Rapid thermal processing of next generation silicon solar cells

The rapid thermal processing (RTP) system requires critical control of temperature uniformity. For most RTP system, the structure and heating modes of heating component determined the control strategy. Major types of the heating system of nowadays RTP systems were reviewed and compared. Then a heating system for RTP was proposed to improve the uniformity of heaving emission, which includes optimally designed light path and high efficient light reflecting system. The simulating results of that were also given.

This paper highlights the basic principles of rapid thermal processing (RTP) systems and the important areas of concern. The basic system characteristics, the fundamental physics involved, and the techniques for temperature measurement and control are extensively reviewed. We summarize the options currently available for 15 RTP equipment manufacturers and point out the latest developments in RTP system design and temperature measurement. Some novel options for temperature control (optical, fiber optical, and photoacoustic) are included.

Issues of rapid thermal processing (RTP) system design and process applications are reviewed. Temperature measurement is the most important and limiting factor in current RTP systems. Problems related to the temperature measurement and control and potential solutions are discussed. Process uniformity control is another important issue in RTP system design. Reactor chamber design, selection and arrangement of heat source, as well as issues related to dislocation generation, patterned and doped wafer, and ramp-up (down) thennal cycle are considered. Experimental results (RTO, RTCVD silicon nitride and polysilicon) based on an in-house RTP system developed in our laboratory are taken as examples to demonstrate the process applications and system requirements for single wafer processing.

A first-principles approach to the modeling of a rapid thermal processing (RTP) system to obtain temperature uniformity is described. RTP systems are single wafer and typically have a bank of heating lamps which can be individually controlled. Temperature uniformity across a wafer is difficult to obtain in RTP systems. A temperature gradient exists outward from the center of the wafer due to cooling for a uniform heat flux density on the surface of the wafer from the lamps. Experiments have shown that the nonuniform temperature of a wafer in an RTP system can be counteracted by adjusting the relative power of the individual lamps, which alters the heat flux density at the wafer. The model is composed of two components. The first predicts a wafer's temperature profile given the individual lamp powers. The second determines the relative lamp power necessary to achieve uniform temperature everywhere but at the outermost edge of the wafer (cooling at the edge is always present). The model has been verified experimentally by rapid thermal chemical vapor deposition of polycrystalline silicon with a prototype LEISK RTP system. The wafer temperature profile is inferred from the poly-Si thickness. Results showed a temperature uniformity of +or-1%, an average absolute temperature variation of 5.5 degrees C, and a worst-case absolute temperature variation of 6.5 degrees C for several wafers processed at different temperatures.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

Rapid thermal processing (RTP) is becoming increasingly more important in semiconductor wafer fabrication. A nonlinear physical model for a generic RTP system is described. This generic RTP system is representative of the state-of-the-art RTP systems. A low-order nonlinear model is developed. A model-based LQG controller is designed for the low-order model which successfully controls the full-order nonlinear simulation model.

A new proprietary rapid thermal processing (RTP) method has been developed and implemented for the fast switching of a gas ambient surrounding a wafer inside a RTP furnace operated in the low pressure or atmospheric pressure regime. By controlling the gas flow pattern around a semi-conductor wafer, the effective volume of process gas interacting with the wafer has been reduced by a factor of 33. Thus, real-time gas sequencing can be realized so that multiple rapid thermal processing steps, involving dry and wet rapid thermal oxidation (RTO), rapid thermal nitridation (RTN), rapid thermal annealing (RTA) and chemical vapor deposition (CVD), can be carried out sequentially in a single RTP cycle. Experimental data from ion implant anneal and thermal oxide thin film growth will be presented to illustrate the major technical challenges and solutions associated with the integration of the new method into the Summit/spl trade/ RTP systems. Using this approach, the benefits of rapid thermal processing with high productivity and quick ambient switching is realized.

The design of a decentralized controller has been studied as an integral part of the development of a commercial rapid thermal processing (RTP) system for manufacturing display glass. The glass RTP system uses bulb-type tungsten-halogen lamps for heating. A highly uniform temperature distribution with a maximum temperature difference of less than 6 °C between any two points is required during glass processing, regardless of the size of the glass. In designing a decentralized controller that satisfies this requirement, the problems of optimal sensor location, lamp grouping, optimization-based controller tuning, and time-varying bias input signals were identified and solved. The performance of the controller was investigated experimentally and numerically.

A resistively heated, vacuum- and atmospheric-pressure-compatible, single-wafer furnace (SWF) system is designed to improve the operational flexibility of conventional furnaces and the productivity of single-wafer rapid thermal processing (RTP) systems. The heat source design and system operation concepts are described. The temperature measurement/control techniques and thermal characteristics of the heat source are described. The heat transfer mechanism between the heat source and Si wafer is discussed. Temperature and process uniformity in SWF were demonstrated in TiSi formation, implant annealing and thin-oxide formation. The defect-generation phenomenon in Si wafers during atmospheric pressure RTP in a SWF system is investigated as a function of temperature, process time, wafer handling method and speed. Highly repeatable slip-free RTP results were achieved in 200-mm-diameter Si wafers processed at 1100°C for 60 s (up to 5 times) through the optimization of the wafer handling method and speed.

A novel method for the estimation of the temperature distribution in a rapid thermal processing (RTP) system is developed in this paper. The proposed method uses a proper orthogonal decomposition algorithm to extract the dominant modes of the temperature distribution and a reduced-order model is obtained. Then, a reduced-order sliding-mode observer is developed to capture the dynamics of the dominant modes. The estimated dynamics of the dominant modes can be used to reconstruct the temperature distribution. It is proved that the estimation error would be drawn into a small boundary rapidly. Test results confirm the effectiveness of the proposed observer for the RTP system.

In this paper, a model-based control method for RTP (Rapid Thermal Processing) system is proposed. RTP system is a device used to heat semiconductor wafers uniformly. It can heat wafers rapidly and reduce the processing time. However, it is very difficult for a RTP system to achieve the extremely stringent requirement on temperature uniformity (±1[K] or less) without suitably controlling and coordinating the radiative heat flux from the halogen lamps. In this research, the location of lamps is optimized first. Then, a feedback control system is designed which provides optimal temperature control during the thermal processing. The design is carried out based on a linearized model and H2 optimal control. The effect of sensor location is also investigated. Numerous simulations show that satisfactory performances are obtained in both the tracking and the uniformity of wafer temperature.

Expeditious urbanization and rapid industrialization have significantly influenced the rise of energy demand globally in the past two decades. Solar energy is considered a vital energy source that addresses this demand in a cost-effective and environmentally friendly manner. Improving solar cell efficiency is considered a prerequisite to reinforcing silicon solar cells’ growth in the energy market. In this study, the influence of various parameters like the thickness of the absorber or wafer, doping concentration, bulk resistivity, lifetime, and doping levels of the emitter and back surface field, along with the surface recombination velocity (front and back) on solar cell efficiency was investigated using PC1D simulation software. Inferences from the results indicated that the bulk resistivity of 1 Ω·cm; bulk lifetime of 2 ms; emitter (n+) doping concentration of 1×1020 cm−3 and shallow back surface field doping concentration of 1×1018 cm−3; surface recombination velocity maintained in the range of 102 and 103 cm/s obtained a solar cell efficiency of 19%. The Simulation study presented in this article allows faster, simpler, and easier impact analysis of the design considerations on the Si solar cell wafer fabrications with increased performance.

We consider the recursive identification and feedback control of the rapid thermal processing (RTP) system where the asymmetry of the convective heat transfer coefficient, caused by gas flow in the chamber, is taken into consideration. The success of RTP depends on the precise control of water temperature by adjusting the strength of the heating lamps to minimize dopant redistribution as well as wafer warpage. An efficient method of recursive identification and optimal feedback control is developed by separating the radiation field from the temperature field of the wafer and converting the heat conduction equation for the wafer temperature to a reduced-order model by means of the Karhunen-Loève Galerkin procedure.

In this letter, we have demonstrated phosphorus diffusion into silicon at a temperature of 700 °C using dual spectral source rapid thermal processing (RTP). The optical energy of vacuum ultraviolet irradiation in conjunction with tungsten halogen lamps (light source used in conventional RTP) is responsible for diffusion at low temperatures. Shallow junctions with high surface concentration were formed and no significant degradation in the bulk minority carrier lifetimes was observed. A qualitative explanation for the observed results is offered based on the role of photoeffects in RTP.

The oxidation and nitridation processes of niobium films in a rapid thermal processing (RTP) – system were investigated. 200 and 500 nm niobium films were deposited via sputtering on sapphire-(1-102)-substrate. At first niobium films were oxidized in molecular oxygen at temperatures ranging from 350 to 500 °C and for times of 1, 2 and 5 min and then nitridated in ammonia at 1000 °C for 1 min using an RTP system. For characterisation of the niobium films complementary analytical methods were used: X-ray diffraction (XRD) for phase analysis, secondary ion mass spectrometry (SIMS) for determining the elemental depth profiles of the films, scanning electron microscopy (SEM) and atomic force microscopy (AFM) for characterisation of the surface morphology of the films. The influence of the substrate, single crystalline sapphire, on the reactivity of the niobium films was studied in dependence of temperature, time of reaction and film thickness. The possibility of existence of niobium oxynitride phase was investigated. According to XRD and SIMS data, there is evidence that an oxynitride phase is formed after oxidation and subsequent nitridation in the bulk of some Nb films. In some of the experiments crack formation in the films or even delamination of the Nb films from the substrates was observed.

In this work, efficiency enhancement of wafer based polycrystalline silicon (pc-Si) solar cells has been investigated by using plasmonic silver nanoparticles (Ag NPs) on the top surface. Ag NPs has been fabricated by rapid thermal processing (RTP) of non-continuous silver thin film at low temperature regime (200–300 °C) for various RTP durations (5–30 min). The results obtained reveals that an optimum RTP durations of 20 min leads to drastic reflectance reduction of pc-Si wafers with minimum average particle size at all temperatures. At 20 min RTP duration, the total reflectance of the pc-Si wafers integrated with Ag NPs reduced from 35.1% of the raw pc-Si wafer to 12.97, 17.9 and 19.31% respectively at 200, 250 and 300 °C in the wavelength region 300–800 nm. Around 3% increase in conversion efficiency of pc-Si solar cells is observed due to incorporation of plasmonic Ag nanoparticles.