Fuel design real-time to control HCCI combustion

Homogeneous Charge Compression Ignition (HCCI) combustion in a small-scale engine (25 cc) was experimentally examined. Historically, HCCI combustion has been studied in engines sized for passenger vehicles and trucks (approximately 500 cc and larger). HCCI combustion in large-scale engines is characterized by higher efficiency than SI and CI combustion. High rates of heat flux, due to large surface area to volume ratio and engine body material, initially prevented the small-scale engine from operating in HCCI mode. The high level of heat transfer was overcome and sustained small-scale HCCI operation was achieved with n-heptane fuel. Large-scale HCCI engines utilize ultralow equivalence ratios to achieve high efficiencies. The small-scale HCCI engine could not operate with equivalence ratios lower than 0.73. Performance characteristics including power, efficiency, and NOx emissions of the small-scale HCCI engine were poorer than when operated in SI mode. Recommendations to overcome high rates of heat flux and increase small-scale HCCI engine efficiency are presented.

<div class="section abstract"><div class="htmlview paragraph">The Homogeneous Charge Compression Ignition (HCCI) combustion eliminates the issues of higher particulate matter and nitrogen oxides emissions that prevail in the traditional compression ignition (CI) combustion mode. The complete replacement of traditional fuels with renewable fuels for internal combustion engines is challenging because significant infrastructure changes in the production and delivery systems are required to ensure renewable fuel availability and economic feasibility. Thus, the use of renewable acetone blended with traditional gasoline has been proposed in the present study to smoothen the transition from the traditional CI to the HCCI engines. HCCI experiments were performed in a light-duty diesel engine at 1500 rpm rated speed. By varying the volumetric proportion of the acetone in the gasoline from 20% to 40%, the HCCI engine load range from 20%-60% was achieved, significantly higher than the limited diesel HCCI load range of 20%-38%. An ignition-quality enhancer, 2-Ethylhexyl nitrate, at 6 vol.%, was blended in the acetone-gasoline to prevent the higher cyclic IMEP fluctuations at the lower engine loads. The empirical correlation of the start of combustion (CA10) established on a rapid compression machine facility was validated for the HCCI engine. The combustion phasing (CA50) was predicted using CA10 and fresh air equivalence ratio. A double-Weibe function was developed to characterize specifically the high-temperature heat release rate during the HCCI combustion and determine the extent of its fast-burning core region. An in-depth energy balance study was conducted to elucidate the reason for the indicated thermal efficiency trends. The acetone-gasoline-fuelled HCCI engine generated smoke and nitrogen oxides emissions that were less than 0.0007 g/kW-h and 2.5 g/kW-h, respectively, at all the engine loads. This study concluded that lower exhaust emissions could be obtained without compromising engine performance when the acetone-gasoline blends are used as fuels for operating the HCCI engine.</div></div>

Homogenous charge compression ignition (HCCI) combustion in diesel engines can provide for cleaner operation with ultra-low NOx and soot emissions. While HCCI combustion has generated significant attention in the last decade, however, to date, it has seen very limited application in production diesel engines. HCCI combustion is typically characterized by earlier than top-dead-center (pre-TDC) phasing, very high pressure rise rates, short combustion durations and minimal control over the timing of the combustion event. To offset the high reactivity of the diesel fuel, large amounts of EGR (30 to 60%) are usually applied to postpone the initiation of combustion, shift the combustion towards TDC and alleviate to some extent, the high pressure rise rates and the reduced energy efficiency. In this work, a detailed analysis of HCCI combustion has been carried out on a high-compression ratio, single-cylinder diesel engine. The effects of intake boost, EGR quantity/temperature, engine speed, injection scheduling and injection pressure on the operability limits have been empirically determined and correlated with the combustion stability, emissions and performance metrics. The empirical investigation is extended to assess the suitability of common alternate fuels (n-butanol, gasoline and ethanol) for HCCI combustion. On the basis of the analysis, the significant challenges affecting the real-world application of HCCI are identified, their effects on the engine performance quantified and possible solutions to overcome these challenges explored through both theoretical and empirical investigations. This paper intends to provide a comprehensive summary of the implementation issues affecting HCCI combustion in diesel engines.

An ion current probe using a spark plug was applied to gasoline-fuelled homogeneous charge compression ignition (HCCI) combustion with hot residual gas in order to verify the possibility of using it as a combustion sensor. The ion current signal for single-cycle HCCI combustion had a simple profile and effectively one maximum value. There is a possibility that a similar ion current signal corresponding to the completed reaction can be obtained, depending on the location of the probe during HCCI combustion. The ionization reaction for HCCI combustion is affected by the chemical ionization reaction with heat release, and there is a possibility that the ion current can be used to detect heat release corresponding to the chemical ionization reaction. A strong correlation between the timing of the integrated ion current and the timing of the mass fraction burned is observed. The timing of the mass fraction burned is assumed from the timing of the integrated ion current, and the mass fraction burned (up to 70 per cent) can be determined, even if the engine driving condition changes within the scope of the test. There is a correlation between the timing of the maximum ion-current and the maximum rate of heat release, and there is a possibility that the maximum value of the rate of heat release can be inferred by detecting the timing of the maximum ion current. There is a correlation between the timing of the maximum ion current and the timing of the maximum pressure at each cycle. Therefore, it may be possible to monitor the variation of the HCCI combustion phasing.

Homogeneous charge compression ignition (HCCI) engines have low nitrogen oxide and particulate matter engine-out emissions but have higher unburned hydrocarbon and carbon monoxide emissions than the conventional spark ignition (SI) and diesel engines do. Only for sufficiently high exhaust gas temperatures can an exhaust after-treatment be used; thus a low exhaust gas temperature in certain operating conditions can limit the operating range in HCCI engines. The influences of the engine conditions on the exhaust gas temperature in a single-cylinder experimental engine are investigated at 340 steady state operating points. The variation in the exhaust gas temperature is also studied under transient conditions and during mode switching between SI and HCCI combustion. For the conditions tested, a significant number of data have an exhaust gas temperature below 300°C which is below the light-off temperature of typical catalytic converters on the market. Three different categories of engine variables are recognized and classified by how the exhaust temperature is affected by changing that variable. The first category is defined as the primary variables (e.g. the intake pressure and the fuel octane number) for which the location of ignition timing is the dominant factor in influencing the exhaust temperature. The other groups include compounding variables such as the engine speed and opposing variables such as the intake temperature, the coolant temperature, and the equivalence ratio. In addition, experimental results show that the exhaust temperature for HCCI engines is not strongly dependent on the engine load, unlike that for SI engines where the engine load is a main factor in determining the exhaust temperature.

<div class="htmlview paragraph">The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges.</div> <div class="htmlview paragraph">Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies.</div> <div class="htmlview paragraph">The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission. The objectives are to develop advanced new catalyst formulation for efficient CO/HC conversion at low temperature, possibly coupled with new emerging technologies based on non-thermal plasma concept and adapted to the specific HCCI exhaust emissions.</div> <div class="htmlview paragraph">This paper presents one of the first steps of the study: the definition of the oxidation catalyst boundary conditions under HCCI combustion. For this, we perform a detailed characterisation of the CO and HC emissions on a NADI™ dual mode engine (HCCI at low load and switch to conventional combustion at high load), based on a 2.2-liter, 4-cylinder for passenger car.</div> <div class="htmlview paragraph">The regulated pollutant emissions (CO, THC) have been measured with standard gas analyzer devices. Moreover, hydrocarbon speciation has been done with a C1-C9 gas chromatograph (GC) coupled with a FID system. In addition, aldehydes and ketones emissions have been analyzed by means of a High Pressure Liquid Chromatograph (HPLC).</div> <div class="htmlview paragraph">The results show that HCCI combustion tends to form higher methane emissions than conventional combustion. Moreover, high EGR rates lead to higher oxygenated emissions, in particular formaldehyde. If aldehydes are easily converted when the catalyst is warm, methane is not oxidized at these temperatures.</div> <div class="htmlview paragraph">The next steps of the program will be the definition, the fabrication and the tests of an HCCI-dedicated efficient oxidation catalyst to comply with CO and HC emissions standards. Non-thermal plasma reactor will be also mounted in the exhaust line to help the oxidation reaction.</div>

This is the final report of the High Efficiency Clean Combustion (HECC) Research Program for the U.S. Department of Energy. Work under this co-funded program began in August 2005 and finished in July 2010. The objective of this program was to develop and demonstrate a low emission, high thermal efficiency engine system that met 2010 EPA heavy-duty on-highway truck emissions requirements (0.2g/bhp-hr NOx, 0.14g/bhp-hr HC and 0.01g/bhp-hr PM) with a thermal efficiency of 46%. To achieve this goal, development of diesel homogenous charge compression ignition (HCCI) combustion was the chosen approach. This report summarizes the development of diesel HCCI combustion and associated enabling technologies that occurred during the HECC program between August 2005 and July 2010. This program showed that although diesel HCCI with conventional US diesel fuel was not a feasible means to achieve the program objectives, the HCCI load range could be increased with a higher volatility, lower cetane number fuel, such as gasoline, if the combustion rate could be moderated to avoid excessive cylinder pressure rise rates. Given the potential efficiency and emissions benefits, continued research of combustion with low cetane number fuels and the effects of fuel distillation are recommended. The operation of diesel HCCI was only feasible at part-load due to a limited fuel injection window. A 4% fuel consumption benefit versus conventional, low-temperature combustion was realized over the achievable operating range. Several enabling technologies were developed under this program that also benefited non-HCCI combustion. The development of a 300MPa fuel injector enabled the development of extended lifted flame combustion. A design methodology for minimizing the heat transfer to jacket water, known as precision cooling, will benefit conventional combustion engines, as well as HCCI engines. An advanced combustion control system based on cylinder pressure measurements was developed. A Well-to-wheels analysis of the energy flows in a mobile vehicle system and a 2nd Law thermodynamic analysis of the engine system were also completed under this program.

Detection of low Temperature heat release (LTHR) in the standard Cooperative Fuel Research (CFR) engine in both SI and HCCI combustion modes

The main aim of this study is to investigate theoretically the formation of nitric oxide (NO) in a homogeneous charge compression ignition (HCCI) engine fueled with blends of ethanol and synthetic gasoline (RON25, RON50, RON75). A detailed kinetic mechanism involving 1086 chemical species and 4754 elementary reactions taking place in a HCCI engine modeled as an adiabatic single-zone reactor was applied to simulate the emission of the investigated pollutant. A close agreement between experimental and calculated results of ignition delay, species concentrations in ideal reactors, and laminar flame velocities of pure ethanol, n-heptane and iso-octane confirmed the reliability of the kinetic model. An analogous comparison, but considering a set of data (NO formation, temperature, and pressure) obtained in a single-cylinder HCCI engine operated with different mixtures of primary reference fuels (n-heptane and iso-octane) over the equivalence ratio range from approximately 0.15 to 0.4, revealed the consistency of the adiabatic single-zone model. Despite the low to moderate content of NO typically observed in the exhausts from HCCI engines, a further decrease of this pollutant was still revealed at all the considered simulating conditions when the percentage of ethanol in the fuel (synthetic gasoline) was increased. However, the extent of NO reduction was more evident for blends involving up to approximately 20% of ethanol (<E20) and synthetic gasolines with low octane number (<RON50). From a practical point-of-view, this finding reveals that the injection of a small volume of ethanol to gasoline (<20%) could be an alternative procedure to reduce the rates of exhaust gas recirculation applied to control the HCCI operation, making it a promising strategy to have a conciliation between low NO and moderate UHC and CO emissions in gasoline HCCI.

An improved phenomenological soot model coupled with a reduced n-heptane chemical mechanism was implemented into KIVA-3V code to describe soot formation and oxidation processes in diesel homogeneous charge compression ignition (HCCI) combustion. This model was first validated by the shock tube experiments with a rich n-heptane mixture over wide temperature and pressure ranges. The computational results demonstrate that the phenomenological soot model is capable of predicting the soot yield, particle diameter, and number density with satisfactory accuracy. Then the model was applied to investigate the influence of the orifice diameter and injection pressure on soot emissions in a constant-volume combustion vessel under typical diesel combustion conditions. The predictions showed qualitative agreement with the measurements on the soot volume fraction distribution. The results also indicate that the soot formation can almost be suppressed as the local equivalence ratio is kept lower than 2.0. Finally, the model was used to explore the potentials of soot reduction with HCCI combustion for diesel engines. The overall trend of soot with the variations in the start of injection timing was well reproduced by the model. With the help of an equivalence ratio—temperature map, it was found that nitrogen oxide emissions could be markedly reduced by applying a high exhaust gas recirculation rate and relative low compression ratio for diesel HCCI engines. However, the mixture preparation by using a multi-hole injector with early injection strategy remains a limitation for further reduction in soot emissions.

In homogeneous charge compression ignition engines, the ignition takes place in the absence of any external source, initiated by the autoignition of the well-mixed in-cylinder charge. The heat loss from the hot combustion gases to the surroundings causes the thermal conditions in the cylinder to deteriorate. These conditions are governed by the interaction of the chemical processes with the temperature and pressure changes in the cylinder. As a result, the heat release rate and the heat transfer inside the combustion chamber play significant roles in the homogeneous charge compression ignition combustion mode. The use of detailed chemical kinetics mechanisms in predictive combustion models increases the simulation time, which makes the utilization of these mechanisms questionable. As a result, reduced mechanisms of smaller sizes are required. However, in developing a reduced chemical kinetics mechanism from the detailed chemical kinetics mechanism, it is not common to consider the role of heat transfer, and this is needed to focus on only the kinetics aspects of homogeneous charge compression ignition. The objective of this work is to investigate the effect of heat transfer (through the boundaries of the combustion chamber) on the development of the reduced mechanisms from the detailed mechanisms. A single-zone combustion model is used to simulate the homogeneous charge compression ignition engine. Insignificant species and reactions of the detailed GRI-Mech 3.0 mechanism are eliminated by employing a two-stage reduction process based on a directed relation graph with error propagation and principal-component analysis methods respectively. Several different operating conditions are considered. The results demonstrate that the reduction process based on the directed relation graph with error propagation is hardly affected by considering the heat transfer. However, taking into account the heat transfer slightly influences the reduction process based on the principal-component analysis. Simulation outcomes from the generated mechanisms under adiabatic conditions and non-adiabatic conditions agree closely with the results obtained from the detailed mechanism. The differences in the crank angle when 50% of heat is released, the peak pressure and the maximum heat release between the original mechanisms and the reduced mechanisms are less than 1° crank angle, 1% and 1% respectively. Therefore, for a chemical mechanism reduction strategy, considering the heat transfer component will lead to only a minor effect on the generated reduced mechanism.

The Homogeneous Charge Compression Ignition (HCCI) combustion has potential to radically reduce emissions, especially NOx, but is inherently difficult to achieve and control, especially when natural gas is used as fuel. Hydrogen addition, particularly from fuel reforming was successfully used as an aid. Methane reforming with exhaust gas and air in a monolith catalytic reactor is presented here as a source of hydrogen. An open-loop fuel exhaust gas reforming system has been developed and tested; experimental results are compared with two different models of basic thermodynamic equilibria calculations. The experimental results have shown that for low temperature of engine exhaust gas, typical for HCCI conditions, additional air is needed to produce the quantities of H2 required to enhance the feasibility and range of HCCI combustion. At the low reactor inlet temperatures needed for the HCCI application the simplified three-reaction thermodynamic model is in broad agreement with experimental results, while the high hydrogen yields predicted from the multi-component equilibrium model for medium temperature reforming are difficult to achieve in a practical reformer.

Homogenous charge compression ignition (HCCI) combustion is a low temperature combustion process which combines high combustion efficiency with ultra-low [Formula: see text] raw emissions. Steep increases of the in-cylinder pressure and unstable combustion sequences at the limits of the operating range can damage the engine and limit the use of HCCI to part load operation. This can be done using closed loop combustion control based on combustion parameters like the indicated mean effective pressure and the combustion phasing. Since in-cylinder pressure sensors are expensive components and therefore not suitable for series application, ion current sensors can be used as an additional source of information about the combustion. Combustion analysis using methods similar to those used in pressure based measurements can be implemented using an online analysis of the ion current signal. In this study, the ion current sensor will be examined for its suitability for combustion control under HCCI conditions with lean air/fuel ratios and high compression ratios. Research has found that the ion current signal is strongly depended on the boundary conditions. Especially the air/fuel ratio which plays an important role for signal strength during the combustion process. When using valve timings with negative valve overlap in combination with a fuel pre-injection, a further peak of the ion current signal close to the gas exchange top dead center can be found in addition to the one during combustion. At the same time, it is hard to extract information from the cylinder pressure signal during NVO. Under lean conditions this peak even exceeds the signal during combustion. This study analyzes the ion current signal during NVO and its potential to be used for future combustion control concepts. The ion current signal shows potential to stabilize HCCI combustion at high loads. However, the prediction of late combustion cycles is still challenging.

Homogeneous charge compression ignition (HCCI) combustion, when applied to a gasoline engine, offers the potential for a noticeable improvement in fuel economy and dramatic reductions in NOx emissions. In this study, Computational Fluid Dynamic (CFD) is used coupled with detailed chemical mechanism (38 species and 69 reactions) for simulation of HCCI combustion of iso-octane and transitional flow inside the combustion chamber of a 2-stroke engine. Results show that increasing the overall gas temperature significantly advances the HCCI combustion timing. Concerning the equivalence ratio, by increasing it the ignition timing has been advanced and the maximum cylinder pressure has been increased. When equivalence ratio increases to more than 0.5 , NOx emissions significantly increases and go beyond 1000 [ppm].

&lt;div class="htmlview paragraph"&gt;To limit pollutants from transport and to reach a low level of exhaust emission, Low Temperature Combustion (LTC) modes such as Homogeneous Charge Compression Ignition (HCCI) are being studied. HCCI process is based on the auto-ignition of a highly diluted air/fuel mixture. It allows very low level of NO&lt;sub&gt;x&lt;/sub&gt; and particulate emissions. But several problems must be solved: firstly the limited combustion range, the difficulty to control the combustion process, the noise but also the high HC and CO emissions. Two ways appear as very promising to improve HCCI combustion: engine technology and fuel formulation.&lt;/div&gt; &lt;div class="htmlview paragraph"&gt;In this work, attention is paid on initiation and HCCI combustion control through fuel formulation. This article shows the effect of acetal addition (and in particular butylal addition) in a Diesel base fuel.&lt;/div&gt; &lt;div class="htmlview paragraph"&gt;It seems to be difficult to have only an “HCCI engine” because the operation zone of the engine is too small. More likely, it will be a Diesel/HCCI engine. The advantage of acetal is to reduce significantly particulate emissions of a Diesel engine. This is an advantage for a Diesel/HCCI engine, when the engine works in Diesel combustion but it is necessary to get a better understanding of the influence of acetal addition in a Diesel base fuel during the HCCI combustion.&lt;/div&gt; &lt;div class="htmlview paragraph"&gt;Butylal can have a good potential to improve the HCCI combustion by delaying the initiation of a Diesel base fuel but due to its versatile aspect, it is difficult to control, for all the experimental conditions, its effect on the initiation and the HCCI combustion of a Diesel base fuel.&lt;/div&gt;