the ROI. The experimental results indicate that the proposed system achieves a better spotting performance for detonator coded characters than the state-of-the-art text spotting methods in terms of accuracy and efficiency.