Implementation Challenges and Solutions for Homogenous Charge Compression Ignition Combustion in Diesel Engines

Homogeneous Charge Compression Ignition (HCCI) combustion in a small-scale engine (25 cc) was experimentally examined. Historically, HCCI combustion has been studied in engines sized for passenger vehicles and trucks (approximately 500 cc and larger). HCCI combustion in large-scale engines is characterized by higher efficiency than SI and CI combustion. High rates of heat flux, due to large surface area to volume ratio and engine body material, initially prevented the small-scale engine from operating in HCCI mode. The high level of heat transfer was overcome and sustained small-scale HCCI operation was achieved with n-heptane fuel. Large-scale HCCI engines utilize ultralow equivalence ratios to achieve high efficiencies. The small-scale HCCI engine could not operate with equivalence ratios lower than 0.73. Performance characteristics including power, efficiency, and NOx emissions of the small-scale HCCI engine were poorer than when operated in SI mode. Recommendations to overcome high rates of heat flux and increase small-scale HCCI engine efficiency are presented.

<div class="htmlview paragraph">The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges.</div> <div class="htmlview paragraph">Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies.</div> <div class="htmlview paragraph">The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission. The objectives are to develop advanced new catalyst formulation for efficient CO/HC conversion at low temperature, possibly coupled with new emerging technologies based on non-thermal plasma concept and adapted to the specific HCCI exhaust emissions.</div> <div class="htmlview paragraph">This paper presents one of the first steps of the study: the definition of the oxidation catalyst boundary conditions under HCCI combustion. For this, we perform a detailed characterisation of the CO and HC emissions on a NADI™ dual mode engine (HCCI at low load and switch to conventional combustion at high load), based on a 2.2-liter, 4-cylinder for passenger car.</div> <div class="htmlview paragraph">The regulated pollutant emissions (CO, THC) have been measured with standard gas analyzer devices. Moreover, hydrocarbon speciation has been done with a C1-C9 gas chromatograph (GC) coupled with a FID system. In addition, aldehydes and ketones emissions have been analyzed by means of a High Pressure Liquid Chromatograph (HPLC).</div> <div class="htmlview paragraph">The results show that HCCI combustion tends to form higher methane emissions than conventional combustion. Moreover, high EGR rates lead to higher oxygenated emissions, in particular formaldehyde. If aldehydes are easily converted when the catalyst is warm, methane is not oxidized at these temperatures.</div> <div class="htmlview paragraph">The next steps of the program will be the definition, the fabrication and the tests of an HCCI-dedicated efficient oxidation catalyst to comply with CO and HC emissions standards. Non-thermal plasma reactor will be also mounted in the exhaust line to help the oxidation reaction.</div>

An improved phenomenological soot model coupled with a reduced n-heptane chemical mechanism was implemented into KIVA-3V code to describe soot formation and oxidation processes in diesel homogeneous charge compression ignition (HCCI) combustion. This model was first validated by the shock tube experiments with a rich n-heptane mixture over wide temperature and pressure ranges. The computational results demonstrate that the phenomenological soot model is capable of predicting the soot yield, particle diameter, and number density with satisfactory accuracy. Then the model was applied to investigate the influence of the orifice diameter and injection pressure on soot emissions in a constant-volume combustion vessel under typical diesel combustion conditions. The predictions showed qualitative agreement with the measurements on the soot volume fraction distribution. The results also indicate that the soot formation can almost be suppressed as the local equivalence ratio is kept lower than 2.0. Finally, the model was used to explore the potentials of soot reduction with HCCI combustion for diesel engines. The overall trend of soot with the variations in the start of injection timing was well reproduced by the model. With the help of an equivalence ratio—temperature map, it was found that nitrogen oxide emissions could be markedly reduced by applying a high exhaust gas recirculation rate and relative low compression ratio for diesel HCCI engines. However, the mixture preparation by using a multi-hole injector with early injection strategy remains a limitation for further reduction in soot emissions.

<div class="section abstract"><div class="htmlview paragraph">The Homogeneous Charge Compression Ignition (HCCI) combustion eliminates the issues of higher particulate matter and nitrogen oxides emissions that prevail in the traditional compression ignition (CI) combustion mode. The complete replacement of traditional fuels with renewable fuels for internal combustion engines is challenging because significant infrastructure changes in the production and delivery systems are required to ensure renewable fuel availability and economic feasibility. Thus, the use of renewable acetone blended with traditional gasoline has been proposed in the present study to smoothen the transition from the traditional CI to the HCCI engines. HCCI experiments were performed in a light-duty diesel engine at 1500 rpm rated speed. By varying the volumetric proportion of the acetone in the gasoline from 20% to 40%, the HCCI engine load range from 20%-60% was achieved, significantly higher than the limited diesel HCCI load range of 20%-38%. An ignition-quality enhancer, 2-Ethylhexyl nitrate, at 6 vol.%, was blended in the acetone-gasoline to prevent the higher cyclic IMEP fluctuations at the lower engine loads. The empirical correlation of the start of combustion (CA10) established on a rapid compression machine facility was validated for the HCCI engine. The combustion phasing (CA50) was predicted using CA10 and fresh air equivalence ratio. A double-Weibe function was developed to characterize specifically the high-temperature heat release rate during the HCCI combustion and determine the extent of its fast-burning core region. An in-depth energy balance study was conducted to elucidate the reason for the indicated thermal efficiency trends. The acetone-gasoline-fuelled HCCI engine generated smoke and nitrogen oxides emissions that were less than 0.0007 g/kW-h and 2.5 g/kW-h, respectively, at all the engine loads. This study concluded that lower exhaust emissions could be obtained without compromising engine performance when the acetone-gasoline blends are used as fuels for operating the HCCI engine.</div></div>

Detection of low Temperature heat release (LTHR) in the standard Cooperative Fuel Research (CFR) engine in both SI and HCCI combustion modes

<div class="section abstract"><div class="htmlview paragraph">The purpose of this paper is to find a way to extend the high load limit of homogeneous charge compression ignition (HCCI) combustion. This paper presents the effect of in-cylinder flow and stratified mixture on HCCI combustion by experiments and three-dimensional computer fluid dynamics coupled with a detailed chemical reaction calculation. The first study was conducted using a rapid compression and expansion machine (RCEM) equipped with a flow generation plate to create in-cylinder turbulent flow and with a control unit of in-cylinder wall temperature to create in-cylinder temperature distribution. The study assesses the effect of the turbulent flow and the temperature distribution on HCCI combustion. In the second study, the numerical simulation of HCCI combustion was conducted using large eddy simulation coupled with a detailed chemical reaction calculation. The study analyzes the interaction between in-cylinder turbulent flow and mixture distribution and HCCI combustion. The result shows that turbulent flow effects a change in the distribution of chemical species which is a trigger of combustion initiation.</div></div>

An ion current probe using a spark plug was applied to gasoline-fuelled homogeneous charge compression ignition (HCCI) combustion with hot residual gas in order to verify the possibility of using it as a combustion sensor. The ion current signal for single-cycle HCCI combustion had a simple profile and effectively one maximum value. There is a possibility that a similar ion current signal corresponding to the completed reaction can be obtained, depending on the location of the probe during HCCI combustion. The ionization reaction for HCCI combustion is affected by the chemical ionization reaction with heat release, and there is a possibility that the ion current can be used to detect heat release corresponding to the chemical ionization reaction. A strong correlation between the timing of the integrated ion current and the timing of the mass fraction burned is observed. The timing of the mass fraction burned is assumed from the timing of the integrated ion current, and the mass fraction burned (up to 70 per cent) can be determined, even if the engine driving condition changes within the scope of the test. There is a correlation between the timing of the maximum ion-current and the maximum rate of heat release, and there is a possibility that the maximum value of the rate of heat release can be inferred by detecting the timing of the maximum ion current. There is a correlation between the timing of the maximum ion current and the timing of the maximum pressure at each cycle. Therefore, it may be possible to monitor the variation of the HCCI combustion phasing.

The Homogeneous Charge Compression Ignition (HCCI) combustion has potential to radically reduce emissions, especially NOx, but is inherently difficult to achieve and control, especially when natural gas is used as fuel. Hydrogen addition, particularly from fuel reforming was successfully used as an aid. Methane reforming with exhaust gas and air in a monolith catalytic reactor is presented here as a source of hydrogen. An open-loop fuel exhaust gas reforming system has been developed and tested; experimental results are compared with two different models of basic thermodynamic equilibria calculations. The experimental results have shown that for low temperature of engine exhaust gas, typical for HCCI conditions, additional air is needed to produce the quantities of H2 required to enhance the feasibility and range of HCCI combustion. At the low reactor inlet temperatures needed for the HCCI application the simplified three-reaction thermodynamic model is in broad agreement with experimental results, while the high hydrogen yields predicted from the multi-component equilibrium model for medium temperature reforming are difficult to achieve in a practical reformer.

Effect of a narrow fuel spray angle and a dual injection configuration on the improvement of exhaust emissions in a HCCI diesel engine

For researching the influence of n-butanol proportion in diesel fuel on homogeneous charge compression ignition (HCCI) combustion of the free-piston diesel engine generator (FPDEG), a three-dimensional (3D) moving mesh computational fluid dynamics (CFD) simulation model of a FPDEG prototype was developed. A detailed chemical reaction mechanism of diesel fuel was selected as the HCCI combustion mechanism and coupled in the established HCCI combustion simulation model of the FPDEG prototype. The validity of the established HCCI combustion simulation model is proved by comparing the simulation and experimental pressure curves under the condition of pure diesel fuel. The simulation results of different n-butanol proportions in diesel fuel showed that as the n-butanol proportion increased from 0 to 60%, the maximum heat release rate decreased to 59.6 J/deg, the calculated indicated thermal efficiency augmented to 4.6%, the calculated indicated mean effective pressure increased to 0.057 MPa, and the final NOx and CO content decreased to 0.239 and 0.57 g/kg fuel, respectively, but the final soot content increased to 0.000562 g/kg fuel. Therefore, the n-butanol proportion of diesel fuel played a vital role in combustion and emission progress of the FPDEG.

A study on the reduction of exhaust emissions through HCCI combustion by using a narrow spray angle and advanced injection timing in a DME engine

This paper presents some experimental operating and combustion properties of homogeneous charge compression ignition (HCCI) combustion. HCCI operating range, start of combustion, burn duration, indicated mean effective pressure, indicated specific emissions, and indicated specific fuel consumption are evaluated as charge dilution and octane number are varied. Primary reference fuels with octane numbers of 20, 40, and 60 are used in this study. The autoignition properties of the air-fuel mixture are varied by changing the fuel octane number, percentage of exhaust gas recirculation (EGR), and air-fuel ratio, while holding the intake temperature, engine speed, and compression ratio constant. Results show that both the start of combustion and the burn duration are sensitive to mixture dilution (excess air or EGR). The fuel octane number is not an effective method of controlling the start of combustion or the burn duration but can be used to increase the load range of the HCCI engine. Both the NO x emissions and the indicated specific fuel consumption increase as the octane number is increased due to lower dilution and higher peak temperatures. Correct amounts of dilution are critical in controlling HCCI combustion. Separating dilution into EGR and excess air, it is found that a given amount of EGR is more effective at controlling the start of combustion and the burn duration than the same amount of excess air.

Study on the knock tendency and cyclical variations of a HCCI engine fueled with n-butanol/n-heptane blends

Fuel design real-time to control HCCI combustion

Homogenous charge compression ignition (HCCI) combustion is a low temperature combustion process which combines high combustion efficiency with ultra-low [Formula: see text] raw emissions. Steep increases of the in-cylinder pressure and unstable combustion sequences at the limits of the operating range can damage the engine and limit the use of HCCI to part load operation. This can be done using closed loop combustion control based on combustion parameters like the indicated mean effective pressure and the combustion phasing. Since in-cylinder pressure sensors are expensive components and therefore not suitable for series application, ion current sensors can be used as an additional source of information about the combustion. Combustion analysis using methods similar to those used in pressure based measurements can be implemented using an online analysis of the ion current signal. In this study, the ion current sensor will be examined for its suitability for combustion control under HCCI conditions with lean air/fuel ratios and high compression ratios. Research has found that the ion current signal is strongly depended on the boundary conditions. Especially the air/fuel ratio which plays an important role for signal strength during the combustion process. When using valve timings with negative valve overlap in combination with a fuel pre-injection, a further peak of the ion current signal close to the gas exchange top dead center can be found in addition to the one during combustion. At the same time, it is hard to extract information from the cylinder pressure signal during NVO. Under lean conditions this peak even exceeds the signal during combustion. This study analyzes the ion current signal during NVO and its potential to be used for future combustion control concepts. The ion current signal shows potential to stabilize HCCI combustion at high loads. However, the prediction of late combustion cycles is still challenging.