Generalized Eigenstate Thermalization Hypothesis in 2D Conformal Field Theories.

We revisit certain aspects of thermalization in 2D CFT. In particular, we consider similarities and differences between the time dependence of correlation functions in various states in rational and non-rational CFTs. We also consider the distinction between global and local thermalization and explain how states obtained by acting with a diffeomorphism on the ground state can appear locally thermal, and we review why the time-dependent expectation value of the energy-momentum tensor is generally a poor diagnostic of global thermalization. Since all 2D CFTs have an infinite set of commuting conserved charges, generic initial states might be expected to give rise to a generalized Gibbs ensemble rather than a pure thermal ensemble at late times. We construct the holographic dual of the generalized Gibbs ensemble and show that, to leading order, it is still described by a BTZ black hole. The extra conserved charges, while rendering $c < 1$ theories essentially integrable, therefore seem to have little effect on large-$c$ conformal field theories.

We study the motion of a classical particle subject to anisotropic harmonic forces and constrained to move on the sphere. In the integrable-systems literature this problem is known as the Neumann model. We choose the spring constants in a way that makes the connection with the so-called p = 2 spherical disordered system transparent. We tackle the problem in the N → ∞ limit by introducing a soft version in which the spherical constraint is imposed only on average over initial conditions. We show that the Generalized Gibbs Ensemble, constructed with N conserved charges in involution, captures the long-time averages of all relevant observables of the soft model after sudden changes in the parameters (quenches). We reveal the full dynamic phase diagram with four different phases in which the particles' position and momentum are both extended, only the position quasi-condenses or condenses, and both condense. The scaling properties of the fluctuations allow us to establish in which of these cases the strict and soft spherical constraints are equivalent. We thus confirm the validity of the GGE hypothesis for the Neumann model on a large portion of the dynamic phase diagram.

Two-dimensional CFTs have an infinite set of commuting conserved charges, known as the quantum KdV charges. We study the Generalized Gibbs Ensemble with chemical potentials for these charges at high temperature. In a large central charge limit, the partition function can be computed in a saddle-point approximation. We compare the ensemble values of the KdV charges to the values in a microstate, and find that they match irrespective of the values of the chemical potentials. We study the partition function at finite central charge perturbatively in the chemical potentials, and find that this degeneracy is broken. We also study the statistics of the KdV charges at high level within a Virasoro representation, and find that they are sharply peaked.

Integrable systems do not obey the strong eigenstate thermalization hypothesis (ETH), which has been proposed as a mechanism of thermalization in isolated quantum systems. It has been suggested that an integrable system reaches a steady state described by a generalized Gibbs ensemble (GGE) instead of thermal equilibrium. We prove that a generalized version of the strong ETH holds for noninteracting integrable systems with translation invariance. Our generalized ETH states that any pair of energy eigenstates with similar values of local conserved quantities looks similar with respect to local observables, such as local correlations. This result tells us that an integrable system relaxes to a GGE for any initial state that has subextensive fluctuations of macroscopic local conserved quantities. Contrary to the previous derivations of the GGE, it is not necessary to assume the cluster decomposition property for an initial state.

Virasoro conformal blocks are universal ingredients of correlation functions of two-dimensional conformal field theories (2d CFTs) with Virasoro symmetry. It is acknowledged that in the (classical) limit of large central charge of the Virasoro algebra and large external, and intermediate conformal weights with fixed ratios of these parameters Virasoro blocks exponentiate to functions known as Zamolodchikovs’ classical blocks. The latter are special functions which have awesome mathematical and physical applications. Uniformization, monodromy problems, black holes physics, quantum gravity, entanglement, quantum chaos, holography, mathcal{N} = 2 gauge theory and quantum integrable systems (QIS) are just some of contexts, where classical Virasoro blocks are in use. In this paper, exploiting known connections between power series and integral representations of (quantum) Virasoro blocks, we propose new finite closed formulae for certain multi-point classical Virasoro blocks on the sphere. Indeed, combining classical limit of Virasoro blocks expansions with a saddle point asymptotics of Dotsenko-Fateev (DF) integrals one can relate classical Virasoro blocks with a critical value of the “Dotsenko-Fateev matrix model action”. The latter is the “DF action” evaluated on a solution of saddle point equations which take the form of Bethe equations for certain QIS (Gaudin spin models). A link with integrable models is our main motivation for this research line. For instance, analogous quantities as the “DF on-shell action” appear in 2d CFT realization of the so-called Richardson’s solution of the reduced BCS model describing physics of ultra-small superconducting grains. Precisely, the Richardson solution and its particular limit characterizing the rational Gaudin model have known implementation in 2d CFT in terms of a free field representation of certain (perturbed and unperturbed) WZW blocks. The WZW analogue of the “DF on-shell action” appears here and plays a crucial role, it is a generating function for eigenvalues of quantum integrals of motion. An exploration of relationships between power expansions and Coulomb gas representations of the aforementioned WZW blocks could pave a way for new analytical tools useful in the study of models of the Richardson-Gaudin type.

We compute the Krylov Complexity of a light operator O\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\mathcal{O} $$\\end{document}L in an eigenstate of a 2d CFT at large central charge c. The eigenstate corresponds to a primary operator O\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\mathcal{O} $$\\end{document}H under the state-operator correspondence. We observe that the behaviour of K-complexity is different (either bounded or exponential) depending on whether the scaling dimension of O\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\mathcal{O} $$\\end{document}H is below or above the critical dimension hH = c/24, marked by the 1st order Hawking-Page phase transition point in the dual AdS3 geometry. Based on this feature, we hypothesize that the notions of operator growth and K-complexity for primary operators in 2d CFTs are closely related to the underlying entanglement structure of the state in which they are computed, thereby demonstrating explicitly their state-dependent nature. To provide further evidence for our hypothesis, we perform an analogous computation of K-complexity in a model of free massless scalar field theory in 2d, and in the integrable 2d Ising CFT, where there is no such transition in the spectrum of states.

There is a dichotomy in the nonequilibrium dynamics of quantum many body systems. In the presence of integrability, expectation values of local operators equilibrate to values described by a generalized Gibbs ensemble, which retains extensive memory about the initial state of the system. On the other hand, in generic systems such expectation values relax to stationary values described by the thermal ensemble, fixed solely by the energy of the state. At the heart of understanding this dichotomy is the eigenstate thermalization hypothesis (ETH): individual eigenstates in nonintegrable systems are thermal, in the sense that expectation values agree with the thermal prediction at a temperature set by the energy of the eigenstate. In systems where ETH is violated, thermalization can be avoided. Thus establishing the range of validity of ETH is crucial in understanding whether a given quantum system thermalizes. Here we study a simple model with confinement, the quantum Ising chain with a longitudinal field, in which ETH is violated. Despite an absence of integrability, there exist rare (nonthermal) states that persist far into the spectrum. These arise as a direct consequence of confinement: pairs of particles are confined, forming new `meson' excitations whose energy can be extensive in the system size. We show that such states are nonthermal in both the continuum and in the low-energy spectrum of the corresponding lattice model. We highlight that the presence of such states within the spectrum has important consequences, with certain quenches leading to an absence of thermalization and local observables evolving anomalously.

We consider quantum quenches in the so-called q-boson lattice model. We argue that the Generalized Eigenstate Thermalization Hypothesis holds in this model, therefore the Generalized Gibbs Ensemble (GGE) gives a valid description of the stationary states in the long time limit. For a special class of initial states (which are the pure Fock states in the local basis) we are able to provide the GGE predictions for the resulting root densities. We also give predictions for the long-time limit of certain local operators. In the q → ∞ limit the calculations simplify considerably, the wave functions are given by Schur polynomials and the overlaps with the initial states can be written as simple determinants. In two cases we prove rigorously that the GGE prediction for the root density is correct. Moreover, we calculate the exact time dependence of a physical observable (the one-site Emptiness Formation Probability) for the quench starting from the state with exactly one particle per site. In the long-time limit the GGE prediction is recovered.

After a quench, observables in an integrable system may not relax to the standard thermal values, but can relax to the ones predicted by the generalized Gibbs ensemble (GGE) [M. Rigol et al., Phys. Rev. Lett. 98, 050405 (2007)]. The GGE has been shown to accurately describe observables in various one-dimensional integrable systems, but the origin of its success is not fully understood. Here we introduce a microcanonical version of the GGE and provide a justification of the GGE based on a generalized interpretation of the eigenstate thermalization hypothesis, which was previously introduced to explain thermalization of nonintegrable systems. We study relaxation after a quench of one-dimensional hard-core bosons in an optical lattice. Exact numerical calculations for up to 10 particles on 50 lattice sites (≈10(10) eigenstates) validate our approach.

We review selected advances in the theoretical understanding of complex quantum many-body systems with regard to emergent notions of quantum statistical mechanics. We cover topics such as equilibration and thermalisation in pure state statistical mechanics, the eigenstate thermalisation hypothesis, the equivalence of ensembles, non-equilibration dynamics following global and local quenches as well as ramps. We also address initial state independence, absence of thermalisation, and many-body localisation. We elucidate the role played by key concepts for these phenomena, such as Lieb–Robinson bounds, entanglement growth, typicality arguments, quantum maximum entropy principles and the generalised Gibbs ensembles, and quantum (non-)integrability. We put emphasis on rigorous approaches and present the most important results in a unified language.

We investigate the eigenstate thermalization hypothesis (ETH) of highly excited descendant states in two-dimensional large central charge c conformal field theory. We use operator product expansion of twist operators to calculate the short interval expansions of entanglement entropy and relative entropy for an interval of length ℓ up to order ℓ12. Using these results to ensure ETH of a heavy state when compared with the canonical ensemble state up to various orders of c, we get the constraints on the expectation values of the first few quasiprimary operators in the vacuum conformal family at the corresponding order of c. Similarly, we also obtain the constraints from the expectation values of the first few Korteweg-de Vries charges. We check these constraints for some types of special descendant excited states. Among the descendant states we consider, we find that at most only the leading order ones of the ETH constraints can be satisfied for the descendant states that are slightly excited on top of a heavy primary state. Otherwise, the ETH constraints are violated for the descendant states that are heavily excited on top of a primary state.

We consider the Quantum Null Energy Condition (QNEC) for holographic conformal field theories in two spacetime dimensions (CFT_22). We show that QNEC saturates for all states dual to vacuum solutions of AdS_33 Einstein gravity, including systems that are far from thermal equilibrium. If the Ryu-Takayanagi surface encounters bulk matter QNEC does not need to be saturated, whereby we give both analytical and numerical examples. In particular, for CFT_22 with a global quench dual to AdS_33-Vaidya geometries we find a curious half-saturation of QNEC for large entangling regions. We also address order one corrections from quantum backreactions of a scalar field in AdS_33 dual to a primary operator of dimension h in a large central charge expansion and explicitly compute both, the backreacted Ryu–Takayanagi surface part and the bulk entanglement contribution to EE and QNEC. At leading order for small entangling regions the contribution from bulk EE exactly cancels the contribution from the back-reacted Ryu-Takayanagi surface, but at higher orders in the size of the region the contributions are almost equal while QNEC is not saturated. For a half-space entangling region we find that QNEC is gapped by h/4h/4 in the large h expansion.

We investigate a weak version of subsystem eigenstate thermalization hypothesis (ETH) for a two-dimensional large central charge conformal field theory by comparing the local equivalence of high energy state and thermal state of canonical ensemble. We evaluate the single-interval Rényi entropy and entanglement entropy for a heavy primary state in short interval expansion. We verify the results of Rényi entropy by two different replica methods. We find nontrivial results at the eighth order of short interval expansion, which include an infinite number of higher order terms in the large central charge expansion. We then evaluate the relative entropy of the reduced density matrices to measure the difference between the heavy primary state and thermal state of canonical ensemble, and find that the aforementioned nontrivial eighth order results make the relative entropy unsuppressed in the large central charge limit. By using Pinsker’s and Fannes-Audenaert inequalities, we can exploit the results of relative entropy to yield the lower and upper bounds on trace distance of the excited-state and thermal-state reduced density matrices. Our results are consistent with subsystem weak ETH, which requires the above trace distance is of power-law suppression by the large central charge. However, we are unable to pin down the exponent of power-law suppression. As a byproduct we also calculate the relative entropy to measure the difference between the reduced density matrices of two different heavy primary states.

We investigate dynamical equilibration of expectation values in closed quantum systems for realistic non-equilibrium initial states. Thereby we find that the corresponding long-time expectation values depend on the initial expectation values if eigenstate thermalisation is violated. An analytical expression for the deviation from the expected ensemble value is derived for small displacements from equilibrium. Additional numerics for magnetisation and energy equilibration in an asymmetric anisotropic spin-(1/2)-ladder demonstrate that the analytical predictions persist beyond the limits of the theory. The results suggest eigenstate thermalisation as a physically necessary condition for initial-state–independent equilibration.

The electrocatalytic hydrogen evolution reaction (HER) is an efficient and economic pathway to generate clean hydrogen energy in a sustainable manner. To improve the HER activity of Earth-abundant catalysts, reducing the dimension of materials is an effective strategy, and in this context two-dimensional (2D) materials have received substantial research attention owing to their large surface area and 2D charge transport channels. However, the thermodynamically stable basal surface of 2D catalysts is usually inactive in catalysis, which significantly impedes further optimization of the 2D HER catalysts. In this Minireview, we highlight in detail that defect engineering in 2D catalysts could bring multiple benefits in improving the HER activity. From the point of view of kinetics, defect sites could serve as active sites for catalyzing the HER process directly, and the introduction of defect structures may result in the optimization of electronic structures of the catalysts, thereby facilitating the HER process. Besides, for catalytically inert substrate materials, the defect sites could act as anchoring sites for catalyst loading, thus realizing efficient HER performance with the aid of enhanced electric conductivity. We anticipated that this Minireview could provide useful guidance for designing advanced HER catalysts in the future.